Corrosion of aluminium nitride substrates in acid,alkaline solutions and water

Aluminium nitride substrates were immersed in acid, basic solutions and deionized water for 1–120 h at room temperature. The corrosion rates are higher in basic solutions (NaOH and KOH) than those in acid solutions (CH₃COOH, HCOOH, HNO₃, HCl and H₂SO₄) and deionized water. The weight loss of AIN corroded in alkali aqueous reaches 70% and results in an increase in surface roughness ranging from 10 nm to 7 m after 3 days corrosion. However, the weight loss in acid solution is only 1/700 of the alkali case. Violent chemical reactions between AIN and basic solutions were observed. Na₂O, or Na₂Al₂O₄·6H₂O, is the intermediate product, and NaOH is a catalytic agent of the reaction. The surface morphology of the AIN etched by alkaline solutions is coral-like in microscopic view and appears like hills. In contrast, only several atomic layers of AIN surface are etched off in acid solutions and in deionized water. The lightly etched surface is mirror-like and flat, and the shapes of the grains are visible under the microscope, as the corrosion rate of each AIN grain varies with different crystal orientations. Consequently, after etching in acid solutions, the resulting microscopic surface morphology looks like a map of a jigsaw puzzle.     

Metal Ions versus Protons: Tracking of Charge-Carrier Insertion into a Cathode Oxide in Aqueous Rechargeable Batteries

Protons in aqueous electrolytes can perform as an additional type of charge carrier for insertion/extraction in addition to the primary carrier cations in aqueous rechargeable batteries. Despite many diverse claims regarding the effect of protons, mutually conflicting experimental results and their interpretations without direct evidence have been reported over the last decade. Systematic examinations and analyses are thus imperative to clarify the conditions of proton insertion in aqueous rechargeable batteries. Utilizing V₂O₅ as a model cathode and beaker-type cells with a sufficient amount of ZnSO₄ aqueous electrolytes in this work, it is demonstrated that protons are inserted into the cathode prior to Zn-ions in low-pH conditions (pH ≤ 3.0). In stark contrast, the influence of protons on the discharge voltage and capacity is insignificant, when either the pH becomes higher (pH ≥ 4.0) or the electrolyte volume is considerably low in coin-type cells. Similar behavior of pH-dependent proton insertion is also verified in Na–, Mg–, and Al-ion electrolytes. Providing a resolution to the controversy regarding proton insertion, the present study emphasizes that the influence of protons substantially varies depending on the pH and relative volume of electrolytes in aqueous batteries.     

Portable and Efficient Implementation of CRYSTALS-Kyber Based on WebAssembly

With the rapid development of quantum computers capable of realizing Shor’s algorithm, existing public key-based algorithms face a significant security risk. Crystals-Kyber has been selected as the only key encapsulation mechanism (KEM) algorithm in the National Institute of Standards and Technology (NIST) Post-Quantum Cryptography (PQC) competition. In this study, we present a portable and efficient implementation of a Crystals-Kyber post-quantum KEM based on WebAssembly (Wasm), a recently released portable execution framework for high-performance web applications. Until now, most Kyber implementations have been developed with native programming languages such as C and Assembly. Although there are a few previous Kyber implementations based on JavaScript for portability, their performance is significantly lower than that of implementations based on native programming languages. Therefore, it is necessary to develop a portable and efficient Kyber implementation to secure web applications in the quantum computing era. Our Kyber software is based on JavaScript and Wasm to provide portability and efficiency while ensuring quantum security. Namely, the overall software is written in JavaScript, and the performance core parts (secure hash algorithm-3-based operations and polynomial multiplication) are written in Wasm. Furthermore, we parallelize the number theoretic transform (NTT)-based polynomial multiplication using single instruction multiple data (SIMD) functionality, which is available in Wasm. The three steps in the NTT-based polynomial multiplication have been parallelized with Wasm SIMD intrinsic functions. Our software outperforms the latest reference implementation of Kyber developed in JavaScript by ×4.02 (resp. ×4.32 and ×4.1), ×3.42 (resp. ×3.52 and ×3.44), and ×3.41 (resp. ×3.44 and ×3.38) in terms of key generation, encapsulation, and decapsulation on Google Chrome (resp. Firefox, and Microsoft Edge). As far as we know, this is the first software implementation of Kyber with Wasm technology in the web environment.     

Environmental Hydrogen Embrittlement of G41400 and G43400 Steel Bolting in Atmospheric Versus Immersion Services

This article is based on a review of data in the literature and those released by the California Department of Transportation and reported by the Bureau of Safety and Environmental Enforcement (BSEE). In 2013, hot dip galvanized (HDG) threaded rods failed due to environmental hydrogen embrittlement (EHE) cracking on the San Francisco–Oakland Bay Bridge. These rods were made of G41400 steel, conforming to ASTM A354 Grade BD (39 HRC max). All 32 EHE failures occurred in the bottom threads that had been immersed in pools of water, inadvertently, under no stress, for over four years before they were pretensioned. Several failure analysis reports stated that they failed due to EHE cracking because they were pretensioned while being immersed in water. This is erroneous, however, because one or more of the failed rods were not immersed in water during pretensioning and afterward. Conversely, hydrogen from metal corrosion of the HDG BD rods can diffuse into them under no stress while corroding in standing water for several years. The EHE cracking occurred when subsequently pretensioned. None of about 4000 threaded ends of HDG BD rods that have been exposed only to marine atmosphere (but not immersed in water) has failed in three to four years in service under a pretension load. These data are compared with recent EHE cracking of G43400 bolting in subsea oil production facilities in the Gulf of Mexico, reported by the BSEE.

     

Redox and pH Dual Responsive Polymer Based Nanoparticles for In Vivo Drug Delivery

Responsive nanomaterials have emerged as promising candidates as drug delivery vehicles in order to address biomedical diseases such as cancer. In this work, polymer‐based responsive nanoparticles prepared by a supramolecular approach are loaded with doxorubicin (DOX) for the cancer therapy. The nanoparticles contain disulfide bonds within the polymer network, allowing the release of the DOX payload in a reducing environment within the endoplasm of cancer cells. In addition, the loaded drug can also be released under acidic environment. In vitro anticancer studies using redox and pH dual responsive nanoparticles show excellent performance in inducing cell death and apoptosis. Zebrafish larvae treated with DOX‐loaded nanoparticles exhibit an improved viability as compared with the cases treated with free DOX by the end of a 3 d treatment. Confocal imaging is utilized to provide the daily assessment of tumor size on zebrafish larva models treated with DOX‐loaded nanoparticles, presenting sustainable reduction of tumor. This work demonstrates the development of functional nanoparticles with dual responsive properties for both in vitro and in vivo drug delivery in the cancer therapy.     

Carbon Nanodot‐Sensitized Modulation of Alzheimer's β‐Amyloid Self‐Assembly,Disassembly, and Toxicity

The self‐assembly of amyloidogenic peptides into β‐sheet‐rich aggregates is a general feature of many neurodegenerative diseases, including Alzheimer's disease, which signifies the need for the effective attenuation of amyloid aggregation toward alleviating amyloid‐associated neurotoxicity. This study reports that photoluminescent carbon nanodots (CDs) can effectively suppress Alzheimer's β‐amyloid (Aβ) self‐assembly and function as a β‐sheet breaker disintegrating preformed Aβ aggregates. This study synthesizes CDs using ammonium citrate through one‐pot hydrothermal treatment and passivates their surface with branched polyethylenimine (bPEI). The bPEI‐coated CDs (bPEI@CDs) exhibit hydrophilic and cationic surface characteristics, which interact with the negatively charged residues of Aβ peptides, suppressing the aggregation of Aβ peptides. Under light illumination, bPEI@CDs display a more pronounced effect on Aβ aggregation and on the dissociation of β‐sheet‐rich assemblies through the generation of reactive oxygen species from photoactivated bPEI@CDs. The light‐triggered attenuation effect of Aβ aggregation using a series of experiments, including photochemical and microscopic analysis, is verified. Furthermore, the cell viability test confirms the ability of photoactivated bPEI@CDs for the suppression of Aβ‐mediated cytotoxicity, indicating bPEI@CDs' potency as an effective anti‐Aβ neurotoxin agent.     

Delignification kinetics of empty fruit bunch (EFB): a sustainable and green pretreatment approach using malic acid-based solvents

Recently, the development of efficient and environmentally benign solvents has received great attention to replace current harsh organic solvents. In this context, low-transition-temperature mixtures (LTTMs) have emerged as favorable green solvents for biomass delignification. Palm oil biomass, empty fruit bunch (EFB) was pretreated with commercial l-malic acid and microwave hydrothermally extracted cactus malic acid-derived LTTMs at 60, 80, and 100 °C. The LTTMs applied in this study were derived from malic acid–choline chloride–water and malic acid–monosodium glutamate–water with a molar ratio of 2:4:2 and 3:1:5, respectively. Three first-order reactions were used to express the delignification kinetic model of EFB. The first term was based on the initial stage and assigned as infinite due to the fast rate of delignification which could not be detected. The second and third terms were proportional to bulk and residual delignification stages. A good agreement was obtained between the kinetic model and the experimental data obtained in this study with R²?≥?0.91. The activation energies for the delignification reactions using l-malic acid and cactus malic acid-based LTTMs in the bulk and residual stages were approximated as 36–56 and 19–26 kJ/mol and 34–90 and 47–87 kJ/mol, respectively.