FE modeling of warm flanging process of large T-pipe from thick-wall cylinder

The large T-branch pipe made from the thick-wall cylinder is an important part in power, petroleum, and chemical equipment. The warm flanging process is used to manufacture the high-performance large T-branch pipe from thick-wall cylinder. The warm flanging process has a bulk-forming characteristic with heterogeneous temperature field and represents very different from the sheet flanging process. The finite element method is adopted to study the warm flanging process of large T-branch pipe due to complex local heating and local deformation. A viscoplastic FE model was built to simulate the whole process in the same process, including heating, forming, cooling, and relevant elastic springback. Only one set of mesh was used to ensure the connection of heating and forming, which was never proposed in the warm flanging process before. The experiment was conducted to verify the proposed model by comparing the geometry and defects. Accordingly, two kinds of typical defects, buckling and wrinkling, were found in both of the simulation and experiment results. And, the reasons of defects were investigated with the stress and metal flow analysis. The short lower die leads to the buckling. Due to the ellipse outer edge, the uneven rebound makes wrinkling at the ends of the process. Three relevant improved methods, lengthening the lower die, increasing the fillet of the upper die, and increasing the radius of the upper die, were proposed and studied to decline the defects.     

Relation between impurities and oxide-scale growth mechanisms on Ni-34Cr and Ni-20Cr alloys. II. Influence of sulphur

The oxidation of presulphidized Ni-Cr alloys has been studied by taking into account the influence of the two distinct oxidation mechanisms described in part I of this article. Sulphur enters the Cr₂O₃ scale (in Ni-34Cr alloys) mainly as S^2– species, which at high temperatures increases the V_Cr content, and hence the oxidation kinetics. Sulphur is randomly distributed in the scale, except at the inner oxide-alloy interface, where intergranular microsulphides are analyzed in the oxide-scale zone. In the case of NiO, NiCr₂O₄, Cr₂O₃ oxide multilayers (in a Ni-20Cr alloy), sulphur in the S^2– state is distributed in the oxide layers or at Si-precipitate interfaces. Such a distribution leads to crack formation, especially during cooling.     

不同频率交变磁场下低合金钢焊缝微区磁致塑性变形与磁致伸缩的关系

通过改变交变磁场的频率(磁感应强度一定),研究了QSTE420钢焊缝的磁致微区塑性变形和磁致伸缩幅值随频率的变化趋势,并探讨了磁致微区塑性变形和磁致伸缩两者之间的关系。结果表明:随交变磁场频率的降低,QSTE420钢焊缝区域的磁致塑性变形更加明显,而磁致伸缩幅值则逐渐减小;磁致伸缩所引起的应力、应变不是磁致微区塑性变形的主要原因。     

Material characterization of blanked parts in the vicinity of the cut edge using nanoindentation technique and inverse analysis

Sheet metal blanking is widely used in various industrial applications such as automotive and electrical rotating machines. When this process is used, the designer can be faced with several problems introduced by the change of the material state in the vicinity of the cut edge. In general, blanking operations severely affect mechanical and physical properties of blanked parts. To take into account these modifications during the part design, it is important to assess the influence of the process parameters on the resulting material properties. Previous experimental and numerical investigations of blanking process have been carried out, leading to the development and the validation of a finite element model that predicts the shape of the cut edge and state of the material. The study presented in this paper makes use of nanoindentation technique to improve the validation of the previously cited model. To this end, nanoindentation tests were combined with inverse identification technique to approach some of the characteristics of material state like work hardening near its cut edges. Indentation tests were carried out in the vicinity of several parts of cut edges. Based on the corresponding load versus penetration curves, the evolution of the yielding stress resulting from the material work hardening was estimated and compared to the predictions obtained from the numerical simulation of blanking process. These comparisons show good agreement between the measurements and the predictions from finite element model.     

大尺寸直径非接触光电检测系统研究

提出了一种基于激光位移测头的大尺寸直径光电测量系统，可用于直径达φ52200mm的大尺寸工件的非接触测量。文章详细论述了测量系统结构、工作原理及同轴度测量方法，并对影响测量精度的主要误差来源进行了分析，结果表明测量精度达0．02mm。     

Anionic polymerization and copolymerization of cyclosiloxanes initiated by trimethylsilylmethyllithium

Summary A novel initiator, i.e. trimethylsilylmethyllithium has been successfully used for the ring opening polymerization of cyclosiloxanes, in toluene or in the bulk, in the presence of the cryptand [211] or DMSO. Suitable conditions have been found in which monomodal distributions of molecular weights are observed for homopolymers of 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane (V₄) as well as for copolymers of V₄ with D₃ or D₄. Laboratoire de Chimie Macromoléculaire associé au CNRS, URA 24     

Linear alkylbenzene

Linear alkylbenzene (LAB) was introduced in the mid-1960s as a raw material for cleaning products. Since then, continuing and explosive research on its biodegradation and on its environmental and human toxicity has been performed. The efficiency of linear alkylbenzene sulfonate as surfactant is clearly established, and it is one of the safest and most cost-effective products in widespread commercial use. The aim of the present paper is to survey the most important developments and understandings of the chemistry of LAB production and of its physical and environmental properties. The expected consequence of this analytical survey is to envisage the continuous challenges for the detergents industry in catalytic production of LAB, better control of selectivity, replacement of corrosive and mineral liquid acid catalyst by heterogeneous acid catalyst and the maintenance of competitiveness of LAB with respect to natural alcohols.     

Proposed Phenomenological PTCR Model and Accompanying Phenomenological PTCR Chart

The positive temperature coefficient of resistivity (PTCR) behavior of semiconductive BaTiO₃ is well explained by the Heywang model, which predicts the resistivity behavior above the Curie point based on the acceptor state density at the grain boundaries, the charge carrier density, and the energy gap, E _s, between the conduction band and the acceptor levels. However, the relationship between these parameters and the production parameters (sintering time, composition, and cooling rate) is not well understood. Recently, the present authors have found that E _s can be increased by thorough oxidation. This increase is attributed to a change in the oxidation state of the acceptor. Based on this finding and results from the literature, a phenomenological PTCR model and an accompanying PTCR chart for acceptor–donor-codoped BaTiO₃ are proposed to clarify this relationship. The PTCR chart clarifies that acceptor dopant concentrations, oxidation time, and oxygen partial pressure during oxidation or cooling can be optimized simultaneously to obtain optical PTCR properties.     

Practical considerations for high spatial and temporal resolution dynamic transmission electron microscopy

Although recent years have seen significant advances in the spatial resolution possible in the transmission electron microscope (TEM), the temporal resolution of most microscopes is limited to video rate at best. This lack of temporal resolution means that our understanding of dynamic processes in materials is extremely limited. High temporal resolution in the TEM can be achieved, however, by replacing the normal thermionic or field emission source with a photoemission source. In this case the temporal resolution is limited only by the ability to create a short pulse of photoexcited electrons in the source, and this can be as short as a few femtoseconds. The operation of the photo-emission source and the control of the subsequent pulse of electrons (containing as many as 5 x 10(7) electrons) create significant challenges for a standard microscope column that is designed to operate with a single electron in the column at any one time. In this paper, the generation and control of electron pulses in the TEM to obtain a temporal resolution <10(-6)s will be described and the effect of the pulse duration and current density on the spatial resolution of the instrument will be examined. The potential of these levels of temporal and spatial resolution for the study of dynamic materials processes will also be discussed.     

航空发动机典型量检具参数化设计

航空发动机量检具是航空发动机工装的一类,对应不同型号发动机的同一种零件,该零件的工装结构尺寸随零件的系列尺寸相应变化。本文在分析了发动机工装设计过程的基础上,对工装进行了数字化建模,并将系列尺寸的工装模型参数化、模板化,开发出了工装设计系统,使设计人员在工装设计中缩短了设计周期,降低了设计成本,并成功应用在某航空发动机企业的工装设计部门中。