Ambient flash sintering of reduced graphene oxide/zirconia composites:Role of reduced graphene oxide

Fabrication of graphene/ceramic composites commonly requires a high-temperature sintering step with long times as well as a vacuum or inert atmosphere,which not only results in property degradation but also significant equipment complexity and manufacturing costs.In this work,the ambient flash sintering behavior of reduced graphene oxide/3 mol% yttria-stabilized ZrO₂(rGO/3 YSZ) composites utilizing rGO as both a composite component and a conductive additive is reported.When the sintering condition is carefully optimized,a dense and conductive composite can be achieved at room temperature and in the air within 20 s.The role of the rGO in the FS of the rGO/3 YSZ composites is elucidated,especially with the assistance of a separate investigation on the thermal runaway behavior of the rGO.The work suggests a promising fabrication route for rGO/ceramic composites where the vacuum and furnace are not needed,which is of interest in terms of simplifying the fabrication equipment for energy and cost savings.     

Interfacial assembly of sandwich mixed (Phthalocyaninato)(Porphyrinato) rare earth triple-decker complexes: Effect of in situ coordination

Interfacial assembly of sandwich mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker complexes [(Pc)Eu(Pc)Eu(TPyP)] (1) and [(TPyP)Sm(Pc)Sm(TPyP)] (2) (Pc = phthalocyaninate, TPyP = meso-tetrakis(4-pyridyl)porphyrinate) has been comparatively studied at the air/pure water and the air/CdCl₂ aqueous solution subphase interfaces. Surface pressure-area isotherms revealed the remarkable increase of limiting mean molecular area of the triple-deckers with the presence of Cd²⁺, suggesting the occurrence of in situ interfacial coordination. The formation of coordination bonds between the pyridyl groups of TPyP macrocycles in the triple-deckers and Cd²⁺ ions from the subphase was further supported by FT-IR spectroscopic data. Electronic absorption measurements showed the formation of J-aggregates of the triple-decker molecules in the interfacial assembled films.     

基于EMD分解的变压器励磁涌流鉴别

针对励磁涌流波形畸变严重且会出现尖顶波,而故障电流基本保持基频正弦波特征的特点,提出了一种利用HHT(Hilbert-Huang Transform)的EMD(Empirical Mode Decomposition)分解来识别变压器励磁涌流的新方法.该方法利用EMD将数据分解成有限个IMF(Intrinsic Mode Function),定义并计算各个IMF在X轴上的投影面积Sc、Simf的比重系数Kc及其最大值Kmax.在比较励磁涌流和故障电流Kmax不同特点的基础上,提出了一种变压器保护新方案.理论分析及动模实验结果表明,该方法能够正确区分励磁涌流及故障电流,其判断时间约20ms;方法实现方便,不受非周期分量等影响.     

IRS辅助的SWIPT系统中基于能效优先的波束成形设计与优化

以智能反射面(intelligent reflecting surface,IRS)辅助的无线携能通信(simultaneous wireless information and power transfer,SWIPT)系统为背景,研究了该系统中基于能效优先的多天线发送端有源波束成形与IRS无源波束成形联合设计与优化方法。以最大化接收端的最小能效为优化目标,构造在发送端功率、接收端能量阈值、IRS相移等多约束下的非线性优化问题,用交替方向乘子法(alternating direction method of multipliers,ADMM)求解。采用Dinkelbach算法转化目标函数,通过奇异值分解(singular value decomposition,SVD)和半定松弛(semi-definite relaxation,SDR)得到发送端有源波束成形向量。采用SDR得到IRS相移矩阵与反射波束成形向量。结果表明,该系统显著降低了系统能量收集(energy harvesting,EH)接收端的能量阈值。当系统总电路功耗为−15 dBm时,所提方案的用户能效为300 KB/J。当IRS反射阵源数与发送天线数均为最大值时,系统可达最大能效。     

谐振器加载石墨烯的双通带可调滤波衰减器设计

石墨烯材料在微波段的阻抗可控特性是其最有价值的应用特性之一。文中首次分析了石墨烯对微带 多模谐振的影响机理,提出了一种集成滤波衰减功能为一体的灵活可控器件。首先,对不同位置加载石墨烯的微带双 模谐振器进行了严格的等效电路建模,通过奇偶模分析法及输入导纳参数计算,探究了双模谐振受石墨烯阻抗及其加 载位置的影响,明晰了石墨烯材料对微波谐振器的影响。随后设计了动态可调的滤波衰减器并阐述了石墨烯材料在谐 波控制上的潜在应用点。最后,采用不同尺寸的双模谐振器进行石墨烯加载并完成双通带幅度独立可控的滤波衰减器 的设计,仿真与实测结果吻合良好,验证了阻抗可控石墨烯材料在可调微波衰减类器件上的应用前景。     

光纤光栅在高功率连续光纤激光器中的发展及展望

目前光纤光栅在高功率连续光纤激光器中的应用主要有两个方面,一是作为谐振腔腔镜,二是用来抑制激光器的非线性效应。首先论述了光纤光栅作为腔镜技术的发展现状,然后着重论述了能够抑制光纤激光器中非线性效应的特殊光纤光栅的发展状况。并详细描述了倾斜布拉格光纤光栅抑制受激拉曼散射和受激布里渊散射、长周期光纤光栅抑制受激拉曼散射以及相移长周期光纤光栅抑制自相位调制或四波混频等非线性效应引起的光谱展宽的研究进展。最后展望了光纤光栅在高功率光纤激光器领域的发展趋势,认为光纤光栅将朝着更高承载功率与长波长方向发展,同时认为基于飞秒激光刻写的光纤光栅技术、能够同时抑制多种非线性效应的光纤光栅技术、以及基于光纤光栅的光纤激光器激光偏振控制技术等将成为新的研究热点。     

全固化微脉冲Nd:YVO4激光器的研究

本文利用尾纤输出的半导体激光器泵浦Nd：YVO4激光晶体，获得连续的1064nm激光输出；进行腔内Cr^4 ：YAG晶体调Q和KTP晶体腔内倍频，获得了脉宽约40ns、平均功率107mw、重复率12kHz的532nm微脉冲激光输出。     

STUDY ON PHASE PERCEPTION IN SPEECH

The perceptual effect of the phase information in speech has been studied by auditory subjective tests. On the condition that the phase spectrum in speech is changed while amplitude spectrum is unchanged, the tests show that: (1) If the envelop of the reconstructed speech signal is unchanged, there is indistinctive auditory perception between the original speech and the reconstructed speech; (2) The auditory perception effect of the reconstructed speech mainly lies on the amplitude of the derivative of the additive phase; (3) td is the maximum relative time shift between different frequency components of the reconstructed speech signal. The speech quality is excellent while td <10ms; good while 10ms< td <20ms; common while 20ms< td <35ms, and poor while td >35ms.     

感应电机全阶状态观测器及其无源性转速控制

为了实现感应电机的高动态调速性能,针对电机的非线性本质,提出了一种基于全阶状态观测器及其转速自适应估算的感应电机无源性转速控制方案。在基于感应电机无源性与稳定性分析的基础上,设计了渐近稳定转矩跟踪无源性控制器。针对无源控制律所需转子电流难以观测的问题,提出了一种旋转坐标系下以转子电流和转子磁链为状态变量的全阶状态观测器,并应用该观测器对转速进行估算,实现了感应电机无速度传感器的无源性转速控制。仿真结果表明该控制方法易于实现,采用全阶观测器观测转子电流值和估算转速值更为准确,显著提高了感应电机的动静态性能。