Investigating the role of hierarchy on the strength of composite materials: evidence of a crucial synergy between hierarchy and material mixing

Natural materials are often organized in complex hierarchical architectures to optimize mechanical properties. Artificial bio-inspired materials, however, have thus far failed to successfully mimic how these architectures improve material characteristics, for example strength. Here, a method is proposed for evaluating the role of hierarchy on structural strength. To do this, we consider different hierarchical architectures of fiber bundles through analytical multiscale calculations based on a fiber bundle model at each hierarchical level. In general, we find that an increase in the number of hierarchy levels leads to a decrease in the strength of material. However, when a composite bundle with two different types of fibers is considered, an improvement in the mean strength is obtained for some specific hierarchical architectures, indicating that both hierarchy and material "mixing" are necessary ingredients to obtain improved mechanical properties. Results are promising for the improvement and "tuning" of the strength of bio-inspired materials.     

Conformationally pre-organized and pH-responsive flat dendrons: synthesis and self-assembly at the liquid-solid interface

Efficient Cu-catalyzed 1,3-dipolar cycloaddition reactions have been used to prepare two series of three regioisomers of G-1 and G-2 poly(triazole-pyridine) dendrons. The G-1 and G-2 dendrons consist of branched yet conformationally pre-organized 2,6-bis(phenyl/pyridyl-1,2,3-triazol-4-yl)pyridine (BPTP) monomeric and trimeric cores, respectively, carrying one focal and either two or four peripheral alkyl side chains. In the solid state, the conformation and supramolecular organization were studied by means of a single crystal X-ray structure analysis of one derivative. At the liquid-solid interface, the self-assembly behavior was investigated by scanning tunneling microscopy (STM) on graphite surfaces. Based on the observed supramolecular organization, it appears that the subtle balance between conformational preferences inherent in the dendritic backbone on the one side and the adsorption and packing of the alkyl side chains on the graphite substrate on the other side dictate the overall structure formation in 2D.     

Mobile Active-Vision Traffic Surveillance System for Urban Networks

Abstract:   This article discusses the development of a mobile bus-mounted machine vision system for transit and traffic monitoring in urban corridors, as required by intelligent transportation systems. In contrast to earlier machine vision technologies used for traffic management, which rely mainly on fixed-point detection and simpler algorithms to detect certain traffic characteristics, the new proposed approach makes use of a recent trend in computer vision research; namely, the active vision paradigm. Active vision systems have mechanisms that can actively control camera parameters such as orientation, focus, zoom, and vergence in response to the requirements of the task and external stimuli. Mounting active vision systems on buses will have the advantage of providing real-time feedback of the current traffic conditions, while possessing the intelligence and visual skills that allow them to interact with a rapidly changing dynamic environment, such as moving traffic and continuously changing image background.     

Behavior of corrosion-damaged RC columns wrapped with FRP under combined flexural and axial loading

This paper presents the results of a research program aimed at investigating the effectiveness of carbon fiber-reinforced polymers (CFRP) to upgrade corrosion-damaged eccentrically loaded reinforced concrete (RC) columns. A total of 16 square RC columns with end corbels were constructed. Test specimen had an overall length of 1200 mm whereas each end corbel had a cross section of and a length of 350 mm. The specimen in the test region was having longitudinal steel ratio of 1.9%. The damaged specimens were exposed to 30 days of accelerated corrosion that corresponded to a steel mass loss of about 4.25%. The main test parameters were the CFRP repair scheme (no wrapping, full-wrapping, and partial-wrapping) and the eccentricity-to-section height (e/h) ratio (0.3, 0.43, 0.57, and 0.86). The strength of the damaged columns fully wrapped with CFRP was up to 40% higher than that of the control undamaged columns. The strength gain was inversely proportional to the eccentricity ratio. Partial CFRP-wrapping was 8% less effective than full CFRP-wrapping at nominal e/h of 0.3. At higher e/h values, the confinement level had a negligible effect on the columns’ strength. An analytical model was then proposed to predict the columns’ strength under eccentric loading. A comparative analysis between predicted and experimental results demonstrated the model’s accuracy and reliability.     

Lidar backscatter signal recovery from phototransistor systematic effect by deconvolution

Backscatter lidar detection systems have been designed and integrated at NASA Langley Research Center using IR heterojunction phototransistors. The design focused on maximizing the system signal-to-noise ratio rather than noise minimization. The detection systems have been validated using the Raman-shifted eye-safe aerosol lidar (REAL) at the National Center for Atmospheric Research. Incorporating such devices introduces some systematic effects in the form of blurring to the backscattered signals. Characterization of the detection system transfer function aided in recovering such effects by deconvolution. The transfer function was obtained by measuring and fitting the system impulse response using single-pole approximation. An iterative deconvolution algorithm was implemented in order to recover the system resolution, while maintaining high signal-to-noise ratio. Results indicated a full recovery of the lidar signal, with resolution matching avalanche photodiodes. Application of such a technique to atmospheric boundary and cloud layers data restores the range resolution, up to 60 m, and overcomes the blurring effects.     

Recent Progress in Discrete Dislocation Dynamics and Its Applications to Micro Plasticity

We present a self-contained review of the discrete dislocation dynamics (DDD) method for the numerical investigation of plasticity in crystals, focusing on recent development and implementation progress. The review covers the theoretical foundations of DDD within the framework of incompatible elasticity, its numerical implementation via the nodal method, the extension of the method to finite domains and several implementation details. Applications of the method to current topics in micro-plasticity are presented, including the size effects in nano-indentation, the evolution of the dislocation microstructure in persistent slip bands, and the phenomenon of dislocation avalanches in micro-pillar compression.     

Synthesised magnetic nanoparticles coated zeolite (MNCZ) for the removal of arsenic (As) from aqueous solution

A novel adsorbent, magnetic nanoparticle (γ-Fe₂O₃)-coated zeolite (MNCZ), was prepared for the removal of arsenic (As) ions from aqueous solution. The influence of different sorption parameters, that is, contact time, acidic reaction (pH) and initial arsenic concentration were studied using batch equilibrium techniques. The results obtained showed that the MNCZ was effective for the removal of As from aqueous solution, and the percentage removal of As could reach over 95.6% at a pH value of 2.5 within 15?min. Moreover, the removal of As depended on the initial concentration of As. For the regeneration of MNCZ material, 0.1?M NaOH was suitable for the desorption of As (70% after 15?min), and the regenerated material showed an adsorption capacity of 93.95% within five cycles. We concluded that MNCZ presents a reusable adsorbent for a fast, convenient and highly efficient removal of As from aqueous solution.     

Power saving mechanism for VoIP services over WiMAX systems

The IEEE 802.16 system provides the power saving class (PSC) type II as a power saving algorithm for voice over internet protocol (VoIP) service, but it is not designed to consider silent periods of VoIP traffic. The main objective of this paper is to introduce a power conservation mechanism that combines power saving modes class I, class II and class III which is applicable to VoIP service with silence suppression which basically follows PSC II during talk-spurt periods but in silence periods it combine PSC I and PSC III. According to experimental results, more than 96 % power reduction can be achieved in mutual silence period by using the proposed VoIP power saving mechanism for VoIP services during silent periods with respect to the Quality of Services.