BCI Competition 2003--Data sets Ib and IIb: feature extraction from event-related brain potentials with the continuous wavelet transform and the t-value scalogram

The t-CWT, a novel method for feature extraction from biological signals, is introduced. It is based on the continuous wavelet transform (CWT) and Student's t-statistic. Applied to event-related brain potential (ERP) data in brain-computer interface (BCI) paradigms, the method provides fully automated detection and quantification of the ERP components that best discriminate between two samples of EEG signals and are, therefore, particularly suitable for classification of single-trial ERPs. A simple and fast CWT computation algorithm is proposed for the transformation of large data sets and single trials. The method was validated in the BCI Competition 2003, where it was a winner (provided best classification) on two data sets acquired in two different BCI paradigms, P300 speller and slow cortical potential (SCP) self-regulation. These results are presented here.     

Calibration method for multiangle lidar measurements

A new method based on a two-angle approach is developed to determine the lidar solution constant from scanning elastic lidar data, hence providing a relative calibration for each lidar scan. Once the solution constant is determined, the vertical profiles of atmospheric extinction can be calculated. With this calibration method a minimization technique is used that replaces the linear regression used in a known two-angle approach that requires only local atmospheric homogeneity over a restricted altitude calibration range rather than overall horizontal homogeneity. Lidar signals from at least one pair of elevation angles are used, averaged in time when the system is operated in a permanent two-angle mode, or an arbitrary number of signal pairs is used, when a two-dimensional lidar scan is being processed. The method is tested extensively with synthetic data. The calibration method is a robust tool for determining the solution constant to the lidar equation and for obtaining vertical profiles of atmospheric extinction.     

Distortions of the extinction coefficient profile caused by systematic errors in lidar data

The influence of lidar data systematic errors on the retrieved particulate extinction coefficient profile in clear atmospheres is investigated. Particularly, two sources of the extinction coefficient profile distortions are analyzed: (1) a zero-line offset remaining after subtraction of an inaccurately determined signal background component and (2) a far-end incomplete overlap due to poor adjustment of the lidar system optics. Inversion results for simulated lidar signals, obtained with the near- and far-end solutions, are presented that show advantages of the near-end solution for clear atmospheres.     

Diagnose von Korrosionsfällen an einer Saturationskolonne für Synthesegas

Diagnosis of case histories from a synthesis gas saturation column The saturation column, made of steel type 1Cr18Ni9Ti (wall thickness: 8 mm), in which the gas is cooled down to 240°C by a water jet and, simultaneously saturated with water vapour, failed after only 3000 hours' operation; the failure was attributable to a damaged footing tube. An analysis of the damaged parts suggested, that the main cause of the failure was not the design of the equidistant shells, i. e. the welding connection between the tubes and the two shells, which had originally been assumed to be faulty, but in a first line the material selection which was wrong in view of possible corrosion. The tensile stresses resulting from the rigid connection of the footing pipes are but one of the factors contributing to the development of stress corrosion cracking. This opinion concerning the reason of the first failure was confirmed when another failure occurred after another 1000 hours' operation of the column: a thorough inspection revealed some spots where stress corrosion cracking bad developed.     

Corrosion of Titanium-Aluminum Intermetallides. Part 2. Electrolytic Oxidation of γ‐TiAl,TiAl3, and α2‐Ti3Al in Sea Water

Potentiodynamic polarization, XRD, Auger electron spectroscopy, and scanning electron microscopy have been applied to determine the mechanisms of electrolytic corrosion of the intermetallides TiAl, TiAl₃, and ₂Ti₃Al in 3% NaCl solution with the addition of MgSO₄ in comparison with the corrosion of the pure metals (Al and Ti). There is comparatively high corrosion resistance in TiAl and Ti₃Al because of the protective action from thin films of rutile TiO₂. Evidence is obtained for the differences between these intermetallides from the appearance of pure titanium on deep anodic polarization (above +0.15 V for TiAl and +0.7 V for Ti₃Al): the aluminum and titanium enter the solution in the forms of Al³⁺ and TiO²⁺ and intermetallides dissolve rapidly. The final solid-state products from anodic oxidation in that case are rutile, magnesium aluminate, and also magnesium and sodium titanates. In addition to pure titanium, TiAl and ₂Ti₃Al as constructional materials may be recommended for use in sea water.     

Enthalpies of Solution and Mixing for Graphite in Molten Silicon at 2000 K

Partial and integral enthalpies of mixing have been determined in an isoperibolic calorimeter for liquid alloys in the silicon – carbon binary system at 2000 K. These enthalpies of mixing are small exothermic quantities which agree with published data. The enthalpy of mixing _f Hº₂₉₈ has been calculated for silicon carbide.     

Design criteria and optical characteristics of one-dimensional photonic crystals based on periodically grooved silicon

Photonic bandgap (PBG) regions have been calculated for periodically grooved Si structures, acting as a one-dimensional photonic crystal. The wavelength range of the PBG as a function of the ratio (DSi/A) is presented, where DSi is the width of the Si walls and A is the grooved silicon lattice constant. The influence of the parameter DSi, the refractive index of the space between the Si walls and the number of structure periods, m, on the forming of PBG regions is discussed. A good correlation between the calculated and the experimentally observed PBG regions is obtained.     

Observations of infrared bands of asymmetrical ozone isotopologues 16O16O18O and 16O18O18O

Infrared spectra (0.003 cm(-1) resolution) of 16O16O18O and 16O18O18O ozone isotopologues have been recorded and analyzed in the range 600-5000 cm(-1). Several thousand rovibrational lines belonging to 32 absorption bands have been measured and assigned. An accurate determination of band centers through the rovibrational analysis has been done, 12 bands being observed for the first time to our knowledge. In addition to atmospheric retrieval applications, these results are also useful for a validation of potential energy surfaces and for the study of isotope effects in dynamic processes of ozone.     

Detection of cyclic lipopeptide biomarkers from Bacillus species using atmospheric pressure matrix-assisted laser desorption/ionization mass spectrometry

A novel approach to microbial detection using atmospheric pressure matrix-assisted laser desorption/ionization with an ion trap mass spectrometer to analyze whole cell bacteria is introduced. This new approach was tested with lyophilized spores and cultures of Bacillus globigii (BG) grown on agar media for 4 days or longer. At each stage of growth, it was found that biomarkers, identified as cyclic lipopeptides known as fengycin and surfactin, could be detected by pulsed ultraviolet laser irradiation of intact BG cells (approximately 5 mg) cocrystallized with alpha-cyano-4-hydroxycinnamic acid. Furthermore, definitive amino acid sequence information was obtained by performing tandem mass spectrometry on the precursor ions of the cyclic lipopeptides. The investigation was broadened to include the examination of aerosolized BG spores collected from the atmosphere and directly deposited onto double-sided tape. Subsequent analysis of the recovered spores resulted in the production of mass peaks consistent with fengycin. Other Bacillus species were analyzed for comparison and showed mass spectral peaks also identified as originating from various cyclic lipopeptides. Further studies were conducted using a pulsed infrared laser as the excitation source to analyze BG cells (approximately 5 mg) suspended in a matrix of 0.03 M ammonium citrate and glycerol resulting in the production of ions characteristic of fengycin and surfactin.