Identification of subwatershed sources for chlorinated pesticides and polychlorinated biphenyls in the Ballona Creek watershed

Santa Monica Bay forms part of the western border of the greater Los Angeles region. The Ballona Creek watershed is highly urbanized and past studies indicate that Ballona Creek is the largest source for most pollutants to Santa Monica Bay. This study evaluates the contribution of subwatersheds to PCB and chlorinated pesticide loading during wet weather flow. Fifteen storm drains from these subwatersheds were sampled during three storms during the 2005-2006 winter rainy season. A series of grab samples were taken over the duration of the storms. The suspended solids were analyzed for polychlorinated biphenyls (PCBs) and chlorinated pesticides. A geographic information system (GIS) was used to calculate the runoff volume from each subwatershed to estimate pollution mass loading. There was no statistical difference among subswatersheds; however, a disproportionate mass of PCB loading came from site 5, which had no obvious sources. No specific subwatersheds were identified as key sources for chlorinated pesticides. These results may serve as a model for other locations with concerns for historic PCB and chlorinated pesticides loadings.     

Anthropogenic forcing of estuarine hypoxic events in sub-tropical catchments: landscape drivers and biogeochemical processes

Episodic hypoxic events can occur following summer floods in sub-tropical estuaries of eastern Australia. These events can cause deoxygenation of waterways and extensive fish mortality. Here, we present a conceptual model that links key landscape drivers and biogeochemical processes which contribute to post-flood hypoxic events. The model provides a framework for examining the nature of anthropogenic forcing. Modification of estuarine floodplain surface hydrology through the construction of extensive drainage networks emerges as a major contributing factor to increasing the frequency, magnitude and duration of hypoxic events. Forcing occurs in two main ways. Firstly, artificial drainage of backswamp wetlands initiates drier conditions which cause a shift in vegetation assemblages from wetland-dominant species to dryland-dominant species. These species, which currently dominate the floodplain, are largely intolerant of inundation and provide abundant labile substrate for decomposition following flood events. Decomposition of this labile carbon pool consumes oxygen in the overlying floodwaters, and results in anoxic conditions and waters with excess deoxygenation potential (DOP). Carbon metabolism can be strongly coupled with microbially-mediated reduction of accumulated Fe and Mn oxides, phases which are common on these coastal floodplain landscapes. Secondly, artificial drainage enhances discharge rates during the flood recession phase. Drains transport deoxygenated high DOP floodwaters rapidly from backswamp wetlands to the main river channel to further consume oxygen. This process effectively displaces the natural carbon metabolism processes from floodplain wetlands to the main channel. Management options to reduce the impacts of post-flood hypoxia include i) remodifying drainage on the floodplain to promote wetter conditions, thereby shifting vegetation assemblages towards inundation-tolerant species, and ii) strategic retention of floodwaters in the backswamp wetlands to reduce the volume and rate during the critical post-flood recession phase.     

Reflections on conceptual tempo: Relationship between cognitive style and performance as a function of task characteristics.

Reflectives have been shown to outperform impulsives on tasks that require a cautious, systematic approach. A study was conducted to determine whether reflectives, particularly high-anxious reflectives, would show superior performance on speeded tasks; i.e., whether they would exhibit flexibility vs continued caution at the expense of performance. 46 male and 54 female 4th graders, selected by their scores on the Test Anxiety Scale for Children and the Lie Scale for Children as being reflective and impulsive, high and low anxious, were presented with speeded tasks of increasing difficulty. Results reveal that contrary to prediction, high-anxious reflectives performed as well as low-anxious reflectives and both were generally faster and more accurate than impulsives. Only for girls on the most difficult task was there evidence that reflection in combination with high anxiety resulted in overly cautious behavior and impaired performance. Results suggest a definition of cognitive style that stresses the strategy used rather than the disposition for long or short decision times. In addition, a model is proposed to predict the relative speed and accuracy of reflectives and impulsives as a function of the strategy required and the degree of intertrial transfer on the task. (25 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)