A Structurable Gel‐Polymer Electrolyte for Sodium Ion Batteries

In this work, a structurable gel‐polymer electrolyte (SGPE) with a controllable pore structure that is not destroyed after immersion in an electrolyte is produced via a simple nonsolvent induced phase separation (NIPS) method. This study investigates how the regulation of the nonsolvent content affects the evolving nanomorphology of the composite separators and overcomes the drawbacks of conventional separators, such as glass fiber (GF), which has been widely used in sodium ion batteries (SIBs), through the regulation of pore size and gel‐polymer position. The interfacial resistance is reduced through selective positioning of a poly(vinylidene fluoride‐co‐hexa fluoropropylene) (PVdF‐HFP) gel‐polymer with the aid of NIPS, which in turn enhances the compatibility between the electrolyte and electrode. In addition, the highly porous morphology of the GF/SGPE obtained via NIPS allows for the absorption of more liquid electrolyte. Thus, a greatly improved cell performance of the SIBs is observed when a tailored SGPE is incorporated into the GF separator through charge/discharge testing compared with the performance observed with pristine GF and conventional GF coated with PVdF‐HFP gel‐polymer.     

Low‐Power Nonvolatile Charge Storage Memory Based on MoS2 and an Ultrathin Polymer Tunneling Dielectric

Low‐power, nonvolatile memory is an essential electronic component to store and process the unprecedented data flood arising from the oncoming Internet of Things era. Molybdenum disulfide (MoS₂) is a 2D material that is increasingly regarded as a promising semiconductor material in electronic device applications because of its unique physical characteristics. However, dielectric formation of an ultrathin low‐k tunneling on the dangling bond‐free surface of MoS₂ is a challenging task. Here, MoS₂‐based low‐power nonvolatile charge storage memory devices are reported with a poly(1,3,5‐trimethyl‐1,3,5‐trivinyl cyclotrisiloxane) (pV3D3) tunneling dielectric layer formed via a solvent‐free initiated chemical vapor deposition (iCVD) process. The surface‐growing polymerization and low‐temperature nature of the iCVD process enable the conformal growing of low‐k (≈2.2) pV3D3 insulating films on MoS₂. The fabricated memory devices exhibit a tunable memory window with high on/off ratio (≈10⁶), excellent retention times of 10⁵ s with an extrapolated time of possibly years, and an excellent cycling endurance of more than 10³ cycles, which are much higher than those reported previously for MoS₂‐based memory devices. By leveraging the inherent flexibility of both MoS₂ and polymer dielectric films, this research presents an important milestone in the development of low‐power flexible nonvolatile memory devices.     

Corrugated Quantum-Well Infrared Photodetector Focal Plane Arrays

Corrugated quantum-well infrared photodetectors (C-QWIPs) have been proposed for long-wavelength infrared detection. In this work, we optimize the detector structure and produce a number of large format focal plane arrays (FPAs). Specifically, we adopt one-corrugation-per-pixel geometry to increase the active detector volume and incorporate a composite cover layer to preserve the large sidewall reflectivity, which results in a large detector quantum efficiency. We also optimize the detector material structure such as the final state energy, the doping density, and the number of quantum well periods to improve the FPA operation under the existing readout electronics. As a result, high FPA sensitivity has been achieved, and their characteristics are in agreement with the detector model. Based on this model, we perform a systematic analysis on the FPA performance with a wide range of detector and system parameters. We find that C-QWIP FPAs are capable of high-speed imaging especially for those with longer cutoff wavelengths.     

Phase Diversity for an Antenna-Array System With a Short Interelement Separation

This paper presents a simple procedure of obtaining a diversity gain in an antenna-array system with a short interelement separation, typically less than the carrier wavelength. The new technique provides a diversity gain through a noncoherent combination of received signals at each antenna element. The diversity gain arises because, as the number of signal components of the received signal at each antenna element becomes large enough and as the arrival angle of each signal component is distinct from one another, which is a general signal circumstance in most practical code division multiple access (CDMA) signal environments, the amplitudes of the received signals become nearly independent due to the phase difference among the received signals. The diversity gain was referred to as ldquophase diversityrdquo in this paper. The proposed technique is first theoretically analyzed to estimate the performance in terms of pseudorandom-noise-code acquisition, which is verified through extensive computer simulations. Then, through the experimental results that are obtained from a CDMA array-antenna base station system, it has been shown that the performance of noncoherent detection is proportionally improved to the number of antenna elements.     

Adaptive power saving mechanism considering the request period of each initiation of awakening in the IEEE 802.16e system

Performance of the IEEE 802.16 e power management is mainly affected by two operating parameters: the minimum sleep interval (T _min) and the maximum sleep interval (T _max), in sleep-mode operation. To enhance the performance, this letter proposes a new power saving mechanism, which adaptively controls these parameters by considering the request period of each initiation of awakening (Tint)- The numerical analysis and simulation results show that this mechanism can achieve better energy conservation with reasonable response delay of Medium Access Control (MAC) Service Data Units (SDUs) than the standard operation.     

Chiral Se Nanobrooms with Wavelength and Polarization Sensitive Scattering

High-index dielectric nanostructures offer strong magnetic and electric resonances in the visible range and low optical losses, stimulating research interest in their use for light manipulation technologies. Lithographic fabrication of dielectric nanostructures, while providing precise control over the pattern dimensions, limits the scalability of this approach for practical applications due to an inefficient fabrication process and limited production quantity. Here, the colloidal synthesis of high-index chiral dielectric nanostructures with a broom-like geometry made from trigonal Se is demonstrated. The anisotropic morphology and crystal structure of Se nanobrooms enable both linearly and circularly polarized scattering, as well as spectrum variation along the particle axis, which is, to the authors’ knowledge, the first observation of such behavior from dielectric colloidal nanostructures. To show the versatility of the highly scattering Se NB suspensions, 2D and 3D printing of Se NB inks are demonstrated as a proof of concept. This approach provides a way to manipulate light using aqueous dispersions of high-index dielectric nanostructures, unlocking their potential to fit in various morphologies and dimensions in 2D and 3D for broad applications.     

Mucoadhesive Phenolic Pectin Hydrogels for Saliva Substitute and Oral Patch

Oral disease is one of the most common conditions worldwide, negatively affecting general health, reducing the quality of life, and often developing into systemic illness. However, the design of therapeutic agents for oral diseases is challenging due to various unique features of the oral cavity, including its wet and dynamic environment and curved shape. Herein, the development of highly biocompatible mucoadhesive functional hydrogels for oral applications is reported, generated by introducing bio-inspired phenolic moieties into a pectin polymer. Pyrogallol-functionalized pectin (Pec-PG) can be crosslinked in situ via autoxidation without chemical agents and readily fabricated as various formulations. Sprayable Pec-PG hydrogel exhibits strong mucoadhesion and outstanding hydration ability ex vivo and in vivo, thus displaying significant potential as a novel saliva substitute for dry mouth. The authors further show that topical application of mucoadhesive Pec-PG patches pre-loaded with corticosteroid significantly promotes the repair of diabetic oral ulcer tissue via prolonged drug release, free radical scavenging, and physical barrier effects. Moreover, similar applications for oral ulcer treatment using a pectin hydrogel modified with catechol (Pec-CA), another phenolic moiety are demonstrated. Together, these findings suggest that mucoadhesive phenolic pectin derivatives can provide highly biocompatible, convenient, and effective hydrogel platforms for treating oral diseases.     

Hybrid film of chemically modified graphene and vapor-phase-polymerized PEDOT for electronic nose applications

A hybrid of graphene and conducting polymer holds great potential as the active materials for high performance chemical sensor application. In this work, a thin hybrid film of reduced graphene oxide (RG-O) and poly(3,4-ethylenedioxythiophene) (PEDOT) was fabricated by means of vapor phase polymerization and explored as active material for chemical sensors. The chemical sensors based on hybrid film of RG-O and PEDOT are capable of detecting electrical signals caused by the absorption of trace levels of different analyte vapors with high sensitivity, selectivity and fast response.