Critical state behaviour of granular materials from isotropic and rebounded paths: DEM simulations

This paper presents the results of numerical simulations using the three-dimensional discrete element method (DEM) on the critical state behaviour of isotropically compressed and rebounded assemblies of granular materials. Drained and undrained (constant volume) numerical simulations were carried out. From these numerical simulations of drained and undrained tests, it has been shown that the steady state is same as the critical state. Critical state for both isotropically compressed and rebounded assemblies form unique curved line that can be approximated by a bilinear line as proposed by Been et al. [Géotechnique 41(3): 365–381, 1991]. Further more, evolution of the internal variables such as average coordination number and induced anisotropy coefficients during shear deformation has been studied.     

Optimization of nitrilase production from a new thermophilic isolate

A new thermostable nitrilase‐producing isolate identified as Streptomyces sp. MTCC 7546 has been studied extensively for the optimization of enzyme production operating in batch mode. The benzonitrile was observed as inducer of nitrilase production. The isolate showed maximum nitrilase production after 24 h of incubation at optimal conditions. The strain grows well on a variety of carbon sources and produces the nitrilase that catalyses the hydrolysis of nitriles to acids without formation of amides. The enzyme is mostly active against mono‐ and di‐aliphatic nitriles (10 mmol L^?1) at pH of 7.4 and at a temperature of 50 °C. Copyright © 2007 Society of Chemical Industry     

Laser beam machining—A review

Laser beam machining (LBM) is one of the most widely used thermal energy based non-contact type advance machining process which can be applied for almost whole range of materials. Laser beam is focussed for melting and vaporizing the unwanted material from the parent material. It is suitable for geometrically complex profile cutting and making miniature holes in sheetmetal. Among various type of lasers used for machining in industries, CO₂ and Nd:YAG lasers are most established. In recent years, researchers have explored a number of ways to improve the LBM process performance by analysing the different factors that affect the quality characteristics. The experimental and theoretical studies show that process performance can be improved considerably by proper selection of laser parameters, material parameters and operating parameters. This paper reviews the research work carried out so far in the area of LBM of different materials and shapes. It reports about the experimental and theoretical studies of LBM to improve the process performance. Several modelling and optimization techniques for the determination of optimum laser beam cutting condition have been critically examined. The last part of this paper discusses the LBM developments and outlines the trend for future research.     

Development of noncontact end effector for handling of bakery products

The application of automation for handling of nonrigid or semirigid products and air permeable materials is limited due to lack of suitable end effectors. The majority of robotic manipulators and end effectors are not easily applicable because of lack of contact rigidity with nonrigid or semirigid products due to their unpredictable and unstable behaviour and with materials which are sensitive to deformation, especially bakery products (baked and unbaked) in the biscuits industry (Erzincanli and Sharp, Food Control 8:185–190, 1997). Also, during the handling process, the risk of contamination is high due to direct contact with food products. Hence, the need for noncontact robotic end effectors is strongly felt. In this paper a noncontact type end effector having a rectangular cross-section designed for handling bakery products is discussed for use in the biscuits manufacturing industry. These end effectors operate on the principle of generating vacuum, which lifts the material without any mechanical contacts. The present work explores the possibility of using radial flow nozzles in the biscuits industry. The basic working principle is presented, followed by experimental results. An automatic noncontact end effector system may be found quite useful for the food handling industry.     

Effect of Microstructure on the Radioluminescence and Transparency of Ce-Doped Strontium Hafnate Ceramics

In this paper we report on the fabrication and characterization of SrHfO(3):Ce ceramics. Powders were prepared by solid-state synthesis using metal oxides and carbonates. X-ray diffraction measurements showed that phase-pure SrHfO(3) is formed at 1200°C. Inductively coupled plasma spectroscopy confirmed the purity and composition of each batch. SrHfO(3) exhibits several phase changes in the solid, but this does not appear to be detrimental to the ceramics. Microprobe experiments showed uniform elemental grain composition, whereas aluminum added as charge compensation for trivalent cerium congregated at grain boundaries and triple points. Radioluminescence spectra revealed that the light yield decreases when the concentration of excess Sr increases. The decrease in the light yield may be related to the change of Ce(3+) into Ce(4+) ions. For stoichiometric SrHfO(3):Ce, the light yield is about four times that of bismuth germanate (BGO), the conventional benchmark, indicating great potential for many scintillator applications.     

BEM and FEM analysis of planar moving cracks in creeping solids

Applications of the boundary element method (BEM) and the finite element method (FEM), to the analysis of two-dimensional problems of moving cracks in creeping bodies, is the subject of this paper. In the absence of an acceptable crack growth law valid under small scale transient as well as extended steady state creep conditions, the computer simulations are carried out here for crack extension at prescribed constant speeds. It is shown here that the BEM is most effective for the analysis of transient crack growth under small scale creep conditions while the FEM appears to be best suited for the study of crack growth under conditions of extensive creep throughout most of the structure. These two methods, therefore, tend to complement each other for this class of problems. It is felt that the numerical methods presented here can, in conjunction with experiments, be very useful for the evaluation of existing crack growth laws as well as for the development of new ones.

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Résumé Le sujet du mémoire est l'application de la méthode par valeurs aux limites (BEM) et de la méthode par éléments finis (FEM) à l'analyse de problèmes bidimensionnels de fissures en extension dans des composants soumis à fluage.En l'absence d'une loi d'extension de fissure qui soit applicable tant sous des conditions de fluage transitoire à petite échelle que de fluage stable généralisé, on procède aux simulations per calcul on considérant le développement d'une fissure à des vitesses constantes fixées.On montre que la méthode BEM est plus efficace pour analyser la croissance d'une fissure de fluage en régime transitoire à une petite échelle, tandis que la méthode FEM convient le mieux pour étudier la croissance d'une fissure dans des conditions de fluage s'étendant à l'ensemble du composant.Dès lors, les deux méthodes tendent à se compléter pour cette classe de problèmes. On estime que les méthodes numériques qui sont présentées ici, peuvent être très utiles, en association avec des essais, pour évaluer les lois existantes en matière de propagation de fissures, ainsi que pour en développer de nouvelles.

     

Influence of initial mixing methods on melt‐extruded single‐walled carbon nanotube–polypropylene nanocomposites

We report the first direct comparison of melt‐extruded polypropylene–single‐walled carbon nanotube (PP/SWNT) nanocomposites prepared by three different initial mixing methods. The standard deviation of the G‐band intensity obtained using Raman mapping was found to be the best measure of dispersion uniformity in the extruded composites, and dispersion uniformity was found to generally correlate with rheological and thermal properties. For all three initial mixing methods, both unmodified and sidewall‐functionalized purified SWNTs were evaluated. Surprisingly, in all cases, dodecylated SWNTs prepared using the reductive alkylation method were less uniformly dispersed in the final composite than the unmodified SWNTs. The simplest process, dry blending, resulted in poor nanotube dispersion and only polymer crystallization was significantly affected by the presence of the nanotubes. A slightly more complex rotary evaporation process resulted in significantly more uniform dispersion and significant changes in rheological properties, polymer crystallization, and thermal stability. The most elaborate process tested, hot coagulation, enabled the most uniform dispersion and the greatest change in properties but also resulted in some polymer degradation. POLYM. ENG. SCI., 50:1831–1842, 2010. © 2010 Society of Plastics Engineers     

A comparative series solutions of Japanese encephalitis model using differential transform method and variational iteration method

In this study, a deterministic mathematical model involving the transmission dynamics of Japanese encephalitis (JE) is presented and studied. The biologically feasible equilibria and their stability properties have been discussed. This study investigates a series of solutions to the system of ordinary differential equations (ODEs) in the transmission dynamics of JE. To get approximate series solutions of the JE model, we employed the differential transform method (DTM) and variational iteration method (VIM). DTM utilizes the transformed function of the original JE model, while VIM uses the general Lagrange multiplier to develop the correction functional for the JE model. The results show that the VIM solution is more accurate than the DTM solution for short intervals of time. In addition, the fractional compartmental model of JE is briefly discussed. We illustrated the profiles of the solutions of each of the compartments, from which we found that the fourth-order Runge–Kutta method solutions are more accurate than the DTM and VIM solutions for long intervals of time.     

Preliminary investigation of the impact of polymer composition on electrochemical properties of coatings as determined by electrochemical impedance spectroscopy

The influence of structural and systematic compositional variations in glycidyl carbamate (GC) functional polymers on the electrochemical properties of their coatings was studied. There are few reports which focus on the correlation of structural and compositional variations in polymer films with their electrochemical barrier properties, diffusion properties with regards to water and aqueous electrolytes, and corrosion performance. To begin to fill this knowledge gap, two sets of GC functional polymers were studied. The polymer compositions were designed to vary the extent of polar hydrophilic groups, non-polar hydrophobic groups, and reactive epoxy groups in the final coatings. Impedance responses of the coatings were found to be closely related to the structural and compositional variations of these GC polymer films. In addition, single frequency EIS experiments were used in an attempt to understand the water uptake behavior of these polymer films using NaCl solution and ionic liquid under immersed condition. The resulting transport property data of the films was correlated to their polymer structure and composition. Moreover, a novel attempt at ranking the stability of coating using capacitance measurement during a cyclic wetting–drying condition was also attempted. The information obtained from this work can potentially be used to optimize the polymer for the specific performance properties needed in the protective coating applications, saving significant time and effort in the research and development stage.