掺硫硒化镓晶体在太赫兹波段的光学特性

利用太赫兹时域光谱技术测量了掺硫硒化镓(GaSe1-xSx)晶体在太赫兹波段的光学参数,包括折射系数、吸收系数等.使用自由空间电光取样法获得了太赫兹电磁波的脉冲波形.对不同硫掺杂量的硒化镓晶体进行了研究,在硫的掺杂量为0,0.01,0.14,0.26,0.37时,在0.2-2.0THz测得了GaSe1.S.的折射系数、...     

Acoustically Enhanced Water Mist Suppression of Heptane Fueled Flames

Recent research has shown that acoustics can be used to suppress flames from a liquid fuel source. The results of these experiments indicated that acoustics alone are insufficient to control flames beyond the incipient stage. Recent research has also shown that variations in the delivery of water mist to a fire can enhance the mist’s efficiency. Therefore, the addition of acoustics to water mist may be an effective means of enhancing an established fire protection technology. For the first time, acoustics and water mist have been combined and studied as a flame suppression strategy. A series of experiments were conducted that explored the potential for coupling acoustics with water mist as means of flame suppression. Heptane fueled flames were created from two different sized ceramic fiber wicks: 30 mm?×?50 mm with 5 mL of fuel, and 60 mm?×?100 mm with 20 mL of fuel. The flames were then exposed to water mist delivered at a constant rate, which was found to be incapable of suppressing the flames. Next, low frequency sound waves at 62 Hz and 80 Hz were used to suppress flames from both wicks, with each frequency being generated by a different resonator. Finally, acoustics from both resonators were combined with water mist, and used to suppress flames from both wicks. The results showed that a combination of acoustic waves and water mist suppressed the flames more effectively than each individual technique on its own. This finding opens the possibility of developing more efficient ways to use water mist technology.     

CFD boundary conditions for contaminant dispersion,heat transfer and airflow simulations around human occupants in indoor environments

Indoor computational fluid dynamics (CFD) simulations can predict contaminant dispersion around human occupants and provide valuable information in resolving indoor air quality or homeland security problems. The accuracy of CFD simulations strongly depends on the appropriate setting of boundary conditions and numerical simulation parameters. The present study explores influence of the following three key boundary condition settings on the simulation accuracy: (1) contaminant source area size, (2) convective/radiative heat fluxes, and (3) shape/size of human simulators. For each of the boundary conditions, numerical simulations were validated with experimental data obtained in two different environmental chambers. In CFD simulations, a small release area of a contaminant point source causes locally high concentration gradients that require a very fine local grid system. This fine grid system can slow down the simulations substantially. The convergence speed of calculation is greatly increased by the source area enlargement. This method will not influence the simulation accuracy of passive point source within well-predicted airflow field. However, for active point source located within complicated airflow filed, such an enlargement should be carried out cautiously because simulation inaccuracy might be introduced. For setting thermal boundary conditions, convection to radiation heat flux ratio is critical for accurate CFD computations of temperature profiles around human simulators. The recommended convection to radiation (C:R) ratio is 30:70 for human simulators. Finally, simplified human simulators can provide accurate temperature profiles within the whole domain of interest. However, velocity and contaminant concentration simulations require further work in establishing the influence of simplifications on the simulation accuracy in the vicinity of the human simulator.     

Parallel Plates Compared with Conventional Rods as TDR Waveguides for Sensing Soil Moisture

Dielectric methods of estimating the water content of soils, especially TDR, have become accepted as routine measurement techniques. Basic to the TDR technique is the waveguide, which is inserted into the soil for obtaining measurements of the effective soil permittivity, from which water content is estimated. In this study we compare the use of flat stainless steel plates with cylindrical stainless steel rods. We suggest that the use of plates gives a more even distribution of electromagnetic energy within the soil volume sampled and reduces the so called ``skin effect' where the electromagnetic energy is concentrated close to the surface of the electrodes. Plates will not be suitable for all measurement purposes but wherever they can be applied they should result in more representative measurements from the medium under investigation. Calculations of electrical field intensity are presented to compare the relative energy density between the electrodes. Field and laboratory studies were alsoconducted considering some of the practicalities of using the alternative waveguides.     

Event-related potential (ERP) studies of memory encoding and retrieval: a selective review

As event-related brain potential (ERP) researchers have increased the number of recording sites, they have gained further insights into the electrical activity in the neural networks underlying explicit memory. A review of the results of such ERP mapping studies suggests that there is good correspondence between ERP results and those from brain imaging studies that map hemodynamic changes. This concordance is important because the combination of the high temporal resolution of ERPs with the high spatial resolution of hemodynamic imaging methods will provide a greatly increased understanding of the spatio-temporal dynamics of the brain networks that encode and retrieve explicit memories.     

Exploring scenarios for the future of energy management in UK property

The most appropriate responses to the energy management of buildings from now until 2050 are investigated through a process of scenario planning. A qualitative, explorative approach was undertaken to develop four 2050 scenario end-states resulting from an axis of two critical uncertainties not closely correlated: the attitudes of society towards sustainability; and the availability of energy. These scenarios were applied to the property industry through expert workshops, from which trends and themes were identified. The findings are that the property industry should prepare for a transitional period with an uncertain outlook. Therefore, it would be prudent for this industry to focus on resilient performance under a diverse set of futures, and plausible shock events, rather than optimizing for today's conditions. This could be challenging in a sector that works on relatively long time scales. Aspects that should be incorporated into property industry strategy are suggested: responding to the potential effects of climate change; understanding what drives communities and investing in buildings that are significant to the community's functions; considering transport links as key to successful property investments; adopting the latest technological innovations; and becoming more ‘full service’ and interdisciplinary. A need for a paradigm shift in the industries' practices was also identified.

Les réponses les plus appropriées à la gestion énergétique des bâtiments d'ici 2050 sont étudiées en ayant recours à un processus de planification par scénarios. Une approche qualitative exploratrice a été adoptée afin de développer quatre conclusions de scénario pour 2050, résultant d'un axe formé par deux incertitudes cruciales qui ne sont pas étroitement corrélées: les attitudes de la société envers la durabilité et la disponibilité de l'énergie. Ces scénarios ont été appliqués à l'industrie de l'immobilier par l'intermédiaire d'ateliers d'experts, grâce auxquels des tendances et des thèmes ont été identifiés. Il en ressort que l'industrie de l'immobilier devrait se préparer à une période de transition offrant des perspectives incertaines. En conséquence, il serait prudent que cette industrie concentre ses efforts sur le maintien de solides performances face à différents avenirs possibles, et à des évènements chocs plausibles, plutôt que sur une optimisation par rapport aux conditions d'aujourd'hui. Ceci pourrait être difficile dans un secteur qui travaille sur des échelles de temps relativement longues. Il est suggéré des aspects qui devraient être intégrés à la stratégie de l'industrie de l'immobilier: répondre aux effets potentiels du changement climatique; comprendre ce qui constitue le moteur des collectivités et investir dans des bâtiments qui soient significatifs pour les fonctions de la collectivité; considérer les liaisons de transport comme essentielles pour des investissements immobiliers réussis; adopter les dernières innovations technologiques; et devenir davantage « un service complet » et interdisciplinaire. A également été identifiée la nécessité d'un changement de paradigme dans les pratiques des industries.

bâtiments, gestion énergétique, planification future, secteur de l'immobilier, résilience, scénarios, incertitude     

A NOVEL METHOD FOR DIRECT NONDESTRUCTIVE DIAGNOSIS OF CARIES AFFECTED TOOTH SURFACES BY LASER MULTIPHOTON IONIZATION

A new nondestructive analytical method for diagnosis of tooth caries is presented. The method is based on the Multiphoton Ionization (MPI) fast conductivity signals measured from tooth surfaces. The signals are acquired for a series of laser wavelengths, thus obtaining full MPI spectra. The results indicate a good correlation between the MPI results and the degree of severity of the caries, as diagnosed using traditional inspection. Moreover, the spectral information can be reduced (using least squares fitting) to a single parameter that provides an objective quantitative estimation of the caries severity. The MPI data can be obtained for tiny points on the dental surface and it is suggested that mapping is possible by scanning method.     

Structures and electronic properties of surface/edges of nanodiamond and nanographite

The structure, electronic and magnetic properties of nanodiamond and nanographite/nanographene are investigated. Detonation nanodiamond particles that are covered with amorphous graphitic composites are hydrothermally treated to remove the graphitic surface composites and to terminate the surface carbon atoms with hydrogen. The number of localized spins of dangling bonds and the hydrogen concentration increase upon the increase in the hydrothermal treatment time up to 40 h. Above 40 h, both drop discontinuously, a surface structural reconstruction was suggested. The creation of dangling bonds and an incomplete hydrogenation of the surface carbon atoms destabilize the surface, resulting in the structural reconstruction. Nanodiamond particles are thermally converted to nanographite/nanographene. A single nanographene sheet is successfully prepared by heat-treating nanodiamond particles. The edge of graphene sheet with its edge carbon atoms being hydrogen-terminated is investigated by UHV-STM/STS. Zigzag edges are found to have non-bonding π-state of edge origin, in good agreement with theoretical prediction.     

Novel nonlinear-modulation acoustic technique for crack detection

Novel nonlinear-modulation methods for crack detection are discussed. The approach is based on the so-called cross-modulation effect consisting of the modulation transfer from an intensive, initially slowly amplitude-modulated stronger (pump) excitation to the probe signal. Advantage of this technique is a very flexible choice of the operation frequencies, since their ratio for both carriers and the modulation may be rather arbitrary. This in its turn allows one to effectively use the sample resonances in order to achieve the necessary level of the pump excitation and to ameliorate conditions for detection of the modulation sidelobes for the probe wave. Unlike higher harmonic-generation methods the initial nonlinear distortions of the pump and probe excitations (e.g. due to nonlinearities in the electronics) are not critical for this technique. In the paper we summarise results of recent test experiments that indicated high sensitivity of the new technique.     

GC/MS characterization of mate tea leaves extracts obtained from high-pressure CO2 extraction

This work presents a study concerning the chemical characteristics and analytical separation process of the essential oil obtained from high-pressure carbon dioxide extraction of Ilex paraguariensis. The experiments were performed in a laboratory-scale unit in the temperature range of 20–40 °C, from 100 to 250 bar. A blend of the I. paraguariensis extracts was percolated through a preparative chromatographic column, containing silica gel, and successively eluted with 150 mL of each of the following solvents: hexane, toluene, dichloromethane, ethyl acetate, acetone and methanol. The raw extract and its fractions were analyzed by gas chromatography coupled to mass spectrometry detection (GC/MS). The fractionation procedure showed to be a good clean up technique due to the isolation of different classes of compounds in each fraction. Chromatographic analyses allowed the identification of caffeine, fatty acids and esters, phytol, squalene, Vitamin E, stigmasterol derivatives and saturated hydrocarbons.