Predictions of nitrate diffusion in sediment using horizontal attenuated total reflection (HATR) by Fourier transform infrared (FTIR) spectrometry

Using a novel and simple method based on horizontal attenuated total reflection (HATR) by Fourier transform infrared (FTIR) spectrometry, the effective diffusion coefficient, De, of nitrate in a contaminated anthropogenic sediment was estimated as 7.34 x 10(-6)cm2 s(-1). This method, which requires as little as 1 mL of sediment sample, was able to measure the De of a chemical species with a reproducibility of +/-3% in about 5h. Based on this De and a pre-determined nitrate reduction rate, the profiles of nitrate concentration in two sediment columns were satisfactorily predicted from a mathematical model. Results showed that the profile in this aged sediment depended mainly on the diffusion of nitrate and, only to a much lesser degree, the rate of nitrate reduction. Measurements in 55 anthropogenic sediment samples collected from five locations and various depths of a contaminated site further showed that the De of nitrate increased linearly with the water content of the sediment, but decreased with the sediment density. The technique demonstrated in this study shall be applicable for the risk assessment of toxic pollutants in contaminated sediments, and for planning the spatial and time intervals of nitrate injection strategy in bioremediation.     

Speciation of selenium in plant water extracts by ion exchange chromatography-hydride generation atomic absorption spectrometry

Determination of selenium (Se) speciation in plants is important in studying the bioavailability and toxicity of Se in Se-contaminated soil/sediment. In this study, we used an anion exchange resin (Dowex 1-10X) to separate Se into non-amino acid organic Se, Se-amino acids, selenite (Se [IV]) and selenate (Se [VI]) in a plant (Stanleya pinnata) extract. The hydride generation atomic absorption spectrometry (HGAAS) was used to determine concentrations of these Se compounds in plant extracts. Results showed that Se compounds can be quantitatively separated by the resin column. Recovery of five spiked standard Se compounds (trimethylselenonium ion (TMSe+), dimethylselenoxide (DMSeO), selenomethionine (Semet), Se [IV] and Se [VII]) in the plant extract ranged from 92.9 to 103%. Water extractable Se accounted for 60.4-72.6% of the total Se in the plant. Among the soluble Se compounds in the plant extract, Se-amino acids were 73-85.5%, Se [VI] ranged from 7.5 to 19.5% and non-amino acid organic Se was less than 7%. Se [IV] in most samples was below the detection limit (1 microg/g). This study showed that considerable amounts of the accumulated Se [VI] in the plant was metabolized to Se-amino acids during growth of the plant.     

Analysis of point load test as a method for preliminary geotechnical classification of rocks

This paper deals with the analysis of the point load compression test made on irregular-shaped rock fragments, proposed in the late 50’s by Protodiakonov. An ample revision of the literature on the subject has been made, and a series of tests, using seven different types of rock materials, has been developed. The results obtained from these tests showed that parameters generally used in literature to relate the unconfined compressive (or tensile) strength of materials, resulting from point load tests, can lead to scattered results, due mainly to the scale effect, of great evidence in such tests. It seems possible to obtain compressive (and tensile) strength of rocks, if the ratio between failure load and the distance between load application poins, with a 3/2 exponent, is considered, in field work, as being the "point load strength index".

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Resume L’article présente une analyse critique de l’essai de compression sur échantillons irréguliers de roche, proposé par Protodiakonov vers la fin des années 50. Tout d’abord on a fait une révision de la littérature disponible sur le sujet et, après, une série d’essais sur sept types différents de matériaux. Les résultats obtenus ont montré que les paramètres plus utilisés, dans la littérature, pour définir la résistance à la compression (ou traction) des roches, d’après les essais ponctuels, peuvent provoquer une dispersion très importante des résultats. Cependant, il nous semble valable de suggérer la possibilité de déterminer, sur le chantier, la résistance à la compression (ou traction) des roches, si l’on considère le quotient entre la charge de rupture et la distance entre les deux points d’application de cette charge, le dénominateur à la puissance 3/2, comme "l’indice de charge ponctuelle".

     

A computer technique for predicting smoke movement in tall buildings

An approach to the analysis of stack effect has been developed which allows the prediction of internal air flow quantities and associated pressure differentials for specific buildings prior to construction. An example of the application of this analysis is presented for a hypothetical 75-story office building. Note: The authors presented this paper at a symposium on “The Control of Smoke Movement on Escape Routes in Buildings,” sponsored by the Joint Fire Research Organization and held on April 9 and 10, 1969 in Hertfordshire, England.     

A preliminary note on the sequential decomposition of pectin by aquatic bacteria

In a eutrophic lake, an inverse relationship was observed between total aerobic heterotrophic bacteria and their pectolytic share which consisted mainly of Flavobacterium-Cytophaga species. When grown in a medium containing pectin and yeast extract as organic compounds pure cultures of the most abundant type of this bacterial group showed a diauxic characteristic of growth. Short time before entering the first lag phase of growth, production of pectolytic enzymes increased until the end of the second log phase of growth. This phenomenon may be due to the mechanism of a catabolic repression and derepression.     

Substrate Stimulated Orientation for Pure Aluminum

Oriented materials are of great importance, but their formation is rarely described. Here, nine Al/Al₂O₃ systems were designed to identify the dominant factors. Electron back-scattered diffraction indicates that the new Al crystal(s) with one or multiple orientation(s) can be stimulated by one single-crystal Al₂O₃ substrates. Synchrotron radiation diffraction shows that the preferred orientation(s) is/are determined based on the initial stage of the liquid–solid transition. The nonpreferred orientation can be suppressed through competition.

     

Microdistortions,Hardness, and Young’s Modulus of Multicomponent Bcc Solid Solutions

Powder Metallurgy and Metal Ceramics - The phase composition, type II microstresses, and coherent scattering domains (CSDs) of multicomponent (medium- and high-entropy) bcc solid solutions with an...     

Predicting construction firm performance: an empirical assessment of the differential impact between industry‐ and firm‐specific factors

It is obvious that the performance of firms hinges upon the dynamics of both industry‐ and firm‐specific factors. A less obvious, and perhaps a more important, line of inquiry is that to the extent that they have a bearing on firm performance, how much do these two groups of factors respectively predict firm performance? To date, performance differences among construction firms that stem from industry‐ and firm‐specific differential effect has remained largely unexplored. Using a dataset comprising 526 firms across various construction‐related sectors, the sector‐by‐sector firm performance variation that is attributable to the heterogeneity of both industry‐ and firm‐specific characteristics was empirically examined. That statistically significant results of different effect sizes are found indicates that although these factors are often assumed to be intertwined it is possible to study their respective impact on firm performance. Future studies could usefully replicate and extend this study to construction firms in other countries to further investigate what drives firm performance under different national, industry and firm contexts.