Failure Analysis of Tool Steel-Based Compaction Punch Used in Powder Metallurgy

Powder metallurgy operations comprise the use of compaction dies and punches for transforming a mass of metallic powders into a porous block of aggregated particles with limited “green” strength. In this kind of application, dies and punches manufactured with tool steel are subjected to heavy loads to compress the metallic powders and form the block, which will be subjected to further consolidation operations such as sintering and/or some mechanical forming operation, such as forging or rolling. In general tool steels are high carbon and high alloyed steels designed for reaching high levels of mechanical strength, sufficient for his type of loading. However, defects on the surface of this material can lead to stress concentration, thus decreasing its fracture strength and eventually leading to failure. In this study, techniques such as optical and scanning electron microscopy are used to evaluate the possible causes of the failure of a compaction punch. The results indicated that machining grooves acted as stress concentrations which led to the premature fracture of the punch.     

Mechanical properties of high density polyethylene/carbon nanotube composites

Carbon-nanotubes (CNTs) have been used with polymers from the date of their inception to make composites having remarkable properties. An attempt has been made in this direction, in order to enhance mechanical and tribological properties of the composite materials. The latter, were achieved through the injection molding of high density polyethylene (HDPE) reinforced with specific volume fraction of CNTs. A considerable improvement on mechanical properties of the material can be observed when the volume fraction of CNT is increased. The composite reinforcement shows a good load transfer effect and interface link between CNT and HDPE. The volumetric wear rate is calculated from the Wang’s model, Ratner’s correlation and reciprocal of toughness. The results obtained clearly show the linear relationship with CNT loading which supports the microscopic wear model. It is concluded that both Halpin–Tsai and modified series model can be used to predict Young’s modulus of CNT–HDPE composites. From thermal analysis study, it is found that melting point and oxidation temperature of the composites are not affected by the addition of CNTs, however its crystallinity seems to increase.     

Dynamics of grain boundaries under applied mechanical stress

Recent results of experimental research into stress-induced grain boundary migration in aluminum bicrystals are reported. Boundary migration under a shear stress was observed to be coupled to a lateral translation of the grains for planar symmetrical 〈100〉 tilt boundaries. This coupling proved to be the typical migration mode of any 〈100〉 tilt boundary, no matter whether low- or high-angle, low Σ CSL coincidence or non-coincidence boundary. The measured ratios of normal boundary motion to the tangential displacement of grains are in an excellent agreement with theoretical predictions. The migration-shear coupling is also observed for asymmetrical 〈100〉 boundaries. Measurements of the temperature dependence of coupled boundary migration revealed that there is a specific misorientation dependence of migration activation parameters. Grain boundaries can act during their motion under the applied stress as sources of lattice dislocations that leads to the generation and growth of new grains in the boundary region. The rate of stress-induced boundary migration decreases with increasing solute content in aluminum. Both the migration activation enthalpy and the pre-exponential mobility factor were found to increase with rising impurity concentration.     

Neurocognitive abnormalities during comprehension of real-world goal-directed behaviors in schizophrenia.

Origins of impaired adaptive functioning in schizophrenia remain poorly understood. Behavioral disorganization may arise from an abnormal reliance on common combinations between concepts stored in semantic memory. Avolition–apathy may be related to deficits in using goal-related requirements to flexibly plan behavior. The authors recorded event-related potentials (ERPs) in 16 patients with medicated schizophrenia and 16 healthy controls in a novel video paradigm presenting congruous or incongruous objects in real-world activities. All incongruous objects were contextually inappropriate, but the incongruous scenes varied in comprehensibility. Psychopathology was assessed with the Scales for the Assessment of Positive and Negative Symptoms (SAPS/SANS) and the Brief Psychiatric Rating Scale. In patients, an N400 ERP, thought to index activity in semantic memory, was abnormally enhanced to less comprehensible incongruous scenes, and larger N400 priming was associated with disorganization severity. A P600 ERP, which may index flexible object–action integration based on goal-related requirements, was abnormally attenuated in patients, and its smaller magnitude was associated with the SANS rating of impersistence at work or school (goal-directed behavior). Thus, distinct neurocognitive abnormalities may underlie disorganization and goal-directed behavior deficits in schizophrenia. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Holographic patterning of luminescent photopolymer nanocomposites

Volume phase gratings in the photopolymerisable composites, containing luminescent nanoparticles have been fabricated for the first time. Nanoparticles of LaPO₄, doped by Ce³⁺ and Tb³⁺ ions (the trade name is REN-X-green) with high luminescence quantum yield were used as a luminescent inorganic additive. The holographic gratings in such materials are formed as a result of the diffusion distribution of the nanoparticles during exposure of photopolymerisable composites to interference pattern. The influence of the pre-polymer formulation and the holographic patterning parameters on the grating formation is comprehensively investigated. The use of the optimised pre-polymer syrup containing two monomers with sufficiently different polymerisation rates allows fabrication of gratings with diffraction efficiency up to 80% at low optical losses (< 5%) (20 μm film thickness). To obtain maximum diffraction efficiency the intensity and the period of the interference pattern were optimised for each formulation. In addition maximum diffraction efficiency was achieved with the nanocomposites containing 30–32 wt.% of nanoparticles. On the other hand the highest possible modulation of the nanoparticles' concentration was obtained for the concentration of about 20 wt.%. In this case maximum ordering of the nanoparticles in the polymer matrix is achieved. The photoluminescence of the nanoparticles within the homogeneous polymer film and within the grating has been measured. The example application of the photopolymerisable composite containing luminescence inorganic nanoparticles in holographic security technology has been demonstrated.     

Is the donut in front of the car? An electrophysiological study examining spatial reference frame processing.

Notes that the process of describing an object's location relative to another object results in ambiguity. How do people handle this ambiguity? The present 3 studies, using a total of 88 undergraduates, examined spatial language processing when use of different reference frames results in ambiguity. This study investigated whether electrophysiological measures of cognitive processing may elucidate underlying reference frame processing; in particular, the authors were interested in semantic integration. Electrophysiological results show a larger N400, peaking between 300 and 375 ms, when the intrinsic frame was not used. Behavioral results mirrored this finding, indicating a reduced cognitive processing requirement for the intrinsic reference frame. Previous work has not definitively tied spatial reference frame processing to specific electrophysiological components and their associated cognitive processes. Although the N400 peak seen in this data is early, additional work supports the N400 interpretation, thereby linking spatial frame processing to semantic integration. Results are discussed within the larger context of spatial reference frame processing. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Characteristics of traditional birth attendants and their beliefs and practices in the Offot Clan, Nigeria

The fragile X syndrome, one of the most common forms of inherited mental retardation, is caused by an expansion of a polymorphic CGG repeat upstream of the coding region in the FMR1 gene. The expansion blocks expression of the FMR1 gene due to methylation of the FMR1 promoter. Functional studies on the FMR1 protein have shown that the protein can bind RNA and might be involved in transport of RNAs from the nucleus to the cytoplasm. A role of FMR1 protein on translation of certain mRNAs has been suggested. An animal model for fragile X syndrome exists and these mice show some behavioural difficulties mimicking the human fragile X syndrome phenotype. This review presents what is known about the protein and what is learned from the animal model for fragile X syndrome.