Novel application of reactive blending: tailoring morphology of PBT/SAN blends

Reactive blending has been usually utilized to stabilize morphology and to improve the properties of multi-component polymer blends by generating copolymers in situ at the interface. However, the present study on blends composed of poly(butylene terephthalate) (PBT) and functionalized styrene-acrylonitrile random copolymer (SAN) demonstrates another possibility for this method, i.e. tailoring morphology and thereby controlling the properties of polymer blends. By varying reaction conditions it was demonstrated that blends could be formed having the same ratio of [PBT]/[SAN] but which possessed completely different microstructural forms: a sea-island morphology with and without micelles, a corded dispersed phase morphology, and a highly oriented, layer-like morphology.     

Effect of micro ploughing during fine particle peening process on the microstructure of metallic materials

In this study, the mechanism of microstructural changes induced by fine particle peening (FPP) treatment was analyzed. Ti–6Al–4V alloy specimens treated with FPP, using tool steel particles with a peening time ranging from 0.1 to 30 s were prepared and examined. Observation of the specimen with short-term FPP treatment revealed that two types of collision dents were formed by the micro abrasive behavior between collided particles and specimen surface. One was the “indented dent,” formed by particles that collided with the surface vertically, and the other was the “ploughed dent,” accompanied by a heap of piled-up material that was ploughed aside during the formation of this dent. Analyses using energy dispersive X-ray spectroscopy (EDS) revealed the presence of particle fragments transferred to the ploughed dents, although no fragments were observed on the indented dents. With an increase in peening time, transferred fragments were embedded into treated materials by deformed material due to a micro ploughing effect. The Fe-rich region became deeper as the particle fragments were embedded. Finally, a lamellar microstructure with a high concentration of Fe was formed by FPP treatment. The effects of micro ploughing during the FPP process on the lamellar modified microstructure formation were clarified. One effect was an enhancement of metal transfer from particles to substrate because virgin metallic surface was exposed; and the other was the mechanical mixing of transferred elements into the substrate.     

Spatial localization of stress-perturbing wave generated by anelectromagnetic acoustic transducer

A new apodization of electromagnetic acoustic transducer has been proposed to generate the stress perturbing wave, which has a spatially localized magnitude distribution. According to the acoustoelastic effect, a stress perturbing wave radiated into metals gives rise to an ultrasound velocity change that corresponds to the deviation of the stress in the metal. In ultrasonic measurements, it is desirable to use a narrow beam in order to obtain a high resolution. A transducer has been constructed which has a Sinc function apodization. To compare with other types of electromagnetic acoustic transducers, including a Limited Bessel-type transducer, numerical simulations are performed. It is shown that the proposed transducer provides the optimum characteristics of the spatially localized magnitude distribution. Furthermore, experimental results are presented to confirm the numerical predictions     

TiO2 thin films using organic liquid materials prepared by Hot-Wire CVD method

TiO₂ thin films prepared by Hot-Wire CVD method have been studied as a protecting material of transparent conducting oxide (TCO) against atomic hydrogen exposures for the fabrications of Si thin film solar cells. It was found that electrical conductivity of the films at room temperature reached a value of 0.4 S/cm. This value is 2-3 orders of magnitude higher than that of TiO₂ films prepared by RF magnetron sputtering and electron-beam evaporation methods in our previous works. The conductivity improvement seems to be partly due to the enlargement of TiO₂ crystallites.     

Crystal orientation of poly(?-caprolactone) blocks confined in crystallized polyethylene lamellar morphology of poly(?-caprolactone)-block-polyethylene copolymers

The crystal orientation of poly(?-caprolactone) (PCL) blocks in PCL-block-polyethylene (PE) copolymers has been investigated using two-dimensional small-angle X-ray scattering (2D-SAXS) and 2D wide-angle X-ray diffraction (2D-WAXD) as a function of crystallization temperature T_c and thickness of PCL layers d_PCL. The PCL blocks were spatially confined in the solid lamellar morphology formed by the crystallization of PE blocks (PE lamellar morphology), an alternating structure of crystallized PE lamellae and amorphous PCL layers. This confinement is expected to be intermediate between hard confinement by glassy lamellar microdomains and soft confinement by rubbery ones, because the crystallized PE lamellae consist of hard PE crystals covered with amorphous (or soft) PE blocks. The 2D-SAXS results showed uniaxial orientation of the PE lamellar morphology after applying the rotational shear to the sample. Therefore, it was possible to investigate crystal orientation of PCL blocks within the oriented PE lamellar morphology. The 2D-WAXD results revealed that the c axis of PCL crystals (i.e., stem direction of PCL chains) was parallel to the lamellar surface normal irrespective of T_c when 16.5 nm ≥ d_PCL ≥ 10.7 nm. However, it changed significantly with changing T_c when d_PCL = 8.8 nm; the c axis was perpendicular to the lamellar surface normal at 45 °C ≥ T_c ≥ 25 °C while it was almost random at 20 °C ≥ T_c ≥ 0 °C. These results suggest that the PE lamellar morphology plays a similar role to glassy lamellar microdomains regarding spatial confinement against subsequent PCL crystallization.     

The Impact of Duodenal Mucosal Vulnerability in the Development of Epigastric Pain Syndrome in Functional Dyspepsia

An unidentified cause of functional dyspepsia (FD) is closely associated with medication resistance. Acid suppression is a traditional and preferential method for the treatment of FD, but the efficacy of this treatment varies between epigastric pain syndrome (EPS) and postprandial syndrome (PDS): it is efficient in the former but not much in the latter. Transepithelial electrical resistance (TEER), a surrogate of mucosal barrier function, was measured under pH 3 and pH 5 acidic conditions using duodenal biopsy specimens obtained from the patients with EPS and PDS and asymptomatic healthy controls. The infiltration of inflammatory cells to the duodenal mucosa was accessed by immunohistochemical analysis. The duodenal mucosal TEER in EPS patients was decreased by exposure to the acidic solution compared to that of the controls and the PDS patients. The decrease in TEER of the EPS patients was observed even under pH 5 weak acidic condition and was correlated to degree of the epigastric pain. Moreover, the duodenal mucosa of EPS patients presented an increase in mast cells and plasma cells that expressed Ig-E. Duodenal mucosal vulnerability to acid is likely to develop EPS.     

A stochastic method to predict the consequence of arbitrary forms of spike-timing-dependent plasticity

Synapses in various neural preparations exhibit spike-timing-dependent plasticity (STDP) with a variety of learning window functions. The window functions determine the magnitude and the polarity of synaptic change according to the time difference of pre- and postsynaptic spikes. Numerical experiments revealed that STDP learning with a single-exponential window function resulted in a bimodal distribution of synaptic conductances as a consequence of competition between synapses. A slightly modified window function, however, resulted in a unimodal distribution rather than a bimodal distribution. Since various window functions have been observed in neural preparations, we develop a rigorous mathematical method to calculate the conductance distribution for any given window function. Our method is based on the Fokker-Planck equation to determine the conductance distribution and on the Ornstein-Uhlenbeck process to characterize the membrane potential fluctuations. Demonstrating that our method reproduces the known quantitative results of STDP learning, we apply the method to the type of STDP learning found recently in the CA1 region of the rat hippocampus. We find that this learning can result in nearly optimized competition between synapses. Meanwhile, we find that the type of STDP learning found in the cerebellum-like structure of electric fish can result in all-or-none synapses: either all the synaptic conductances are maximized, or none of them becomes significantly large. Our method also determines the window function that optimizes synaptic competition.     

THE EFFECTS OF STRESS RATIO ON THE GROWTH BEHAVIOUR OF SMALL FATIGUE CRACKS IN AN ALUMINUM ALLOY 7075-T6 (WITH SPECIAL INTEREST IN STAGE I CRACK GROWTH)

Abstract— The growth behaviour of small fatigue cracks has been investigated on aluminum alloy 7075-T6 at stress ratios R of 0, −1 and −2. The effects of stress ratio are discussed with special interest in the stage I region of small crack growth. Cracks which initiated at R =−1 and −2, grew by a stage I mechanism up to a certain depth followed by stage II crack growth. The stage I to stage II transition occurred under a constant maximum stress intensity factor which was approximately consistent with the threshold effective stress intensity range, λ K _eff,th, for large cracks. At R = 0, on the other hand, stage I crack growth was not observed because of crack initiation at inclusions. Small cracks grew more rapidly than large cracks subjected to the same nominal stress intensity ranges at all the stress ratios, and they grew below the threshold stress intensity range, λ K _th, for large cracks. Stage I cracks, in particular, showed much higher growth rates than large cracks and grew even below λ K _eff,th. It is suggested that stage II crack growth rates should be characterized in terms of an effective stress intensity range, while a micromechanics approach will be necessary to evaluate stage I crack growth rates.     

Ion beam modification of TiO2 films prepared by Cat-CVD for solar cell

The effects of nitrogen ion bombardment on TiO₂ films prepared by the Cat-CVD method have been studied to improve the optical and electrical properties of the material for use in Si thin film solar cells. The refractive index n and the dark conductivity of the TiO₂ film increased with irradiation time. The refractive index n of the TiO₂ film was changed from 2.1 to 2.4 and the electrical conductivity was improved from 3.4 × 10^− 2 to 1.2 × 10^− 1 S/cm by the irradiation. These results are due to the formation of Ti-N bonds and oxygen vacancies in the film.