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21.
Alper Sarıoğlan Ömer Tunç Savaşçı Ayşe Erdem-Şenatalar Vu Thu Ha Gilbert Sapaly Younès Ben Taârit 《Catalysis Letters》2007,118(1-2):123-128
MFI type inorganic carrier was used in two different cationic forms, hydrogen and calcium respectively. MFI-supported molybdenum
and rhenium catalysts were prepared. The activities of the catalysts were compared for the aromatization reaction of methane.
Higher activity values were attained with the catalysts supported on HZSM-5. Aromatics were also observed with the catalysts
supported on CaZSM-5, despite their deficiency in acid sites. Highly dispersed rhenium is expected to be formed with the use
of the inorganic carrier in calcium form. On the other hand, lower reaction rates were observed with rhenium supported on
CaZSM-5, in spite of the improved dispersion of the active rhenium species on this catalyst. This was interpreted in terms
of the critical role of the acid sites in the conversion of methane to aromatics, compared to the improved dispersion of the
active metal. 相似文献
22.
Hong-Gi Lee Jung Youn Lee Kyung-Duk Kim Hoon Kang 《International Journal of Control, Automation and Systems》2014,12(5):1124-1130
Unlike the continuous-time case, algebraic necessary and sufficient conditions for a single output discrete-time system to be state equivalent to a nonlinear observer canonical form have been found and are easier to verify for those who are not accustomed to differential geometry. The geometric conditions look very different from the algebraic conditions. In this paper, we show direct equivalence of the geometric conditions and the algebraic conditions in order to enhance the understanding of the geometric conditions. 相似文献
23.
This paper deals with the triple-diffusive boundary layer flow of nanofluid over a nonlinear stretching sheet. In this model, where binary nanofluid is used, the Brownian motion, thermophoresis, and cross-diffusion are classified as the main mechanisms, which are responsible for the enhancement of the convection features of the nanofluid. The boundary layer equations governed by the partial differential equations are transformed into a set of ordinary differential equations with the help of group theory transformations, which is introduced by Blasius (The boundary layers in fluids with little friction, 1950). The variational finite element method is used to solve these ordinary differential equations. We have examined the effects of different controlling parameters, namely the Brownian motion parameter, the thermophoresis parameter, modified Dufour number, nonlinear stretching parameter, Prandtl number, regular Lewis number, Dufour Lewis number, and nanofluid Lewis number on the flow field and heat transfer characteristics. The physics of the problem is well explored for the embedded material parameters through tables and graphs. The present study has many applications in coating and suspensions, movement of biological fluids, cooling of metallic plate, melt-spinning, heat exchangers technology, and oceanography. 相似文献
24.
Stereological measurements were performed to characterize the indentation crack path in a cubic zirconia-10 vol% alumina (c-ZrO2 -10 vol% Al2 O3 ) composite. Cracks were generated using Vickers indentation, and the crack propagation behavior was characterized as a function of the indentation loading/unloading rates. Cracks that were produced by Vickers indentation formed at higher crack velocities as the loading/unloading rates increased. The amount of contact between the crack and the Al2 O3 particles increased as the indentation rate decreased. The total number of crack-particle interactions per unit crack length also increased as the indentation rate decreased, because of an increase in the number of particles that were fractured per unit crack length, whereas the number of particles that were debonded remained relatively constant as the indentation rate changed. These results suggest that residual thermal mismatch stresses have predominant control of the crack path at lower crack velocities (low indentation loading/unloading rate), whereas elastic mismatch stresses predominate at higher crack velocities (high indentation loading/unloading rate). 相似文献
25.
Sang Bong Lee Eun Kyoung Park Youn Mook Lim Seong Kwan Cho So Yeon Kim Young Moo Lee Young Chang Nho 《应用聚合物科学杂志》2006,100(6):4439-4446
Semi‐interpenetrating polymer network (semi‐IPN) and fully interpenetrating polymer network (full‐IPN) hydrogels composed of alginate and poly(N‐isopropylacrylamide) were prepared with γ‐ray irradiation. The semi‐IPN hydrogels were prepared through the irradiation of a mixed solution composed of alginate and N‐isopropylacrylamide (NIPAAm) monomer to simultaneously achieve the polymerization and self‐crosslinking of NIPAAm. The full‐IPN hydrogels were formed through the immersion of the semi‐IPN film in a calcium‐ion solution. The results for the swelling and deswelling behaviors showed that the swelling ratio of semi‐IPN hydrogels was higher than that of full‐IPN hydrogels. A semi‐IPN hydrogel containing more alginate exhibited relatively rapid swelling and deswelling rates, whereas a full‐IPN hydrogel showed an adverse tendency. All the hydrogels with NIPAAm exhibited a change in the swelling ratio around 30–40°C, and full‐IPN hydrogels showed more sensitive and reversible behavior than semi‐IPN hydrogels under a stepwise stimulus. In addition, the swelling ratio of the hydrogels continuously increased with the pH values, and the swelling processes were proven to be repeatable with pH changes. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4439–4446, 2006 相似文献
26.
Modeling of time to corrosion-induced cover cracking in reinforced concrete structures 总被引:1,自引:0,他引:1
Service life of the concrete structures depends on the protective action provided by the cover concrete against the susceptibility of the reinforcement to the corrosive environment. Depending on the level of the oxidation of metallic iron, corrosion products may have much greater volume than the original iron that gets consumed by the process of corrosion. This volume expansion is mainly responsible for exerting the expansive radial pressure at the steel-concrete interface and development of hoop tensile stresses in the surrounding concrete resulting ultimately in the through cracking of the cover concrete. This cover cracking would indicate the loss of the service life for the corrosion-affected structures. In the present paper, an attempt has been made to develop analytical models for predicting the time to cover cracking by considering the residual strength of the cracked concrete and the stiffness provided by the combination of the reinforcement and expansive corrosion products. The problem is modeled as a boundary value problem wherein the governing equations are expressed in terms of the radial displacement and the analytical solutions are presented considering a simple 2-zone model for the cover concrete viz. cracked or uncracked. The analytical models are then evaluated through their ability to reproduce available experimental trends and subsequently a sensitivity analysis has also been carried out to show the influence of the various variable parameters of the proposed models with reference to the experimental trends. 相似文献
27.
Jong-Hyun Hwang Myoung-Seoup Han Dae-Young Kim Joong-Geun Youn 《Journal of Materials Engineering and Performance》2006,15(3):328-335
High-temperature wear characteristics between plasma spray coated piston rings and cylinder liners were investigated to find
the optimum combination of coating materials using the disc-on-plate reciprocating wear test in dry conditions. The disc and
plate represented the piston ring and the cylinder liner, respectively. Coating materials studied were Cr2O3-NiCr, Cr2O3-NiCr-Mo, and Cr3C2-NiCr-Mo. Plasma spray conditions for the coating materials were established adjusting stand-off distance to obtain a coating
with a porosity content of ∼5%. It was found that a dissimilar coating combination of Cr2O3-NiCr-Mo and Cr3C2-NiCr-Mo provided the best antiwear performance. The addition of molybdenum was found to be beneficial to improve the wear
resistance of the coating. Hardness differences between mating surfaces were also important factors in determining the wear
characteristics, so that it should be controlled below 300 in Vickers hardness under dry conditions. Adhesive wear accompanying
with metal transfer was a dominant wear mechanism for dry conditions. 相似文献
28.
29.
In this paper, we explore the issue of static routing and spectrum/IT resource assignment (RSIA) of elastic all-optical switched intra-datacenter networks (intra-DCNs) by proposing anycast- and manycast-based integer linear programming (ILP) models. The objective is to jointly optimize the DCN resources, i.e., network transmission bandwidth and IT resources, under different situations. First, for given service-request matrices with unknown network transmission bandwidth and IT resources, we propose anycast and manycast ILP models to minimize the maximum numbers of required network and IT resources to accommodate all the service requests. For anycast RSIA issue, we proposed two different ILP models that are based on node-arc and link-path methods, respectively. Node-arc based manycast ILP model is also proposed for the first time to our knowledge. Second, for given network transmission bandwidth and IT resources and known service-request matrices, we propose node-arc based anycast ILP models to maximize the total number of successfully served service requests. To evaluate the efficiency of anycast and manycast models, all proposed ILP models are evaluated and compared with unicast ILP models. Simulation results show that anycast and manycast ILP models perform much better in efficiently using DCN resources and successfully accommodating more service requests when compared to unicast ILP models under the same network conditions. 相似文献
30.
Youn‐Gyoung Chang Seong‐Hee Nam Nam‐Kook Kim Yun‐Ho Kook Jinook Kim Soon‐Sung Yoo Chang‐Dong Kim In‐Byeong Kang In‐Jae Chung 《Journal of the Society for Information Display》2009,17(4):301-307
Abstract— Recently, potential breakthrough technologies for low‐cost processing of TFT‐LCDs and new process developments for flexible‐display fabrication have been widely studied. A roll‐printing process using etch‐resist material as a replacement for photolithographic patterning was investigated. The characterization of the properties of patterns formed in roll printing, a method to fabricate cliché plates for fine patterns, and the design of a new formulation for resist printing ink is reported. The pattern position accuracy, which is one of the most important issues for the successful application of printing processes in display manufacturing was studied and how it can be improved by optimizing the blanket roll structure is explained. New design rules for the layout of the thin‐film‐transistor array was derived to improve the compatibility of roll printing. As a result, a prototype 15‐in.‐XGA TFT‐LCD panel was fabricated by using printing processes to replace all the photolithographic patterning steps conventionally used. 相似文献