Ferroelectric,dielectric, magnetic,structural and photocatalytic properties of Co and Fe doped LaCrO3 perovskite synthesized via micro-emulsion route

In the present investigation, La_1-xCo_xCr_1-yFe_yO₃ (x,y = 0.0, 0.12, 0.36, 0.60) perovskite was fabricated via a facile micro-emulsion route. The synthesized perovskites were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) techniques to examine the effect of Co and Fe ions on the physico-chemical properties. The ferroelectric, dielectric, and magnetic properties of La_1-xCo_xCr_1-yFe_yO₃ were changed significantly as a function of dopants contents (Co and Fe ions). Outcomes revealed that the dielectric, ferroelectric and magnetic properties of LaCrO₃ perovskite can be tuned significantly via Co and Fe doping and La_0.40Co_0.60Cr_0.40Fe_0.60O₃ have potential for photocatalytic dye removal under (visible) light expoure. The photocatalytic activity (PCA) of the pristine LaCrO₃ and La_0.40Co_0.60Cr_0.40Fe_0.60O₃ photocatalyst was evaluated under (visible) light irradiation for crystal violet (CV) dye. Experimental results revealed that La_0.40Co_0.60Cr_0.40Fe_0.60O₃ photocatalyst degrdae almost 77.21% CV dye with the rate constant value of 0.01475 min^?1. In the presence of isopropyl alcohol (IPA) scavenger, the PCA of the La_0.40Co_0.60Cr_0.40Fe_0.60O₃ photocatalyst and rate constant value of the photocatalytic reaction decreased to 32.5% and 0.00491 min^?1, suggesting the superoxide as main active specie. Results revealed that Co and Fe doping doped material is efficient for photocatalytic presentations under solar light expoure.     

Synthesis,characterization and charge transport properties of Pr–Ni Co-doped SrFe2O4 spinel for high frequency devices applications

Ferrites are materials of interest due to their broad applications in high technological devices and a lot of research has been focused to synthesize new ferrites. In this regard, an effort has been devoted to synthesize spinel Pr–Ni co-substituted strontium ferrites with a nominal formula of Sr_1-xPr_xFe_2-yNi_yO₄ (0.0 ≤ x ≤ 0.1, 0.0 ≤ y ≤ 1.0). The cubic structure of pure and Pr–Ni co-substituted strontium ferrite samples calcinated at 1073 K for 3 h has been confirmed through X-ray diffraction (XRD). Average sizes of crystallites (18–25 nm) have been estimated from XRD analysis and nanometer particle sizes of synthesized ferrites have been further verified by scanning electron microscopy (SEM). SEM results have also shown that particles are mostly agglomerated and all the samples possess porosity. It has been observed that at 298 K, the values of resistivity (ρ) increase, while that of AC conductivity, dielectric loss, and dielectric constants decrease with increasing amounts of Pr³⁺ and Ni²⁺ ions. The values of dielectric parameters initially decrease with frequency and later become constant and can be explained on the basis of dielectric polarization. Electrochemical impedance spectroscopy (EIS) studies show that the charge transport phenomenon in ferrite materials is mainly controlled via grain boundaries. Overall, synthesized ferrite materials own enhanced resistivity values in the range of 1.38 × 10⁹–1.94 × 10⁹ Ω cm and minimum dielectric losses, which makes them suitable candidates for high frequency devices applications.     

Comparison of Conventional and Cross-Layer Multimedia Transport Schemes for Wireless Networks

Three competing schemes have been proposed for multimedia transport over broadband wireless channels: (a) traditional UDP (Postel, The User Datagram Protocol, 1980 [1]), (b) semi-cross-layer UDP-Lite (The Lightweight User Datagram Protocol, 2004 [2]), and (c) cross-layer header estimation (Khayam et al., IEEE Transactions on Multimedia 9(2):377–385, 2007 [3]; Khayam and Radha, IEEE Transactions on Wireless Communications 6(11):3946–3954, 2007 [4]). In all these schemes, corrupted and lost packets are recovered using FEC at the application layer. In this paper, we analytically and experimentally compare the performances of these broadband wireless multimedia schemes. First, we derive lower bounds on the excepted FEC redundancy required by ideal cross-layer header estimation, UDP and UDP-Lite over an arbitrary-order Markov wireless channel. We show that under realistic wireless channel conditions, the cross-layer header estimation scheme always requires lesser redundancy than UDP and UDP-Lite. We then propose a practical minimum distance decoding (MDD) header estimation scheme, which is receiver-based, low complexity and highly accurate. Trace-driven multimedia experiments over wireless LANs demonstrate that MDD header estimation requires significantly lesser FEC redundancy and renders better video quality than existing schemes.     

A Functional Programming Framework for Latency Insensitive Protocol Validation

Latency insensitive protocols (LIPs) have been proposed as a viable means to connect synchronous IP blocks via long interconnects in a system-on-chip. The reason why one needs to implement LIPs on long interconnects stems from the fact that with increasing clock frequencies, the signal delay on some interconnects exceeds the clock period. Correctness of a system composed of synchronous blocks communicating via LIPs is established by showing latency equivalence between a completely synchronous composition of the blocks, and the LIP based composition. A design flow based on a synchronous composition specification, and stepwise refinement to LIP composition can be easily conceived, and a proof obligation to show latency equivalence between the synchronous specification and the refinement needs to be discharged. In this work, we propose a functional programming based framework for modeling and simulating LIP, and implement the semantics of various refinement steps in the programming model, so we can validate the LIP model against the original system within this functional programming framework. Such validation becomes easier due to the inherent denotational model of functional languages. We specifically use Standard ML to model the original system implementation as well as its latency insensitive version and compare the two by creating a model that contains both, giving them the same inputs and checking their outputs to be latency equivalent.     

A comprehensive design and performance evaluation study of counter flow wet cooling towers

Fouling of cooling tower fills is one of the most important factors affecting its thermal performance, which reduces cooling tower effectiveness and capability with time. In this paper, the fouling model presented in an earlier paper using the experimental data on fill fouling, is used to investigate the risk based thermal performance of the cooling tower. It is demonstrated that effectiveness of the cooling tower degrades significantly with time indicating that for a low risk level (p=0.01), there is about 6.0% decrease in effectiveness for the given fouling model. The sensitivity analysis of the cooling tower is investigated for both rating and design calculation for different values of mass flow rate ratios. The effect of atmospheric pressure on the thermal performance of the cooling tower is also demonstrated.     

Header Detection to Improve Multimedia Quality Over Wireless Networks

Wireless multimedia studies have revealed that forward error correction (FEC) on corrupted packets yields better bandwidth utilization and lower delay than retransmissions. To facilitate FEC-based recovery, corrupted packets should not be dropped so that maximum number of packets is relayed to a wireless receiver's FEC decoder. Previous studies proposed to mitigate wireless packet drops by a partial checksum that ignored payload errors. Such schemes require modifications to both transmitters and receivers, and incur packet-losses due to header errors. In this paper, we introduce a receiver-based scheme which uses the history of active multimedia sessions to detect transmitted values of corrupted packet headers, thereby improving wireless multimedia throughput. Header detection is posed as the decision-theoretic problem of multihypothesis detection of known parameters in noise. Performance of the proposed scheme is evaluated using trace-driven video simulations on an 802.11b local area network. We show that header detection with application layer FEC provides significant throughput and video quality improvements over the conventional UDP/IP/802.11 protocol stack     

Microstructure and characterization of phases in TIG welded joints of Zircaloy-4 and stainless steel 304L

Tungsten inert gas (TIG) welded joints between Zircaloy-4 and stainless steel 304L have been studied by scanning electron microscope (SEM) having energy dispersive system (EDS) as an attachment. Intermetallic compound Zr(Cr, Fe)₂ and Zr₂Fe–Zr₂Ni eutectic phase have been observed in the molten zone. The surface area occupied by intermetallic compound Zr(Cr, Fe)₂ is about twice compared to Zr₂Fe–Zr₂Ni eutectic phase. The shape of the intermetallic compound is rod like. The phases were also identified by using X-ray diffraction (XRD) technique. EDS and XRD results are quite in agreement.     

A physics‐based model of DC and microwave characteristics of GaN/AlGaN HEMTs

A physics‐based model of AlGaN/GaN High Electron Mobility Transistor (HEMT) is developed for the analysis of DC and microwave characteristics. Large‐ and small‐signal parameters are calculated for a given device dimensions and operating conditions. Spontaneous and piezoelectric polarizations at the heterointerface and finite effective width of the 2DEG gas have been incorporated in the analysis. The model predicts a maximum drain current of 523 mA/mm and transconductance of 138 mS/mm for a 1 μm × 75 μm device, which are in agreement with the experimental data. © 2007 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2007.