Effects of humic acid and electrolytes on photocatalytic reactivity and transport of carbon nanoparticle aggregates in water

The effects of naturally occurring macromolecules such as humic acid (HA) and electrolytes on four fullerene nanoparticle suspensions (i.e., C₆₀, C₆₀(OH)₂₄, single- and multiwall carbon nanotubes) were explored with respect to: (1) characteristics of nanoparticle aggregates, (2) transport of the aggregates through a silica porous media, and (3) production of reactive oxygen species (ROS) from the photosensitized fullerene aggregates. The presence of HA and salts increased the size of aggregates and relative hydrophobicity associated with transport through silica beads, while decreasing ROS production. These data illustrate the importance that transformation of engineered nanomaterials (ENMs) through interactions with aquatic solutes may have in altering the environmental behavior of nanomaterials.     

An Efficient Modified HPSO-TVAC-Based Dynamic Economic Dispatch of Generating Units

Abstract

This paper proposes a novel particle swarm optimization (PSO) algorithm with population reduction, which is called modified new self-organizing hierarchical PSO with jumping time-varying acceleration coefficients (MNHPSO-JTVAC). The proposed method is used for solving well-known benchmark functions, as well as non-convex and non-smooth dynamic economic dispatch (DED) problems for a 24?h time interval in two different test systems. Operational constraints including the prohibited operating zones (POZs), the transmission losses, the ramp-rate limits and the valve-point effects are considered in solving the DED problem. The obtained numerical results show that the MNHPSO-JTVAC algorithm is very suitable and competitive compared to other algorithms and have the capacity to obtain better optimal solutions in solving the non-convex and non-smooth DED problems compared to the other variants of PSO and the state of the art optimization algorithms proposed in recent literature. The source codes of the HPSO-TVAC algorithms and supplementary data for this paper are publicly available at https://github.com/ebrahimakbary/MNHPSO-JTVAC.     

YSZ electrolyte coating on NiO–YSZ composite by electrophoretic deposition for solid oxide fuel cells (SOFCs)

A thick dense film of YSZ has been fabricated on a porous NiO–YSZ substrate from the YSZ powders in the mixtures of absolute acetyl acetone–ethanol suspensions by electrophoretic deposition (EPD) method. Parameters affected on substrate porosity like pre-sintering temperature and percentage of starch and parameters affected on EPD process like applied voltage and time of deposition have been investigated. Linear dependence between weights of deposition, deposition time and applied voltage were observed. A crack-free dense thick film of YSZ was obtained on porous NiO–YSZ substrate. Adhesion between the two layers was observed by SEM. The ability of ionic transfer and permeability of the YSZ electrolyte were investigated by EIS, as well.     

Effect of sintering temperature on the microstructure,roughness and electrochemical impedance of electrophoretically deposited YSZ electrolyte for SOFCs

In the present work, the microstructures of YSZ electrolyte films, which were sintered at various temperatures in the range of 1300–1600 °C, were investigated. First, a suitable and uniform film was deposited on the surface of NiO–YSZ composite by EPD. After the consequence sintering, the surfaces of deposited YSZ films were observed by SEM. In addition, other characteristics of the YSZ electrolyte films such as surface roughness and morphology of the sintered films were investigated by AFM. The ability of ionic transfer and permeability of the YSZ electrolyte was examined by electrochemical impedance spectroscopy at different temperatures. It seems that the YSZ electrolyte sintered at 1400 °C was appropriate for SOFCs applications, because this film had the minimum impedance, minimum roughness and the maximum conductivity. Furthermore, the temperature of 1400 °C was the minimum temperature in which a dense film of YSZ was formed uniformly on the surface of anode and coated it completely.     

On the Largest Possible Mobility of Molecular Semiconductors and How to Achieve It

A large database of known molecular semiconductors is used to define a plausible physical limit to the charge carrier mobility achievable within this materials class. From a detailed study of the desirable properties in a large dataset, it is possible to establish whether such properties can be optimized independently and what would be a reasonably achievable optimum for each of them. All relevant parameters are computed from a set of almost five thousand known molecular semiconductors, finding that the best known materials are not ideal with respect to all properties. These parameters in decreasing order of importance are the molecular area, the nonlocal electron–phonon coupling, the 2D nature of transport, the local electron–phonon coupling, and the highest transfer integral. It is also found that the key properties related to the charge transport are either uncorrelated or “constructively” correlated (i.e., they improve together) concluding that a tenfold increase in mobility is within reach in a statistical sense, on the basis of the available data. It is demonstrated that high throughput screenings, when coupled with physical models of transport produce both specific target materials and a more general physical understanding of the materials space.     

Green facile thermal decomposition synthesis,characterization and electrochemical hydrogen storage characteristics of ZnAl2O4 nanostructure

The ZnAl₂O₄ spinel was synthesized by a facile thermal decomposition method using green chemistry. For the first time, the electrochemical hydrogen storage performances and mechanisms of the ZnAl₂O₄ was studied by the galvanostatic charge-discharge method in 6 M KOH aqueous medium under 1 mA current. Anionic, cationic and polymeric surfactants were used to increase of hydrogen storage and specific area of ZnAl₂O₄ spinel. The composition, structure, morphology and specific surface area of the samples were characterized. The maximum measured discharge capacities of ZnAl₂O₄, ZnAl₂O₄/CTAB, ZnAl₂O₄/PVP and ZnAl₂O₄/SDS were 1250, 3000, 3250 and 4000 mAh/g, respectively. These samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), X-ray energy dispersive spectroscopy (EDS), N₂ adsorption (BET) and transmission electron microscope (TEM).     

Proteomics analysis of liver pathological calcification suggests a role for the IQ motif containing GTPase activating protein 1 in myofibroblast function

To date the cellular and molecular mechanisms by which liver pathological calcifications occur and are regulated are poorly investigated. To study the mechanisms linked to their appearance, we performed a proteomics analysis of calcified liver samples. To this end, human liver biopsies collected in noncalcified (N), precalcified (P), and calcified (C) areas of the liver were subjected to weak ion exchange chromatography, SDS‐PAGE, and LC‐ESI MS/MS analyses. As we previously demonstrated that alpha‐smooth muscle actin (α‐SMA) expressing myofibroblasts were involved in liver pathological calcification, we performed a targeted analysis of actin cytoskeleton remodeling‐related proteins. This revealed dramatic changes in protein expression patterns in the periphery of the calcified areas. More particularly, we found that IQGAP1 and IQGAP2 proteins were subjected to major expression changes. We show that IQGAP1 expression within P and C areas of the liver correlates with the high abundance of myofibroblasts and that IQGAP1 is specifically expressed in these cells. In addition, we find that IQGAP1 is part of a protein complex including β‐catenin and Rac1 mainly in P and C regions of the liver. These results suggest that IQGAP1 may play a critical role in the regulation of cytoskeleton remodeling in liver myofibroblasts in response to liver injury and consequently impact on their function.     

Homogeneous and two phase sulphonation of some aromatic hydrocarbons

The two phase sulphonation of benzene, toluene and p-xylene with concentrated sulphuric acid has been studied in a one litre batch reactor. The kinetic rate constants as a function of sulphuric acid concentration and the overall mass transfer coefficient times the interfacial area per unit volume of the acid phase as a function of agitation speed have been determined. The rates of sulphonation of toluene and p-xylene relative to that of benzene in the range 15.5–17 mol/litre sulphuric acid have been found to be 64 and 280 respectively. Finally, it has been shown that in aromatic sulphonation no linear relationship exists between the logarithms of the partial rate factors and the relative cation localisation energies. This is in contrast to the behaviour of some other electrophilic aromatic substitution such as halogenation, but is similar to aromatic nitration.