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991.
992.
Min Wei Li‐Guo Sun Zhuo‐Ying Xie Jin‐Fang Zhii Akira Fujishima Yasuaki Einaga De‐Gang Fu Xue‐Mei Wang Zhong‐Ze Gu 《Advanced functional materials》2008,18(9):1414-1421
Negatively charged gold nanoparticles (AuNPs) and a polyelectrolyte (PE) have been assembled alternately on a polystyrene (PS) colloid by a layer‐by‐layer (LBL) self‐assembly technique to form three‐dimensional (Au/PAH)4/(PSS/PAH)4 multilayer‐coated PS spheres (Au/PE/PS multilayer spheres). The Au/PE/PS multilayer spheres have been used to modify a boron‐doped diamond (BDD) electrode. Cyclic voltammetry is utilized to investigate the properties of the modified electrode in a 1.0 M KCl solution that contains 5.0 × 10?3 M K3Fe(CN)6, and the result shows a dramatically decreased redox activity compared with the bare BDD electrode. The electrochemical behaviors of dopamine (DA) and ascorbic acid (AA) on the bare and modified BDD electrode are studied. The cyclic voltammetric studies indicate that the negatively charged, three‐dimensional Au/PE/PS multilayer sphere‐modified electrodes show high electrocatalytic activity and promote the oxidation of DA, whereas they inhibit the electrochemical reaction of AA, and can effectively be used to determine DA in the presence of AA with good selectivity. The detection limit of DA is 0.8 × 10?6 M in a linear range from 5 × 10?6 to 100 × 10?6 M in the presence of 1 × 10?3 M AA. 相似文献
993.
Po‐Wen Chung Rajeev Kumar Marek Pruski Victor S.‐Y. Lin 《Advanced functional materials》2008,18(9):1390-1398
A series of poly(N‐isopropylacrylamide)‐coated mesoporous silica nanoparticle materials (PNiPAm‐MSNs) has been synthesized by a surface‐initiated living radical polymerization with a reversible addition–fragmentation chain transfer (RAFT) reaction. The structure and the degree of polymerization of the PNiPAm‐MSNs has been characterized by a variety of techniques, including nitrogen sorption analysis, 29Si and 13C solid‐state NMR spectroscopy, transmission electron microscopy (TEM), and powder X‐ray diffraction (XRD). The thermally induced changes of the surface properties of these polymer‐coated core–shell nanoparticles have been determined by examining their partition activities in a biphasic solution (water/toluene) at different temperatures. 相似文献
994.
Multicomponent hybrid nanostructures that contain two or more nanometer‐scale components have attracted much attention recently owing to the synergistic properties induced by interactions between these different nanometer‐scale objects. Herein, we give an overview of the efforts to synthesize multicomponent nanoparticles with at least one component being magnetic, and focus on our recent developments. The syntheses are based on heterogeneous nucleation and growth of a second and third component onto seed nanoparticles. These multicomponent nanoparticles show interesting magnetic, magneto‐optical, plasmonic, and semiconducting properties that can be modulated by interfacial interactions between different nanocomponents. This opens up a new avenue to advanced multifunctional nanomaterials for device concepts and applications. 相似文献
995.
Efficient TiO2 Photocatalysts from Surface Hybridization of TiO2 Particles with Graphite‐like Carbon
Surface hybridization of TiO2 with graphite‐like carbon layers of a few molecular layers thickness yields efficient photocatalysts. Photoelectrochemical measurements confirm an electronic interaction between TiO2 and the graphite‐like carbon. A TiO2 photocatalyst with a carbon shell of three molecular layers thickness (~1 nm) shows the highest photocatalytic activity which is about two times higher than that of Degussa P25 TiO2 under UV light irradiation. The mechanism of the enhanced photocatalytic activity under UV irradiation is based on the high migration efficiency of photoinduced electrons at the graphite‐like carbon/TiO2 interface, which is due to the electronic interaction between both materials. In addition, a high activity under visible light irradiation is observed after graphite‐like carbon hybridization. TiO2's response is extended into the visible range of the solar spectrum due to the electronic coupling of π states of the graphite‐like carbon and conduction band states of TiO2. 相似文献
996.
Voltage contrast (VC) has been a powerful tool for the failure analysis of integrated circuits and multichip module. As the packing density of printed circuit board (PCB) is increasing, conventional failure analysis methods to detect open or short circuit in PCBs are no longer adequate, and voltage contrast method could be a method for this purpose. However, unlike the cases of integrated circuits and multichip module, there are many areas in PCB that will produce serious charging effect when examine under the scanning electron microscope. One of the areas is the presence of solder mask on PCB.This work examines the feasibility of using voltage contrast for PCB failure analysis. Specially designed PCB is used for experimentation, and it is found that positive bias on one track and zero bias on another copper track provide a better image contrast as compared to negative and zero biases on the tracks. Also, the variation of the image contrast with different spacing between inter copper tracks has studied. It is found that the variation depends on the presence of solder mask and its location. The variation can be very different for negative bias case as compared to the positive bias case.Finite element analysis is also performed to explain the experimental observations. All the observations can be well explained by the charging effect of the solder masks. The charging effect of solder mask is indeed very significant in affecting the image contrast, and it could reduce the contrast to almost zero in some cases. 相似文献
997.
采用直流电化学刻蚀方法制备扫描隧道显微镜钨针尖,研究了电化学刻蚀过程中NaOH溶液浓度、钨丝浸入长度和刻蚀电压对针尖形貌的影响。通过扫描电子显微镜(SEM)测量针尖曲率半径和针尖纵横比值,以表征针尖的尺寸和形状;通过能谱仪(EDS)分析针尖表面成分,以表征表面清洁度;通过场发射显微镜(FEM)得到Fowler-Nordheim (F-N)曲线来检测针尖发射性能。实验结果表明,当溶液浓度为2 mol/L、钨丝浸入长度为4 mm、刻蚀电压为3 V时,可以得到曲率半径约为100 nm、纵横比值为13的针尖,且表面无钨的氧化层。FEM结果显示当对针尖施加500 V的负偏压时,针尖可以稳定发射50 nA量级的电流,且针尖性能具有良好的一致性。 相似文献
998.
999.
1000.
提出了用状态变量法设计基于多端输出的电流控制第二代电流传输器(current controlled second generation current conveyor with muhiple outputs ,简记为MOCCCII)的新型多功能电流模式二阶滤波电路。该滤波电路所需元件较少,二阶滤波器仅需仅需3个MOCCCII、2个电容和1个电阻,无需元件匹配就能同时实现低通、带通、高通滤波输出。该电路所有的无源元件均接地,便于集成且与VLSI工艺兼容,且具有很低的灵敏度。该滤波器可用于通信、电子测量与仪器仪表的信号处理。PSPICE仿真结果与理论分析相吻合,验证了该方法的可行性。 相似文献