N-Fe共掺杂BiVO_4的制备及其光催化活性的研究

采用溶胶凝胶法制备了N和Fe共掺杂的Bi VO4可见光光催化剂,并用X射线衍射(XRD)、比表面积测试(BET)和紫外-可见漫反射谱(UV-Vis DRS)对其进行了表征.结果显示,N-Fe共掺杂对Bi VO4晶型没有产生影响,掺杂前后均为单斜晶系,但晶粒粒径有所减小,BET比表面积相对增大.由UV-Vis可知,N-Fe共掺杂的Bi VO4的吸光强度明显增强,禁带宽度变窄.以可见光降解甲基橙(MO)考察催化剂的光催化活性,N-Fe共掺杂的Bi VO4对MO的降解速率明显高于纯Bi VO4,证明N-Fe共掺杂产生的协同效应提高了Bi VO4在可见光照射下的光催化活性.     

电动汽车跨区域充换电计量计费清分结算研究

为确保电动汽车跨区域充换电顺利完成电费结算,研究了跨区域充换电的交易流程,并提出一种成本清分和收入清分的方法,并建立了运营商运营成本模型和客户支付充换电的费用单价模型.在此基础上,设计开发了一套清分结算系统,并对上述两个模型的实用性加以论证,为实施跨区域充换电提供参考.     

活性粉末混凝土微观层面的研究进展

作为新型水泥基复合材料,活性粉末混凝土具有高强度,高韧性以及高耐久性等优异性能,在桥梁与路面工程、建筑工程、水利工程和特种结构等领域拥有广阔的应用前景.但由于组成中活性组分多,内部结构复杂,微观机理研究尚不够明确,难以为材料的宏观性能提供明确的理论依据.介绍了活性粉末混凝土的基本组成、各组分产生的反应及影响因素,总结了国内外学者对活性粉末混凝土微观形貌及孔结构等的研究成果,更进一步地提出了现阶段微观层面研究和材料本身所存在的问题,指出了发展趋势,并进行了分析和讨论.     

相邻锅炉一次热风联络技术在CFB锅炉上的应用

针对循环流化床锅炉冷态启动用油量较大的问题,采用两台相邻锅炉一次热风风道联络的方法,实践中利用邻炉一次热风进行锅炉冷态启动,以煤代油缩短锅炉点火投油时间。结果表明:此方法使锅炉冷态启动时的用油量大幅下降,达到了显著的节能效果,并在此基础上展望了一次热风联络技术在锅炉防腐保养、冬季防冻等方面的应用前景。     

A Fully Differential Interface Circuit of Closed-loop Accelerometer with Force Feedback Linearization

In this paper,a fifth-order fully differential interface circuit（ IC） is presented to improve the noise performance for micromechanical sigma-delta（ Σ-Δ） accelerometer. A lead compensator is adopted to ensure the stability of the closed-loop high-order system. A low noise capacitance detection circuit is described with a correlated-double-sampling（ CDS） technique to decrease 1 /f noise and offset of the operational amplifier. This paper also proposes a self-test technique for the interface circuit to test the harmonic distortion. An electrostatic force feedback linearization circuit is presented to reduce the harmonic distortion resulting in larger dynamic range（ DR）. The layout of the IC is implemented in a standard 0. 6 μm CMOS technology and operates at a sampling frequency of 250 kHz. The interface consumes 20 mW from a 5 V supply. The post-simulation results indicate that the noise floor of the digital accelerometer is about- 140 dBV /Hz1 /2at low frequency. The sensitivity is 2. 5 V /g and the nonlinearity is 0. 11%. The self-test function is achieved with 98. 2 dB thirdorder harmonic distortion detection based on the electrostatic force feedback linearization.     

球磨损伤处理对土豆淀粉糊性质的影响

利用球磨对土豆淀粉进行损伤处理,研究球磨损伤对土豆淀粉糊性质的影响.研究发现:随着球磨时间的增加,土豆淀粉的损伤淀粉含量升高,且不同损伤时间的差异性显著,溶解度和膨润力呈现上升趋势;糊化特性的测定显示土豆淀粉的峰值黏度、谷值黏度、最终黏度、回生值和糊化温度都随着球磨处理时间的延长而降低;球磨对土豆淀粉的凝胶特性也有一定的影响;随着淀粉损伤程度的增加,土豆淀粉的To、Tp、Tc和ΔH均有下降趋势.     

Fourier transform infrared (FTIR) authentication and batch-to-batch consistency for different types of paints using benchtop and handheld FTIR spectrophotometers for oil and gas industry

Standardization of Fourier transform infrared (FTIR) fingerprint region for paints and assessment on the reproducibility using different spectrophotometers were investigated. While selective fingerprint regions may be confusing for technicians/analysts who are non-chemists, we attempt to generalize these regions (e.g., 1300–1000 cm⁻¹ for Epoxy part A and 1400–1000 cm⁻¹ for Epoxy part B) by choosing a universal region (2000–900 cm⁻¹) that works for different paints. Comparison result using a paired student t-test shows that the degree of similarity (r) values from the studied regions are not statistically different. The paint fails the screening analysis occasionally on-site when analyzed using handheld FTIR due to the higher level of noise that gives low r values (r < 0.900 ± 0.002). The same samples were analyzed using a benchtop FTIR and the r values are above 0.900 ± 0.002. While the screening may lead to a false rejection of the sample on-site, there could be occurrence of false acceptance. The on-site screening of EPZ part A with different formulations, for instance, shows that the r values over the entire IR spectrum are above 0.900 ± 0.002 when analyzed using handheld FTIR. After the samples were analyzed using the benchtop, the r values fall below 0.900 ± 0.002.     

一例1000kV单相自耦变压器局部放电故障的诊断与分析

分析了一台1000kV单相自耦变压器局放试验图谱与数据,通过吊罩解体检查发现了故障部位,并对后续此类产品试验过程中的注意事项提出建议.     

大型现场组装换流变的铁心制作

本文中作者阐述了大型现场组装换流变铁心制作过程中的特殊性和难点,介绍了换流变铁心制作过程中的关键过程及工艺措施.     

SF6密度校验及自动充放一体化装置的研制

SF6密度继电器是监视变电站组合电器SF6实时压力的唯一设备,当表计指针处于额定值但发出报警或闭锁信号时,无法正确判断气室内的真实压力,也无法判断是表计指针卡涩故障还是信号接点异常;当表计指针处于报警或闭锁值时发出信号,无法判断气室压力是确已降低还是表计损坏引起误报警.为此,研制了SF6密度校验及自动充放一体化装置,可在系统发出报警或闭锁信号时校验气室的实际压力,同时免拆卸对原有表计进行读数校验,避免气室压力过低导致断路器闭锁引起事故扩大;在气室充放气体时,压力到达预设值即自动停止,从而消除手动误差,提高了电力系统GIS设备的可靠性,保证电网的安全稳定运行.