Electrochemical properties of some cobalt antimonides as anode materi-als for lithium- ion batteries

Some cobalt antimonides have been prepared and studied as the candidate anode materials for lithium ion batter-ies. Reversible capacities of 424,423 and 546 mA·h·g-1 were measured at the first cycle for as-solidified CoSb2, CoSb3 and annealed CoSb3 respectively. A low lithium ions diffusion coefficient in the order of 10-16 m2·s-1 was estimated from the coulometric titration measurements in the annealed CoSb3 electrode. It was found that the electrochemical properties of fine powders are significantly better than coarse powders. However the SEM picture shows that the nano-sized CoSb3 powders gathered to larger granules, which worsens somewhat the capacity retention of the nano-sized materials, although the volume capacities of the annealed and ball milled CoSb3 remain near twice of that of graphite after 50 cycles.     

Preparation and characterization of TiO2 photoelectrode codoped with aluminum and boron and its application in dye-sensitized solar cell

Nanocrystalline titania films codoped with aluminum and boron were prepared by cathodic vacuum arc deposition. In the process, titanium alloy target was used under an O2/Ar atmosphere, and sensitization of films were carried out by natural dye-sensitized complex in anhydrous ethanol. The structure, surface morphology and UV-vis spectra of titania films codoped were measured by X-ray diffraction analysis, scanning electron microscopy and ultraviolet-visible spectrometer. Theas-deposited films are found to be amorphous. The films annealed were examinedto be of anatase structure with orientation along the (101) planes, the averagecrystal size is in the range between 41 and 45 nm. SEM results show that thereare some pores in the codoped titania films, the optical properties of the dye-sensitized films were also measured which reveals that the spectral responses of films shift to the visible region. Under simulated sunlight illumination, the overall energy conversion efficiency of dye-sensitized nanocrystalline solar cell is 0.9%.     

双端制动器惯性试验台的设计

随着我国汽车工业的迅猛发展,汽车产量不断增多,车速越来越高,对汽车制动性能要求也越来越高。汽车制动器是汽车上的重要设备,其质量的好坏影响着行车的安全。电惯量模拟是近几年兴起的一种比较先进的负载模拟方法,文章就制动器惯性试验台系统结构以及电惯量模拟的方法进行了比较详细的说明。     

CA6140车床数控改造中机械装置设计技巧

介绍了普通车床数控改造中机械装置的几个独特设计，使得数控车床纵向进给系统结构更简单、性能更可靠、装拆更方便。     

钻柄温挤成形及模具设计

介绍了钻柄温挤成形工艺及其模具设计。     

AVL树研究与实现

计算机最广为人知的优点之一是其能储存大量的数据,如今随着时代的发展,储存容量更是犹如日进千里一般极速扩展,大容量的硬盘、U盘早已随处可见。然而,要在巨大的数据中搜索出需要的内容却不是一件容易的事,由此,为了能减少在搜索储存数据上的开销,各种适应于不同访问搜索背景的数据结构应运而生。树,便是计算机学科中最基本的数据结构之一,提供了快速的储存和访问性能。该文探究了带有平衡条件的二叉查找树——AVL树的原理,并对其使用C语言进行了实现。     

锦屏二级水电站3#引水隧洞有盖重防渗固结灌浆试验

本文介绍了锦屏二级水电站3#引水隧洞有盖重防渗固结灌浆试验的施工方法和试验参数。通过防渗固结灌浆试验,总结出在灌浆施工中应及时采集的相关信息和采取的施工工艺,既保证了施工质量又保证了施工速度     

An empirical molecular docking study of a di-iron binding protein with iron ions

Various molecular docking software packages are available for modeling interactions between small molecules and proteins.However,there have been few reports of modeling the interactions between metal ions and metalloproteins.In this study,the AutoDock package was employed to example docking into a di-iron binding protein,bacterioferritin.Each binding site of this protein was tested for docking with iron ions.Blind docking experiments showed that all docking conformations converged into two clusters,one for internal iron binding in sites within the metalloprotein and the other for external iron binding on the protein surface.Local docking experiments showed that there were significant differences between two internal iron binding sites.Docking at one site gave a reasonable root-mean-square deviation(RMSD) distribution with relatively low binding energy.Analysis of the binding mode quality for this site revealed that more than half of the docking conformations were categorized as having good binding geometry,while no good conformations were found for the other site.Further investigations indicated that coordinating water molecules contributed to the stability of binding geometries.This study provides an empirical approach towards the study of molecular docking in metalloproteins.     

基于SSH的住宅小区电子商务平台方案设计

为了促进住宅小区电子商务平台建设,提出一种基于J2EE和SSH架构的解决方案,引入了JQuery、AJAX等前台开发技术,以提高开发效率和提升客户体验,同时采用基于角色的访问控制、日志器等安全技术,充分保证系统安全性。     

OFDM精细定时同步算法性能分析

在OFDM系统中,定时同步估计的精度直接影响到了系统的整体性能.目前尚无文献对OFDM系统的精细定时算法进行理论分析,其性能基本都是通过仿真得到,不便于对OFDM系统性能进行理论分析.本文对瑞利信道下基于PN序列自相关特性的精细定时同步算法性能进行了理论分析,得到了精细定时误差的概率密度函数,与仿真得到的概率密度函数基本一致.