Visible PL Phenomenon at Room Temperature in Disordered Structure of SrWO4 Powder

The SrWO₄ (SWO) powders were synthesized by the polymeric precursor method and annealed at different temperatures. The SWO structure was obtained by X-ray diffraction and the corresponding photoluminescence (PL) spectra was measured. The PL results reveal that the structural order–disorder degree in the SWO lattice influences in the PL emission intensity. Only the structurally order–disordered samples present broad and intense PL band in the visible range. To understand the origin of this phenomenon, we performed quantum-mechanical calculations with crystalline and order–disordered SWO periodic models. Their electronic structures were analyzed in terms of band structure. The appearance of localized levels in the band gap of the order–disordered structure was evidenced and is a favorable condition for the intense PL to occur.     

Measurement uncertainties arising from unpowered shipment of dcvoltage references

We have measured the hysteresis in output voltage arising from loss of power for three Fluke 732B dc voltage references. Continuously powering the internal temperature-controlled oven provides the best accuracy with such Zener-diode-based dc voltage references. Batteries are used to provide power continuity when shipping between laboratories. We have shown that for these particular instruments, an apparent hysteresis induced by humidity is likely to dominate any hysteresis arising from loss of battery power when transit between laboratories takes three days or more. Our conclusion is that as much, if not more, care needs to be taken when dealing with humidity than with loss of battery power when shipping between laboratories. When the highest accuracy of dc voltage comparison is required, it becomes necessary to apply voltage corrections using the measured values of humidity coefficients and the relative humidity occurring during transit     

Effects of dietary α-linolenic acid on the fatty acid composition, storage stability and sensory characteristics of pork loin

Effects of dietary α-linolenic acid on the fatty acid composition, storage stability and sensory characteristics of cooked pork were studied. Dietary α-linolenic acid (LNA) significantly (p < 0.05) increased the proportion of n−3 fatty acids and the degree of unsaturation in the neutral lipids and phospholipids. The increases in n−3 fatty acids were observed in the total lipids, triglycerides, phosphatidylethanolamine and phosphatidylcholine, and mainly consisted of C18:3n3, C20:5n3 and/or C22:5n3.The thiobarbituric acid reactive substances (TBARS) values (mg malondialdehyde per kg meat) of cooked vacuum packaged loins remained below 1.5, but in loose packaged loins TBARS values increased more than 3 times those of 0 time values during 2-day storage at 4 °C. The TBARS values of loins after LNA-enrichment were significantly higher than those of the control in both vacuum and loose packaging, and the increase of unsaturation in fatty acids had a strong prooxidant effect. The increase in dietary LNA enrichment increased oxidation (TBARS values) and had a detrimental effect on the acceptability of cooked pork loins held for 2 days in loose packaging.     

An augmented EDA with dynamic diversity control and local neighborhood search for coevolution of optimal negotiation strategies

In this paper, we present an estimation of distribution algorithm (EDA) augmented with enhanced dynamic diversity controlling and local improvement methods to solve competitive coevolution problems for agent-based automated negotiations. Since optimal negotiation strategies ensure that interacting agents negotiate optimally, finding such strategies—particularly, for the agents having incomplete information about their opponents—is an important and challenging issue to support agent-based automated negotiation systems. To address this issue, we consider the problem of finding optimal negotiation strategies for a bilateral negotiation between self-interested agents with incomplete information through an EDA-based coevolution mechanism. Due to the competitive nature of the agents, EDAs should be able to deal with competitive coevolution based on two asymmetric populations each consisting of self-interested agents. However, finding optimal negotiation solutions via coevolutionary learning using conventional EDAs is difficult because the EDAs suffer from premature convergence and their search capability deteriorates during coevolution. To solve these problems, even though we have previously devised the dynamic diversity controlling EDA (D²C-EDA), which is mainly characterized by a diversification and refinement (DR) procedure, D²C-EDA suffers from the population reinitialization problem that leads to a computational overhead. To reduce the computational overhead and to achieve further improvements in terms of solution accuracy, we have devised an improved D²C-EDA (ID²C-EDA) by adopting an enhanced DR procedure and a local neighborhood search (LNS) method. Favorable empirical results support the effectiveness of the proposed ID²C-EDA compared to conventional and the other proposed EDAs. Furthermore, ID²C-EDA finds solutions very close to the optimum.     

Development of low-cost non-powered prosthesis using multi-axis system of toe joint and ankle

Journal of Mechanical Science and Technology - A prosthetic foot for a low-income class was developed. The prosthetic foot was produced through 3D printing, and a walking situation was produced and...     

Proportionally fair load balancing with statistical quality of service provisioning for aerial base stations

Aerial base stations (ABSs) seem promising to enhance the coverage and capacity of fifth-generation and upcoming networks. With the flexible mobility of ABSs, they can be positioned in air to maximize the number of users served with a guaranteed quality of service (QoS). However, ABSs may be overloaded or underutilized given inefficient placement, and user association has not been well addressed. Hence, we propose a three-dimensional ABS placement scheme with a delay-QoS-driven user association to balance loading among ABSs. First, a load balancing utility function is designed based on proportional fairness. Then, an optimization problem for joint ABS placement and user association is formulated to maximize the utility function subject to statistical delay QoS requirements and ABS collision avoidance constraints. To solve this problem, we introduce an efficient modified gray wolf optimizer for ABS placement with a greedy user association strategy. Simulation results demonstrate that the proposed scheme outperforms baselines in terms of load balancing and delay QoS provisioning.     

Arsenic microdistribution and speciation in toenail clippings of children living in a historic gold mining area

Arsenic is naturally associated with gold mineralisation and elevated in some soils and mine waste around historical gold mining activity in Victoria, Australia. To explore uptake, arsenic concentrations in children's toenail clippings and household soils were measured, and the microdistribution and speciation of arsenic in situ in toenail clipping thin sections investigated using synchrotron-based X-ray microprobe techniques. The ability to differentiate exogenous arsenic was explored by investigating surface contamination on cleaned clippings using depth profiling, and direct diffusion of arsenic into incubated clippings. Total arsenic concentrations ranged from 0.15 to 2.1 µg/g (n = 29) in clipping samples and from 3.3 to 130 µg/g (n = 22) in household soils, with significant correlation between transformed arsenic concentrations (Pearson's r = 0.42, P = 0.023) when household soil was treated as independent. In clipping thin sections (n = 2), X-ray fluorescence (XRF) mapping showed discrete layering of arsenic consistent with nail structure, and irregular arsenic incorporation along the nail growth axis. Arsenic concentrations were heterogeneous at 10 × 10 µm microprobe spot locations investigated (< 0.1 to 13.3 µg/g). X-ray absorption near-edge structure (XANES) spectra suggested the presence of two distinct arsenic species: a lower oxidation state species, possibly with mixed sulphur and methyl coordination (denoted As^≈ III_{(-S, -CH3)}); and a higher oxidation state species (denoted As^≈ V_(-O)). Depth profiling suggested that surface contamination was unlikely (n = 4), and XRF and XANES analyses of thin sections of clippings incubated in dry or wet mine waste, or untreated, suggested direct diffusion of arsenic occurred under moist conditions. These findings suggest that arsenic in soil contributes to some systemic absorption associated with periodic exposures among children resident in areas of historic gold mining activity in Victoria, Australia. Future studies are required to ascertain if adverse health effects are associated with current levels of arsenic uptake.     

Investigation of impact materials around Barringer Meteor Crater by SEM-EDX and micro-PIXE techniques

Impact materials collected at the Barringer Meteor Crater have been characterized by SEM-EDX and micro-PIXE techniques. Fine textural and true elemental images were created. As a main feature silica-bearing shell and an S–Fe–Ni–Cu core could be distinguished. Three different types of S–Fe–Ni–Cu systems were identified such as chalcopyrite, pentlandite and pyrrhotite.