Modification of Nafion membranes by incorporation of cationic polymers for reduction of methanol permeability

A small amount of basic polymer was incorporated in the Nafion membrane. Compared with the re-cast Nafion membrane, the Nafion/basic polymer membrane reduced the methanol permeability considerably. The equilibrium water uptake and proton conductivity decreased, but the thermal and mechanical stability was enhanced with increasing concentration of basic polymer. These property changes were caused by formation of cation/anion complex between acidic Nafion and basic polymer molecules. The effects of the types and molecular weights of basic polymers on the methanol permeability and proton conductivity were not significant.     

Catalytic Degradation of Nitrobenzene and Aniline in Presence of Ozone by Magnesia from Natural Mineral

In this work, magnesia from natural brucite mineral has been used firstly for catalytic degradation of nitrobenzene and aniline in presence of ozone. Compared with single ozonation, the catalytic ozonation accelerated markedly the degradation of nitrobenzene and aniline. The influences of hydroxyl radical scavengers, pH values, and reaction temperatures on degradation were investigated. It was found that the essential of catalysis was the homogeneous catalysis of hydroxyl ions in water, which accelerated the generation of hydroxyl radicals. As a catalyst, magnesia from natural brucite has supplied an economical and feasible choice for catalytic ozonation of nitrobenzene and aniline in industrial wastewater.     

Transformation of Crystal Phase of Micron-sized Rutile TiO2 and Investigation on its Sonocatalytic Activity

The partial transformation of crystal phase of micron-sized TiO₂ powder from rutile to anatase was realized utilizing microwave irradiation in hydrogen peroxide solution. Afterwards, the ultrasound of low power was used as an irradiation source to induce the transition crystal TiO₂ powder to perform the sonocatalytic activity through the degradation of azo fuchsine in aqueous solution. The results show that the sonocatalytic activity of the transition crystal TiO₂ powder is obviously higher than that of pure micron-sized rutile and anatase TiO₂ powders. The degradation ratio of azo fuchsine in the presence of the transition crystal TiO₂ powder attains nearly 80% within 80 min ultrasonic irradiation.     

Promotional effect of Ce on the activity of In/W–ZrO2 for selective reduction of NO x with methane

The Ce modified In/W–ZrO₂ catalysts were prepared by impregnation and mechanical mix method. Their activities for SCR of NO _x with methane were investigated. The activity of the In/W–ZrO₂ catalyst was enhanced by addition of Ce with both methods, while the promotional effect was more pronounced for catalyst prepared by mechanical mix method compared to impregnation method. The function of Ce was to improve the oxidation of NO to NO₂. The maximum NO _x conversion over the mechanical mixed catalyst can be stabilized at 74% at 450 °C in a dry gas flow and 37% at 500 °C in wet flow (24,000 h⁻¹). For the impregnated catalysts, Ce was found to compete with In to adsorb on strong acid site over W–ZrO₂ support and inhibited the formation of InO⁺, which resulted in the lower activity of these catalysts than mechanical mixed catalysts.     

石英陶瓷注凝成型影响因素的研究

介绍了熔融石英陶瓷的注凝成型机理及其工艺过程,分析讨论了影响熔融石英陶瓷注凝成型的主要因素,通过研究确定了合理的制备工艺参数.     

基于弹塑性有限单元法的齿轮轴数值模拟

基于弹塑性有限单元法的一般原理,建立了齿轮轴热处理的热力耦合分析模型,对12Cr齿轮轴热处理工艺中温度、应力以及相变的分布情况进行了模拟,研究了加热规范的成形性,并与实际结果比较证实本模型的有效性,为有限单元法在热处理工艺模拟中的应用奠定了一定基础。     

模具绿色制造过程探讨

介绍了当前模具绿色制造的基本概念和五个主要阶段中需要注意的一些技术性问题，最后对今后整个社会的绿色制造概念推广提出了一些建设性的建议。     

EAF-CSP流程铌微合金化管线钢的连铸工艺

基于珠钢采用铌微合金化技术成功地开发了管线钢X52和X56的事实,结合CSP薄板坯连铸工艺特点,探索出一套适合含铌钢薄板坯连铸的浇注温度制度、结晶器保护渣、连铸拉速和结晶器热流密度匹配及二次冷却曲线等工艺控制技术.     

铝合金双面搅拌摩擦焊初步研究

提出了双面搅拌摩擦焊这种新的焊接方法，对比研究了6K32-T4铝合金搅拌摩擦焊与双面搅拌摩擦焊接头的组织和硬度，并对双面搅拌摩擦焊焊缝进行了XRD分析。研究发现：铝合金双面搅拌摩擦焊与搅拌摩擦焊焊缝组织分区相同；双面搅拌摩擦焊焊缝的硬度略低于搅拌摩擦焊，且焊缝硬度下降区域范围更大；双面搅拌摩擦焊后焊缝依然保持为原有相组成；双面搅拌摩擦焊比搅拌摩擦焊焊接线能量更大，采用双面搅拌摩擦焊代替搅拌摩擦焊有利于提高焊接效率并消除焊缝隧道型缺陷、改善焊缝的性能。     

B对Al-13Si-0.3Mg合金流动性的影响

采用浇注螺旋型试样的方法测量了B对Al-13Si-0．3Mg合金流动性的作用；并通过温度校正的方法校正了浇注温度的误差对测量结果的影响。研究发现随B含量的增加，合金的流动性明显提高。采用对凝固中期的合金进行液淬的方法研究了该合金的凝固方式。根据合金凝固后的组织及合金凝固的方式分析了B影响Al-13Si-0．3Mg合金流动性的原因。