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111.
    
Photothermal steam generation promises decentralized water purification, but current methods suffer from slow water evaporation even at high photothermal efficiency of ≈98%. This drawback arises from the high latent heat of vaporization that is required to overcome the strong and extensive hydrogen bonding network in water for steam generation. Here, light-to-vapor conversion is boosted by incorporating chaotropic/kosmotropic chemistries onto plasmonic nanoheater to manipulate water intermolecular network at the point-of-heating. The chaotropic-plasmonic nanoheater affords rapid light-to-vapor conversion (2.79 kg m−2 h−1 kW−1) at ≈83% efficiency, with the steam generation rate up to 6-fold better than kosmotropic platforms or emerging photothermal designs. Notably, the chaotropic-plasmonic nanoheater also lowers the enthalpy of water vaporization by 1.6-fold when compared to bulk water, signifying that a correspondingly higher amount of steam can be generated with the same energy input. Simulation studies unveil chaotropic surface chemistry is crucial to disrupt water hydrogen bonding network and suppress the energy barrier for water evaporation. Using the chaotropic-plasmonic nanoheater, organic-polluted water is purified at ≈100% efficiency, a feat otherwise challenging in conventional treatments. This study offers a unique chemistry approach to boost light-driven steam generation beyond a material photothermal property.  相似文献   
112.
    
Plasmon-mediated catalysis utilizing hybrid photocatalytic ensembles promises effective light-to-chemical transformation, but current approaches suffer from weak electromagnetic field enhancements from polycrystalline and isotropic plasmonic nanoparticles as well as poor utilization of precious co-catalyst. Here, efficient plasmon-mediated catalysis is achieved by introducing a unique catalyst-on-hotspot nanoarchitecture obtained through the strategic positioning of co-photocatalyst onto plasmonic hotspots to concentrate light energy directly at the point-of-reaction. Using environmental remediation as a proof-of-concept application, the catalyst-on-hotspot design (edge-AgOcta@Cu2O) enhances photocatalytic advanced oxidation processes to achieve superior organic-pollutant degradation at ≈81% albeit having lesser Cu2O co-photocatalyst than the fully deposited design (full-AgOcta@Cu2O). Mass-normalized rate constants of edge-AgOcta@Cu2O reveal up to 20-fold and 3-fold more efficient utilization of Cu2O and Ag nanoparticles, respectively, compared to full-AgOcta@Cu2O and standalone catalysts. Moreover, this design also exhibits catalytic performance >4-fold better than emerging hybrid photocatalytic platforms. Mechanistic studies unveil that the light-concentrating effect facilitated by the dense electromagnetic hotspots is crucial to promote the generation and utilization of energetic photocarriers for enhanced catalysis. By enabling the plasmonic focusing of light onto co-photocatalyst at the single-particle level, the unprecedented design offers valuable insights in enhancing light-driven chemical reactions and realizing efficient energy/catalyst utilizations for diverse chemical, environmental, and energy applications.  相似文献   
113.
对层叠芯片BGA(SDBGA)阵列进行了线性小变形和非线性大翘曲仿真。与实验测量结果相比,线性方法不能反映翘曲形态而非线性大变形仿真能够反映出这种翘曲。原因在于,在小变形假设下,线性仿真不能考虑变形之后横断面惯性矩的变化。而非线性仿真则不受此假设的影响。文中基于非线性特性分析、预测了在整个集成工艺中SDBGA阵列的翘曲。利用“弯曲交互作用”和“翘曲竞争”解释了SDBGA阵列的翘曲特性。通过与线性仿真结果的比较,量化了几何非线性对集成工艺中SDBGA块封装翘曲的影响。  相似文献   
114.
A highly integrated 1.75-GHz 0.35-μm CMOS transmitter is described. The I/Q modulator-based transmitter facilitates integration through the use of a unique mixer, termed a harmonic-rejection mixer, and a wide loop bandwidth phase-locked loop (PLL) for the RF synthesizer. The harmonic-rejection mixers are used to eliminate the need for a discrete IF filter and the use of a wide loop bandwidth PLL allowed for the complete integration of the synthesizers using low-Q components while achieving low phase noise. The entire transmit signal path from the digital-to-analog converters to the power amplifier, including two fully integrated frequency synthesizers, is integrated into a single-chip solution. The transmitter was tested with a testing buffer before the power amplifier (PA) and achieved less than 1.3° rms phase error when modulating a DCS-1800 GMSK signal. The prototype consumed 151 mA from a 3-V supply. A class-C PA, capable of driving 25 dBm off-chip, was included and the output was compared to the testing buffer with little change in the transmitter performance  相似文献   
115.
This article presents a new method for discrimination of various types of pulses generated during an electrical discharge machining process in presence of a rotating electrode. Existing pulse discrimination methods do not perform efficiently in an electrical discharge machine with rotating electrode, as arcs rarely occur during the machining process. Our method involves simultaneous comparison of the gap voltage and current signals with various thresholds. The main advantage of our proposed method is its efficient computation and significantly better accuracy in discriminating between various pulse classes for electrical discharge machining devices with rotating electrode. Experimental studies demonstrate a superior performance of our method in distinguishing normal pulses from harmful arcs, open circuit and short circuit pulses, compared with the state-of-art methods.  相似文献   
116.
    
Despite more than a decade of study, there are still significant obstacles to overcome before graphene can be successfully produced on a large scale for commercial use. Chemical oxidation of graphite to produce graphene oxide (GO), followed by a subsequent reduction process to synthesize reduced graphene oxide (rGO), is considered the most practical method for mass production. Microorganisms, which are abundant in nature and inexpensive, are one of the potential green reductants for rGO synthesis. However, there is no recent review discussing the reported microbial reduction of GO in detail. To address this, we present a comprehensive review on the reduction of GO by a range of microorganisms and compared their efficacies and reaction conditions. Also, presented were the mechanisms by which microorganisms reduce GO. We also reviewed the recent advancements in using microbially reduced GO as the anode and cathode material in the microbial fuel cell (MFC) and algal biophotovoltaics (BPV), as well as the challenges and future directions in microbial fuel cell research.  相似文献   
117.
Efficient wavelet-based image denoising algorithm   总被引:8,自引:0,他引:8  
Characterising the statistics of wavelet coefficients is a critical issue in image compression and denoising. Many powerful approaches have been investigated, but accurate modelling suffers from high computational complexity. In this work an efficient adaptive algorithm to capture the dependency of both inner and inter scale wavelet coefficients is proposed. Experimental results show that compared with other algorithms, in the case of higher noise variance, greater PSNR performance gain may be obtained  相似文献   
118.
With the advent of modern computing technology, there is increased reliance on biometrics to provide stronger personal authentication. Among the variety of biometric solutions in the market, hand-based system is the oldest, and perhaps the most successful form of biometric technology. This paper describes a contactless hand-based biometric system by using visible and infrared imagery. An acquisition device is developed to capture both color and infrared hand images. We modify an ordinary web camera to capture the hand vein that normally requires specialized infrared sensor. The design is simple and low-cost. No additional installation of special apparatus is required. The device can capture the epidermal and subcutaneous features from the hand simultaneously. In specific, five features namely hand geometry, palm print, palmar knuckle print, palm vein, and finger vein are acquired from the hand for recognition. Rigorous experiments had been performed to testify the robustness of the system.  相似文献   
119.
In order to reduce the overall wavelength number required in a wavelength division multiplexing (WDM) network with static traffic loading, new heuristic algorithms for wavelength assignment are proposed in this paper. A new parameter called one-wavelength-decrease cost is defined and used to compare the efficiency of these algorithms. Comparative simulation studies have been carried out for various network topologies to investigate the effectiveness of the proposed algorithms.  相似文献   
120.
This paper describes the modeling, design, and fabrication of quarter-micrometer double delta-doped AlGaAs/InGaAs charge-coupled devices (CCDs) whose epitaxial layers and geometry were based around the device structure of commercial pHEMTs. A quasi-2-D physical model has been developed to investigate the properties of this novel 2-D electron gas CCD. This physical model allows the characteristics of the InGaAs transport channel as well as the dc characteristics of the device to be predicted within a reasonable amount of time. This model also shows how "individual" charge packets can be controllably transferred through the device when appropriate clocking voltages are applied to the gates of the CCD. This capacitive gate structure device is then shown to be successfully fabricated using established GaAs heterostructure fabrication techniques to ensure good repeatability. The dc characteristics of the fabricated CCD delay line are included.  相似文献   
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