Fabrication of a Superhydrophobic Surface from a Smectic Liquid‐Crystal Defect Array

A novel fabrication method is developed for the preparation of superhydrophobic surfaces. The procedure uses focal conic structures of semi‐fluorinated smectic liquid crystals (LCs) whose periodic toric focal conic domains (TFCDs) are prepared on a surface modified substrate. Reactive ion etching (RIE) on the periodic TFCD surface leads to a superhydrophobic surface with a water contact angle of ～160° and a sliding angle of ～2° for a 10 µL water droplet. The results show that this phenomenon is due to the development of a dual‐scale surface roughness arising from the nanoscale protuberance caused by applying the RIE process to the top of the microscale TFCD arrays. The unique surface behavior is further verified by demonstrating that RIE on a flat lamellar liquid crystal film, in which the director is aligned parallel with surface, results in a relatively low hydrophobicity as compared to when periodic TFCDs are subjected to REI. The observations made in this publication suggest that a new approach exists for selecting potential candidates of superhydrophic surface formation based on spontaneous self‐assembly in smectic liquid‐crystalline materials.     

Hard coatings on polycarbonate plate by sol–gel reactions of melamine derivative,poly(vinyl alcohol), and silicates

Hard coatings were deposited on a polycarbonate plate using a sol–gel process with a melamine derivative, poly(vinyl alcohol) (PVA), and silicates and examined as potential substitutes for glass in cars. PVA was partially functionalized with (3-isocyanatopropyl)triethoxysilane, and the synthesized polymer was used to form a coating solution with methylated poly(melamine-co-formaldehyde), tetraethoxysilane, and methyltriethoxysilane. The coatings that contained both the melamine and silicate structures were deposited using a sol–gel process. The optimum conditions and formulation to obtain excellent physical properties of the coating were determined. Smooth coatings with the hardness of a 3H class pencil, excellent abrasion resistance and transparency were formed.     

Phase Diversity for an Antenna-Array System With a Short Interelement Separation

This paper presents a simple procedure of obtaining a diversity gain in an antenna-array system with a short interelement separation, typically less than the carrier wavelength. The new technique provides a diversity gain through a noncoherent combination of received signals at each antenna element. The diversity gain arises because, as the number of signal components of the received signal at each antenna element becomes large enough and as the arrival angle of each signal component is distinct from one another, which is a general signal circumstance in most practical code division multiple access (CDMA) signal environments, the amplitudes of the received signals become nearly independent due to the phase difference among the received signals. The diversity gain was referred to as ldquophase diversityrdquo in this paper. The proposed technique is first theoretically analyzed to estimate the performance in terms of pseudorandom-noise-code acquisition, which is verified through extensive computer simulations. Then, through the experimental results that are obtained from a CDMA array-antenna base station system, it has been shown that the performance of noncoherent detection is proportionally improved to the number of antenna elements.     

Automatic Transformation of Membrane‐Type Electronic Devices into Complex 3D Structures via Extrusion Shear Printing and Thermal Relaxation of Acrylonitrile–Butadiene–Styrene Frameworks

This work demonstrates a means of automatic transformation from planar electronic devices to desirable 3D forms. The method uses a spatially designed thermoplastic framework created via extrusion shear printing of acrylonitrile–butadiene–styrene (ABS) on a stress‐free ABS film, which can be laminated to a membrane‐type electronic device layer. Thermal annealing above the glass transition temperature allows stress relaxation in the printed polymer chains, resulting in an overall shape transformation of the framework. In addition, the significant reduction in the Young's modulus and the ability of the polymer chains to reflow in the rubbery state release the stress concentration in the electronic device layer, which can be positioned outside the neutral mechanical plane. Electrical analyses and mechanical simulations of a membrane‐type Au electrode and indium gallium zinc oxide transistor arrays before and after transformation confirm the versatility of this method for developing 3D electronic devices based on planar forms.     

Improved moment-based quadrature rule and its application to reliability-based design optimization

A moment method known as the fourth moment method can perform reliability analysis without optimization using the first four statistical moments. Numerical integration is used to calculate the statistical moments, where a moment-based quadrature rule can be used for integration nodes and weights. However, the moment-based quadrature rule has to solve a system of linear equations that can be numerically unstable. Considering this point, an improved moment-based quadrature rule is proposed and is applied to reliability-based design optimization. Finally, the moment-based RBDO is applied to numerical examples with a variety of random variables and target reliability indexes. From the numerical results, the performance of the improved moment-based quadrature rule can be confirmed and several guidelines are given for the moment-based RBDO.