Dot Size Thermal Objects Detection in Atmosphere of Infrared Range

The article deals with the experimental studies of atmosphere indistinct radiation structure. The information extraction background of dot size thermal object presence in atmosphere is reasonable. Indistinct generalization of experimental study regularities technique of space-time irregularity radiation structure in infrared wave range is offered. The approach to dot size thermal object detection in atmosphere is proved with a help of threshold method in the thermodynamic and turbulent process conditions, based on the indistinct statement return task solution.     

Deformation Control During Thermal Treatment of Electrospun PbZr0.52Ti0.48O3 Nanofiber Mats

This paper focuses on the deformation origin of PbZr_0.52Ti_0.48O₃ (PZT) fiber mats obtained by electrospinning. The main cause of deformation of the green mats during heating was found to be a nonuniform relaxation of the stretched PVP polymer, due to nonuniform thermal decomposition of the Pb‐hexanoate in the fibers. This relaxation starts under 100°C, well below the polymer decomposition temperature. The shrinkage was found to accelerate above the polymer glass transition point, giving rise to an overall linear change of almost 50%. The “green” PZT mats were easily separated from the collector by first depositing a pure PVP sublayer on the collector. An optimal fabrication and slow multistep thermal treatment process that provides fiber mats with desired PZT phase and overcomes the nonuniform deformation is described.     

Asymptotically Efficient Lattice-Based Digital Signatures

We present a general framework that converts certain types of linear collision-resistant hash functions into one-time signatures. Our generic construction can be instantiated based on both general and ideal (e.g., cyclic) lattices, and the resulting signature schemes are provably secure based on the worst-case hardness of approximating the shortest vector (and other standard lattice problems) in the corresponding class of lattices to within a polynomial factor. When instantiated with ideal lattices, the time complexity of the signing and verification algorithms, as well as key and signature size, is almost linear (up to poly-logarithmic factors) in the dimension n of the underlying lattice. Since no sub-exponential (in n) time algorithm is known to solve lattice problems in the worst case, even when restricted to ideal lattices, our construction gives a digital signature scheme with an essentially optimal performance/security trade-off.     

Peptide structure stabilization by membrane anchoring and its general applicability to the development of potent cell-permeable inhibitors

Isolated protein motifs that are involved in interactions with their binding partners can be used to inhibit these interactions. However, peptides corresponding to protein fragments tend to have no defined secondary or tertiary structure in the absence of scaffolding by the rest of protein molecule. This results in low inhibitor potency. NMR and CD spectroscopy studies of lipopeptide inhibitors of the Hedgehog pathway revealed that membrane anchoring allows the cell membrane to function as a scaffold and facilitate the folding of short peptides. In addition, lipidation enhances cell permeability and increases the concentration of the compounds near the membrane, thus facilitating potent inhibition. The general applicability of this rational approach was further confirmed by the generation of selective antagonists of the insulin-like growth factor 1 receptor with GI(50) values in the nanomolar range. Lipopeptides corresponding to protein fragments were found to serve as potent and selective inhibitors of a number of nondruggable molecular targets.     

Propane Ammoxidation Over the Mo�CV�CTe�CNb�CO M1 Phase: Reactivity of Surface Cations in Hydrogen Abstraction Steps

Density functional theory calculations (GGA-PBE) have been performed to investigate the adsorption of C₃ (propane, isopropyl, propene, and allyl) and H species on the proposed active center present in the surface ab planes of the bulk Mo?CV?CTe?CNb?CO M1 phase in order to better understand the roles of the different surface cations in propane ammoxidation. Modified cluster models were employed to isolate the closely spaced V=O and Te=O from each other and to vary the oxidation state of the V cation. While propane and propene adsorb with nearly zero adsorption energy, the isopropyl and allyl radicals bind strongly to V=O and Te=O with adsorption energies, ??E, being ???1.75 eV, but appreciably more weakly on other sites, such as Mo=O, bridging oxygen (Mo?CO?CV and Mo?CO?CMo), and empty metal apical sites (??E > ?1 eV). Atomic H binds more strongly to Te=O (??E ?? ?3 eV) than to all the other sites, including V=O (??E = ?2.59 eV). The reduction of surface oxo groups by dissociated H and their removal as water are thermodynamically favorable except when both H atoms are bonded to the same Te=O. Consistent with the strong binding of H, Te=O is markedly more active at abstracting the methylene H from propane (E _a  ?? 1.01 eV) than V=O (E _a  = 1.70 eV on V⁵⁺=O and 2.13 eV on V⁴⁺=O). The higher-than-observed activity and the loose binding of Te=O moieties to the mixed metal oxide lattice of M1 raise the question of whether active Te=O groups are in fact present in the surface ab planes of the M1 phase under propane ammoxidation conditions.