A benchmark on the calculation of kinetic parameters based on reactivity effect experiments in the CROCUS reactor

Measurements in the CROCUS reactor at EPFL, Lausanne, are reported for the critical water level and the inverse reactor period for several different sets of delayed supercritical conditions. The experimental configurations were also calculated by four different calculation methods. For each of the supercritical configurations, the absolute reactivity value has been determined in two different ways, viz.: (i) through direct comparison of the multiplication factor obtained employing a given calculation method with the corresponding value for the critical case (calculated reactivity: ρ_calc); (ii) by application of the inhour equation using the kinetic parameters obtained for the critical configuration and the measured inverse reactor period (measured reactivity: ρ_meas). The calculated multiplication factors for the reference critical configuration, as well as ρ_calc for the supercritical cases, are found to be in good agreement. However, the values of ρ_meas produced by two of the applied calculation methods differ appreciably from the corresponding ρ_calc values, clearly indicating deficiencies in the kinetic parameters obtained from these methods.     

Simulation and experimental analyses of electromagnetic transients behaviors of lightning surge on vertical conductors

Simulation of very fast surge phenomena in a three-dimensional (3-D) structure requires a method based on Maxwell's equations, such as the finite-difference time-domain (FDTD) method or the method of moments, because circuit-equation-based methods cannot handle the phenomena. This paper uses a method of thin-wire representation of the vertical conductor system for the FDTD method which is suitable for the 3-D surge simulation. The thin-wire representation is indispensable to simulate electromagnetic surges on wires or steel frames in which the radius is smaller than a discretized space step used in the FDTD simulation. In this paper, a general surge analysis program named the virtual surge test lab based on the Maxwell's equations formulated by the FDTD method, is used to simulate the surge phenomena of a vertical conductor, including the effects of horizontal wave incidence and vertical wave incidence. Experimental results on the reduced scale model have been presented in order to compare among the simulation results by the FDTD method and the results using numerical electromagnetic code based on the MoM.     

Mechanical and microstructure studies on the modification of CA film by blending with PS

DriedMusa paradiciaca (banana) stem and veins of the leaves, which were hitherto discarded as a waste, were collected and used as starting material for the preparation of cellulose and cellulose acetate. This cellulose acetate was mixed with polystyrene to form blend of cellulose acetate-polystyrene in order to provide enhanced stability and extended utility to the end products. The films of these composites or their individual partners were made separately and studied for their mechanical properties, chemical modification and morphological changes. We report here that banana stem is good source of cellulose and that cellulose completely undergoes modification upon esterification.     

Mössbauer spectroscopic studies of Fe-substituted YIG

Compositional dependence of hyperfine parameters, determined through Mössbauer spectral analysis has been studied for Y_3−xFe_5+xO₁₂ (x = 0.0, 0.1, 0.3 and 0.5) garnet system at 300 K. The Mössbauer spectra have been fitted with three sextets in the ferrimagnetic state corresponding to Fe³⁺ ions at tetrahedral (d), octahedral (a) and dodecahedral (c) sites of the crystal structure. It is observed that isormershift, quadrupole shift and hyperfine field of d-site show no significant variation with Fe³⁺ concentration. The change in hyperfine fields of a- and c-sites with composition (x) has been explained on the basis of strength of exchange integrals, change in isomershift can be understood due to s-electron charge distribution and asymmetric displacement of oxygen ions surrounding the a- and c-sites seems to be responsible for observable quadrupole shift. The magneton number values obtained from magnetization and Mossbauer data are in agreement to those calculated using Neel's three sublattice model of ferrimagnetism.     

Investigation of the geothermal anomaly of Travale (Tuscany) by telluric, magnetotelluric and geomagnetic deep sounding measurements

As part of the European Community research programme telluric, magnetotelluric and geomagnetic deep sounding measurements were undertaken at 40 sites within the geothermal area of Travale. In the period range of 6–10,000 s the telluric field inside the Travale graben is strongly polarized and directed, independent of the period, about parallel to the graben strike. The lateral variation of the telluric field amplitude is determined mainly by the distribution of the rocks (e.g. the central part of the geothermal anomaly inside the graben is correlated with a horst structure of resistive rocks) and an influence of the geothermal anomaly on the telluric field distribution cannot be observed. The apparent resistivity, as well as the phase curves, are rather similar at all sites within the graben, exhibiting 4–40 ohm · m for periods of 10 s and 50–500 ohm · m for periods of 10,000 s in E-polarization. In the period range of 10–100 s the E- and B-polarization of magnetotelluric measurements can be interpreted by the 2-D effect of the Travale graben, while with increasing period the induced current system becomes more and more 3-D below all sites. This limits the determination of the sedimentary cover thickness (max. 2500 m) by 1-D and 2-D model calculations to periods of less than 100 s.     

The microscopy cell (MicCell), a versatile modular flowthrough system for cell biology, biomaterial research, and nanotechnology

We describe a novel microfluidic perfusion system for high-resolution microscopes. Its modular design allows pre-coating of the coverslip surface with reagents, biomolecules, or cells. A poly(dimethylsiloxane) (PDMS) layer is cast in a special molding station, using masters made by photolithography and dry etching of silicon or by photoresist patterning on glass or silicon. This channel system can be reused while the coverslip is exchanged between experiments. As normal fluidic connectors are used, the link to external, computer-programmable syringe pumps is standardized and various fluidic channel networks can be used in the same setup. The system can house hydrogel microvalves and microelectrodes close to the imaging area to control the influx of reaction partners. We present a range of applications, including single-molecule analysis by fluorescence correlation spectroscopy (FCS), manipulation of single molecules for nanostructuring by hydrodynamic flow fields or the action of motor proteins, generation of concentration gradients, trapping and stretching of live cells using optical fibers precisely mounted in the PDMS layer, and the integration of microelectrodes for actuation and sensing.     

A frame-based knowledge representation model and its mapping to nested relations

The first part of this paper introduces the basic constructs of a frame representation model and gives a formal definition for them. Subsequently the nested relational model (NF²) is described as an extension of the classical relational model to support relation-valued attributes. In the second part of this paper both models are compared with each other and a mapping of frame representation structures to NF² structures is specified. The structural similarities between frames and NF² relations are made clear and it is shown that their main difference is due to the type polymorphism introduced by the concept hierarchy of the frame model. This causes type collisions to occur in the strictly typed NF² model when frames are directly mapped to NF² structures. Two solutions to this problem are suggested and compared. The paper concludes with a reformulation of query operations of the frame model in terms of NF² algebra operations.     

A dynamic linear programming approach to market allocation of renewable resources in the italian energy system: The case of solar thermal and biogas technologies

In Italy solar thermal energy and energy from biogas are two possible means of reducing dependence on energy imports. Using a multiperiod LP model (MARKAL) the authors assessed the likely potential of both technologies under various circumstances. The study covered the period 1980–2005, in five segments of five years. It focused only on the subsystem of the energy end-uses which can be substituted for by solar thermal and biogas technologies. The overall non-renewable sources which can be saved in 20 years by these technologies total 450 PJ (1 PJ = 10^{1 5} J) if the fuel prices rise at 0 per cent average annual, 1450 PJ if the fuel prices rise at 4.2 per cent average annual, 1860 PJ if the fuel prices rise at 7.2 per cent average annual and 3780 PJ if the fuel prices rise at 15 per cent average annual. However the most competitive technologies appear to be solar water heaters used mainly in the private and commercial sectors and biogas systems used mainly in the agricultural sector. The study was carried out by APRE under ENEA (formerly CNEN) contract and was intended to serve as an analytical basis for establishing an overall development and demonstration strategy for end-use renewable technologies in Italy.     

Compensation of the Piezo-Hall Effect in Integrated Hall Sensors on (100)-Si

Silicon Hall sensors are known to suffer from a long-term drift in the magnetic sensitivity between 1% and 4%, depending on the degree of moisture in the mold compound of the package. This drift is mainly caused by changes of mechanical stress exerted by the plastic package onto the die. We present a system, which continuously measures the relevant stress components, estimates the sensitivity drift, and corrects for it digitally. An individual precalibration versus temperature is necessary to achieve the required level of accuracy. Results from laboratory characterization with pressure cells and lifetime drift during qualification runs show that this system can keep the drift of magnetic sensitivity well below 1%.