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21.
Ting Liu Huimin Zhang Panfei Ma Aimin Chang Hui Jiang 《Journal of the American Ceramic Society》2019,102(8):4393-4398
Core–shell structures have been proposed to improve the electrical properties of negative-temperature coefficient (NTC) thermistor ceramics. In this work, Al2O3-modified Co1.5Mn1.2Ni0.3O4 NTC thermistor ceramics with adjustable electrical properties were prepared through citrate-chelation followed by conventional sintering. Co1.5Mn1.2Ni0.3O4 powder was coated with a thin Al2O3 shell layer to form a core–shell structure. Resistivity (ρ) increased rapidly with increasing thickness of the Al2O3 layer, and the thermal constant (B) varied moderately between 3706 and 3846 K. In particular, Co1.5Mn1.2Ni0.3O4@Al2O3 ceramic with 0.08 wt% Al2O3 showed the increase of ρ double, and the change in its B was less than 140 K. The Co1.5Mn1.2Ni0.3O4@Al2O3 NTC ceramics showed high stability, and their grain size was relatively uniform due to the protection offered by the shell. The aging coefficient of the ceramic was less than 0.2% after aging for 500 hours at 125°C. Taken together, the results indicate that as-prepared Co1.5Mn1.2Ni0.3O4@Al2O3 NTC ceramics with a core–shell structure may be promising candidates for application as wide-temperature NTC thermistor ceramics. 相似文献
23.
Yu-Jiao Liu Xiao-Yang Fan Dr. Dong-Dong Zhang Yin-Zheng Xia Dr. Yan-Jun Hu Feng-Lei Jiang Prof. Fu-Ling Zhou Prof. Yi Liu 《ChemMedChem》2020,15(6):552-558
Based on the potential therapeutic value in targeting mitochondria and the fluorophore tracing ability, a fluorescent mitochondria-targeted organic arsenical PDT-PAO-F16 was fabricated, which not only visualized the cellular distribution, but also exerted anti-cancer activity in vitro and in vivo via targeting pyruvate dehydrogenase complex (PDHC) and respiratory chain complexes in mitochondria. In details, PDT-PAO-F16 mainly accumulated into mitochondria within hours and suppressed the activity of PDHC resulting in the inhibition of ATP synthesis and thermogenesis disorder. Moreover, the suppression of respiratory chain complex I and IV accelerated the mitochondrial dysfunction leading to caspase family-dependent apoptosis. In vivo, the acute promyelocytic leukemia was greatly alleviated in the PDT-PAO-F16 treated group in APL mice model. Our results demonstrated the organic arsenical precursor with fluorescence imaging and target-anticancer efficacy is a promising anticancer drug. 相似文献
24.
Wei Mengnan Ban Boyuan Li Jingwei Sun Jifei Li Feifei Jiang Xuesong Chen Jian 《SILICON》2020,12(2):327-338
Silicon - A novel green cationic surfactant Poly (propylene glycol) bis (2-aminopropyl ether) (PEA) with multiple amine groups was utilized as a collector for flotation separation of quartz from... 相似文献
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通过分析A公司在研发项目范围管理中所存在问题,提出研发项目范围管理的方法及其在C产品的应用实例,通过运用研发项目范围管理的工具和方法,改善产品开发流程,从而缩短新产品开发周期,提高响应市场的速度,并提高企业研发项目的管理能力。 相似文献
27.
Mineralization of Para-Chlorobenzoic Acid in Water by Cobalt-Incorporated MCM-41 Catalyzed Ozonation
Cobalt-incorporated MCM-41(Co-MCM-41) was used as a heterogeneous catalyst for the ozonation of para-chlorobenzoic acid (p-CBA) in aqueous solution. Cobalt oxide supported on MCM-41(Co/MCM-41) was synthesized for comparison. Their textural properties were elucidated by various characterization techniques to understand the relationship between surface texture and catalytic activity. TOC removal at 60 min reached 91% with Co-MCM-41, 83% with Co/MCM-41 and only 52% with ozone alone, respectively. Observations from diffuse reflection spectroscopy demonstrated that different metal phases were formed in these cobalt-modified molecular sieves samples. Radical scavenger experiments indicated the formation of hydroxyl radicals that were responsible for the effective degradation of p-CBA. An integrated approach to the catalytic mechanism was proposed by considering the variation of pH in the course of ozonation as well as its subsequent influence on the dissociation of targeted compounds and surface charge of the catalyst. In the reusability experiments, the reused Co-MCM-41 was able to regain the same catalytic capability as the fresh one within 5 cycles. X-ray photoelectron spectroscopy results indicated that a part of Co2+ was oxidized to Co3+ after oxidation reaction. 相似文献
28.
微型步进马达线圈组卷线上下料基本靠手动作业,效率低下,同时因工人技术水平的不同造成产品品质不稳定的问题多发.为此专门设计了微型步进马达线圈组自动卷线及上下料设备.通过结合现阶段的先进工业技术,采用振动盘分离区分进料,多机构并联三菱PLC及威纶人机界面触摸屏研发了此微型步进马达线圈组自动上下料及卷线设备.通过该设备实现了微型步进马达因工人不足导致产能减少和品质多发问题,减少企业成本,提升产品品质. 相似文献
29.
In this study, the crystal structure, thermal, oxygen transport, electrical conductivity and electrochemical properties of the perovskite NdBa0.5Sr0.5Co2O5+δ (NBSC55) are investigated. In the temperature range of 250 °C–350 °C, the weight loss upon heating was due to a partial loss of lattice oxygen and along with a reduction of Co4+ to Co3+. The tend of weight-loss slows down as temperature increased above 350 °C indicating a reduction of Co3+ to Co2+ during this stage. The oxygen migration is dominated by surface exchange process at high temperature range (650-800 °C); however, the bulk diffusion process prevails at low temperature range (500–600 °C). For long-term testing, the polarization resistance of NBSC55 increases gradually form 3.13 Ω cm2 for 2 h to 3.34 Ω cm2 for 96 h at 600 °C and an increasing-rate for polarization resistance is around 0.22% h?1. The power density of the single cell with NBSC55 cathode reached 341 mW cm?2 at 800 °C. 相似文献
30.