Synthesis and electroluminescent properties of π-conjugated copolymer based on 10-hexylphenothiazine and aromatic 1,2,4-triazole

A new polymer, poly((10-hexyl-3,7-phenothiazine)-alt-(4-(4-butyl-phenyl)-3,5-diphenyl-4H-[1,2,4]triazole)-3,5-diyl) (PT-TAZ), has been synthesized. In order to improve electron injection/transporting ability, we introduce electronegative 1,2,4-triazole group in the backbone. We also synthesized poly(10-hexylphenothiazine-3,7-diyl) (PT) to compare the physical properties with PT-TAZ. The photoluminescence (PL) maximum wavelength, the band gap energy, and the HOMO energy level of PT-TAZ film were 509 nm, 2.67 eV, and −5.06 eV, respectively, which are very comparable to those of PT. The maximum efficiency and brightness of the electroluminescent (EL) device based on PT-TAZ were 0.247 cd/A and 771 cd/m², respectively, which were significantly higher than those of the device based on the polymer without 1,2,4-triazole (TAZ) as a repeat unit (PT) (1.05 × 10⁻⁴ cd/A and 4.4 cd/m²). This is because TAZ unit improves the electron transporting ability in the emissive layer. The turn-on voltage of brightness of the device based on PT-TAZ was 5.0 V, which was slightly higher than that of the based on PT (4.5 V). This is because the ionization potential of PT-TAZ is very similar to that of PT.     

Sliding mode control of a shear-mode type ER engine mount

This paper presents feedback control characteristics of a shear-mode type electro-rheological (ER) engine mount. The field-dependent yield stress of an arabic gum-based ER fluid is obtained using a couette type electroviscometer, and it is incorporated into the governing equation of motion of the ER engine mount, which is derived from a bond graph model. A sliding mode controller which directly represents the field-dependent damping force is formulated by taking into account the stiffness and damping properties of the systems as parameter uncertainties. The controller is then experimentally realized by imposing a semi-active actuating condition. The effectiveness of the proposed ER engine mount is demonstrated showing capabilities of isolating the vibrations due to sinusoidal and random excitations.     

A case study on detection and sizing of defects in steam generator tubes using eddy current testing

Eddy current testing (ECT) method is widely used to detect various types of defects occurring in nuclear steam generator tubes. Therefore, the reliability of its detection and sizing accuracy for defects should be validated. For this purpose, two tubes with defect signals were pulled from an operating steam generator and destructively examined. The defect type was a circumferential crack for one tube and an intergranular attack (IGA) for the other tube. The plus point coil probe showed a better capability to detect and size both a circumferential crack and a volumetric IGA than pancake and bobbin coil probe. The destructive results are correlated with the ECT results obtained during the in-service inspection.     

An experimental study of the mean effective strain in rod (or bar) rolling process

This paper presents an experimental study that investigates the validity of the analytical model [9] for predicting the mean effective strains associated with bar (or rod) rolling. Designed for this purpose were plate and bar rolling experiments which consist of a four-pass groove (oval and round) rolling sequences, which have material at each pass that experience the same amount of mean effective strain. The microstructure and mechanical behaviors of specimens acquired from two types of rolling experiments at 650°C were compared. A parallelism between the mechanical behaviors of a plate-rolled specimen and a bar-rolled specimen has been found at each pass. We therefore concluded that the analytical model has the underlying rationale to be used in the analysis of the rod (or bar) rolling process.     

Big Brother Has Been Here All Along.

As a management consultant with a company who create products for E-businesses in the field of secure data exchange, I am constantly asked for my views on the RIP Bill. As most of you will know, RIP stands for ‘Regulation of Investigatory Powers’, and the Bill is designed to allow MI5 to monitor information exchanged over the Internet.     

Enhanced soft subspace clustering integrating within-cluster and between-cluster information

While within-cluster information is commonly utilized in most soft subspace clustering approaches in order to develop the algorithms, other important information such as between-cluster information is seldom considered for soft subspace clustering. In this study, a novel clustering technique called enhanced soft subspace clustering (ESSC) is proposed by employing both within-cluster and between-class information. First, a new optimization objective function is developed by integrating the within-class compactness and the between-cluster separation in the subspace. Based on this objective function, the corresponding update rules for clustering are then derived, followed by the development of the novel ESSC algorithm. The properties of this algorithm are investigated and the performance is evaluated experimentally using real and synthetic datasets, including synthetic high dimensional datasets, UCI benchmarking datasets, high dimensional cancer gene expression datasets and texture image datasets. The experimental studies demonstrate that the accuracy of the proposed ESSC algorithm outperforms most existing state-of-the-art soft subspace clustering algorithms.     

A novel algorithm for estimation of depth map using image focus for 3D shape recovery in the presence of noise

Three-dimensional shape recovery from one or multiple observations is a challenging problem of computer vision. In this paper, we present a new Focus Measure for the estimation of a depth map using image focus. This depth map can subsequently be used in techniques and algorithms leading to the recovery of a three-dimensional structure of the object, a requirement of a number of high level vision applications. The proposed Focus Measure has shown robustness in the presence of noise as compared to the earlier Focus Measures. This new Focus Measure is based on an optical transfer function implemented in the Fourier domain. The results of the proposed Focus Measure have shown drastic improvements in estimation of a depth map, with respect to the earlier Focus Measures, in the presence of various types of noise including Gaussian, Shot, and Speckle noises. The results of a range of Focus Measures are compared using root mean square error and correlation metric measures.     

Frequency domain lifetime characterization

Time-based measurements are commonly used for lifetime characterization of semiconductors. We have developed the theory, verified by experiment, of frequency-based lifetime characterization as an alternative to time-based measurements for MOS devices biased in inversion. One consideration during lifetime/diffusion length measurements, is whether the near-surface space-charge region or the bulk or quasineutral region is characterized. To characterize the near-surface space-charge region of the device, one usually makes room temperature pulsed MOS capacitor or diode leakage current measurements. We show that room-temperature, frequency-domain capacitance, conductance, or resistance measurements characterize the quasineutral bulk, not the space charge region, in contrast to room-temperature pulsed MOS-C or diode leakage current measurements which characterize the space-charge region     

Kinetic and mechanistic evaluation of tetrahydroborate ion electro-oxidation at polycrystalline gold

The anodic oxidation of tetrahydroborate ion is studied in NaOH at stationary and rotating polycrystalline Au disk electrodes. Linear sweep and cyclic voltammetry are applied varying the scan and rotation rate from 0.005 to 51.200 V s⁻¹ and from 52.3 to 314.1 rad s⁻¹, correspondingly. The effects of variation of BH₄⁻ and NaOH concentrations as well as of the potential limits of the ranges studied have been initially followed. Most of the experiments have been carried out with 10.9 mM NaBH₄ in 1.04 M NaOH at 293 K in the potential range from −1.300 to 0.900 V (vs. Ag/AgCl). It is found that 6 electrons are exchanged in the overall oxidation transformation. The kinetic analysis of the processes determining the two anodic peaks recorded under static conditions at scan rates lower than 0.500 V s⁻¹ shows that 1.4 electrons are exchanged in the potential range of the first one (at ca −0.5 V), while the rate of the second one (at ca +0.3 V) is determined by a quasi-reversible 1-electron transfer reaction. A kinetic evidence for the participation of surface bound intermediates in the electro-oxidation process is provided. Two additional well outlined anodic peaks are recorded in the aforementioned potential range under specific experimental conditions. A quasi-8 electron mechanism involving four oxidation and hydrolysis steps is advanced to explain the experimental results. It accounts for the involvement of borohydride oxidation species and the Au⁺/Au³⁺ mediator couple.     

Signal characteristics of differential-pulsed eddy current sensors in the evaluation of plate thickness

Differential-pulsed eddy current (PEC) signals and their characteristics are investigated as tools for the evaluation of plate thickness by using the reflection-type PEC probe, which consists of an exciter coil and two sensor coils in a differential arrangement. Numerical and experimental signals are first compared to validate numerical simulation results, and good agreement between them is achieved. Investigation of differential PEC signals and their characteristics against thickness and conductivity variations shows that time-related features, such as the time-to-peak and the zero-crossing time, correspond well to plate thickness and conductivity. However, the feature quality of peak value turns out to be very poor. To improve this, the effects of coil characteristics on the input pulse, and consequently on differential PEC signals, are investigated. Results show that the feature quality of peak value may be improved by reducing the time constant, but doing so would worsen the quality of the other two features. Lift-off signals obtained by this probe show that the lift-off point of intersection also appears in the differential reflection-type PEC signals.