Synthesis and characterization of copolythiophene

Copolythiophenes (Co‐PTs), poly(3‐hexylthiophene‐co‐3‐thiophene carboxylic acid) (P3HT‐TCa), poly(3‐hexyloxylthiophene‐co‐3‐thiophene carboxylic acid) (P3HOT‐TCa), and poly(3‐phenylthiophene‐co‐3‐thiophene carboxylic acid) (P3PhT‐TCa), were synthesized by chemical oxidized polymerization to investigate the effect of copolymerization on the properties of polythiophenes (PTs). Gel permeation chromatography showed that the molecular weight (MW) of Co‐PT was lower than that of homopolythiophene. Fourier transform infrared (FTIR) spectra indicated that the copolymerization was successful between the monomers. The λ_max of Co‐PTs gave a “blue shift” in ultraviolet‐visible (UV‐VIS) spectra. Photoluminescence (PL) spectra showed that the PL intensity of Co‐PT became weaker than that of homopolythiophene and the disappearance of PL had been observed in P3HOT‐TCa. The thermal stability of Co‐PT was influenced by the carboxyl for its low decomposition temperature. Furthermore, the copolymerization between multi‐wall carbon nanotube containing thiophene ring (MWNT‐Th) and 3‐hexyloxylthiphene could also take place successfully. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Decentralized weighted control for a class of large‐scale systems with multi‐modes

In this paper, the control synthesis problem for a class of large‐scale systems with multi‐modes that are called large‐scale switched systems is addressed. By introducing the concept of decentralized switching signal and the relevant decentralized average dwell time, the asymptotic stability and weighted ?₂ gain performance are investigated. It should be noted that the decentralized switching covers general switching cases for large‐scale switched systems, namely, it admits both time‐dependent switching signal and arbitrary switching signal blended in the decentralized switching. Then, on the basis of the analysis results, the decentralized weighted control scheme including state feedback controller gains and switching signals is studied. Several design algorithms are proposed to meet different controller design problems. Finally, numerical examples are provided to illustrate theoretical findings within this paper. Copyright © 2013 John Wiley & Sons, Ltd.     

火电厂预应力框架拟静力试验与推覆分析

火电厂作为重点抗震设防建筑,理应具有较强的抗震性能,而现行＂两阶段＂结构设计方法无法提供结构在地震作用下的整体反应。本文采用静力弹塑性分析方法,利用SAP软件,结合我国现行抗震设计规范,分析了火电厂预应力框架在地震作用下的结构反映特性,并通过与拟静力试验结果的对比,提出设计建议。分析表明该结构具有明显的薄弱环节,在设计中应予以重视。     

论我国刑事和解制度的构建

刑事和解是我国刑事政策的重要改革措施,其理论基础有,无讼与和合文化、刑事司法哲学的转向、宽严相济刑事政策.但是,司法实践中的刑事和解存在功能性缺陷和相关法律制度缺位的困境.因此,有必要从存在的困境出发,具体在立法选择和程序设计上探讨刑事和解制度在我国如何合理构建.     

高抗冲聚苯乙烯的阻燃研究

利用锥形量热仪(CONE)研究了阻燃高抗冲聚苯乙烯(HIPS)的燃烧性能,同时也采用垂直燃烧、氧指数等方法进行了对比测试。含十溴二苯乙烷的试样不仅保持了原有的物理机械性能,而且阻燃效果明显。相对于使用十溴二苯醚阻燃的HIPS,十溴二苯乙烷的使用不会产生多溴代二问题,产品符合一定的环保要求。     

Fast‐moving coin recognition using deep learning

Multimedia Tools and Applications - Deep learning has made essential contributions to the development of visual object detection and recognition. Identifying fast-moving objects from the viewpoint...     

Effect of ambient wind on pressure wave generated by high-speed train entering a tunnel

Journal of Central South University - Using three-dimensional, unsteady N-S equations and k-ε turbulence model, the effect of ambient wind on the pressure wave generated by a high-speed train...     

德惠断陷下白垩统碎屑岩储层特征及控制因素分析

德惠断陷下白垩统登娄库组、营城组、沙河子组储层物性差,勘探风险大.利用岩心观察、铸体薄片鉴定、扫描电镜分析、黏土X线衍射分析等方法,分析储层基本特征、储层成岩作用和控制因素.结果表明:德惠断陷下白垩统碎屑岩储层成分成熟度和结构成熟度较低,储层孔隙类型主要有残余原生孔、次生孔和混合孔,储层物性和孔隙结构较差;压实作用是导致储层物性变差的主要原因,溶蚀作用改善储层物性;纵向上发育2个次生孔隙带,主要形成于中成岩期,次生孔隙带的形成与有机质生烃排酸和断裂有关.研究结果为德惠断陷下白垩统进一步油田勘探提供地质依据,对其他地区类似储层研究有一定借鉴意义.     

析架空输电线路上倍容导线的选择

架空输电线路项目扩容改造,当采用倍容导线时,需在技术和经济上对倍容导线进行比较分析。文章对这种导线的种类、特性情况作了介绍,通过在220kV线路上对倍容导线的选择分析,为同类案例的处理提供了借鉴和参考。