级联GMW序列的三项式特性

利用有限域上迹函数的性质,讨论了一类非线性扩频序列:级联GMW序列的三项式特性,即移位相加性。给出了此类序列的三项式时,并对级联GMW序列的性质作了一些讨论。     

A Polymer Defect Passivator for Efficient Hole-Conductor-Free Printable Mesoscopic Perovskite Solar Cells

Due to the low cost and excellent potential for mass production, printable mesoscopic perovskite solar cells (p-MPSCs) have drawn a lot of attention among other device structures. However, the low open-circuit voltage (V_OC) of such devices restricts their power conversion efficiency (PCE). This limitation is brought by the high defect density at perovskite grain boundaries in the mesoporous scaffold, which results in severe nonradiative recombination and is detrimental to the V_OC. To improve the perovskite crystallization process, passivate the perovskite defects, and enhance the PCE, additive engineering is an effective way. Herein, a polymeric Lewis base polysuccinimide (PSI) is added to the perovskite precursor solution as an additive. It improves the perovskite crystallinity and its carbonyl groups strongly coordinate with Pb²⁺, which can effectively passivate defects. Additionally, compared with its monomer, succinimide (SI), PSI serves as a better defect passivator because the long-chained macromolecule can be firmly anchored on those defect sites and form a stronger interaction with perovskite grains. As a result, the champion device has a PCE of 18.84%, and the V_OC rises from 973 to 1030 mV. This study offers a new strategy for fabricating efficient p-MPSCs.     

Molecular-level Designed Polymer Electrolyte for High-Voltage Lithium–Metal Solid-State Batteries

In solid polymer electrolytes (SPEs) based Li–metal batteries, the inhomogeneous migration of dual-ion in the cell results in large concentration polarization and reduces interfacial stability during cycling. A special molecular-level designed polymer electrolyte (MDPE) is proposed by embedding a special functional group (4-vinylbenzotrifluoride) in the polycarbonate base. In MDPE, the polymer matrix obtained by copolymerization of vinylidene carbonate and 4-vinylbenzotrifluoride is coupled with the anion of lithium-salt by hydrogen bonding and the “σ-hole” effect of the C F bond. This intermolecular interaction limits the migration of the anion and increases the ionic transfer number of MDPE (t_Li⁺ = 0.76). The mechanisms of the enhanced t_Li⁺ of MDPE are profoundly understood by conducting first-principles density functional theory calculation. Furthermore, MDPE has an electrochemical stability window (4.9 V) and excellent electrochemical stability with Li–metal due to the CO group and trifluoromethylbenzene (ph-CF₃) of the polymer matrix. Benefited from these merits, LiNi_0.8Co_0.1Mn_0.1O₂-based solid-state cells with the MDPE as both the electrolyte host and electrode binder exhibit good rate and cycling performance. This study demonstrates that polymer electrolytes designed at the molecular level can provide a broader platform for the high-performance design needs of lithium batteries.     

A Colorimetric Hydrocarbon Sensor Employing a Swelling‐Induced Mechanochromic Polydiacetylene

Exceptional challenges have confronted the rational design of colorimetric sensors for saturated aliphatic hydrocarbons (SAHCs). The main reasons for this difficulty are the extremely nonpolar nature of these targets and their lack of functional groups that can interact with probes. By taking advantage of a mechanochromic conjugated polydiacetylene (PDA) and the hydrocarbon‐induced swelling properties of polydimethylsiloxane (PDMS), a sensor film that enables simple, colorimetric differentiation between a variety of C5 to C14 aliphatic hydrocarbons is fabricated. The unprecedented PDA–PDMS composite sensor undergoes a blue‐to‐red colorimetric transition on a timescale that is dependent on the chain length of the hydrocarbon target. In addition, the development of the red color is directly proportional to the swelling ratio of the film. This straightforward approach enables naked‐eye differentiation between n‐pentane and n‐heptane. The versatility of the sensor system is demonstrated by using it for the colorimetric determination of kerosene in adulterated diesel oil. Finally, the observation that a PDA microcrystal in the film undergoes significant expansion and tearing in concert with a blue‐to‐red colorimetric transition during the swelling process provides direct evidence for the mechanism for the mechanochromic behavior of the PDA.     

Novel Hybrid Content Synchronization Scheme for Augmented Broadcasting Services

As a new hybrid broadcasting service, augmented broadcasting shows enhanced broadcasting content on a large TV screen, while augmented reality (AR) on a mobile device augments additional graphical content onto an input image from the device's own camera to provide useful and convenient information for users. A one‐sided broadcasting service using AR has already been attempted in virtual advertisements during sport broadcasts. However, because its augmentation is preprocessed before the video image is transmitted, the viewer at home may have no influence on this formation; and no interaction for the user is possible unless the viewer has a direct connection to the content provider. Augmented broadcasting technology enables viewers to watch mixed broadcasting content only when they want such service and to watch original broadcasting content when they do not. To realize an augmented broadcasting service, the most important issue is to resolve the hybrid content synchronization over heterogeneous broadcast and broadband networks. This paper proposes a novel hybrid content synchronization scheme for an augmented broadcasting service and presents its implementation and results in a terrestrial DTV environment.     

基带芯片物理层控制方案的设计

对多核基带芯片物理层控制方案进行了简单的讨论,提出了一种用于GSM移动终端基带芯片物理层控制(L1C)的方案,根据GSM的帧结构设计了基时钟电路,并以物理层信号处理流程为依据,建立了物理层上下行的调度时序,初步完成了基带芯片SoC系统多核之间的任务调度和时序控制。     

硫酸盐法蒸煮脱木素历程的近红外光谱表征法

利用近红外光谱法对木材硫酸盐法蒸煮过程脱木素历程进行了研究。结果表明,利用红外光谱能较好地表征木材的三段脱木素历程。这为下一步近红外光谱在线测量仪的开发奠定了理论基础。     

分别采用正负延迟触发的存储测试方法

针对弹载存储测试系统中单一的负延迟触发方式稳定性不高,所测数据单一,测试电路集成度不高,数据易丢失等问题,提出了分别采用正负延迟触发的存储测试方法。该方法通路1以采样信号值的变化为触发信号,采用负延迟触发方式;通路2以发射击发机构运动为触发信号,采用正延迟触发方式。分析与试验表明:两种触发方式的结合,能够最大限度地减小外界干扰信号的影响,在数据采集过程中同步将数据存储于非易失存储器中,实时保存所测数据,有效提高了单次测试的可靠性,最大限度提高了系统的可利用性。     

地面防空训练模拟中的电子战仿真建模与实现

围绕当前信息化作战训练转型的需要,研究了在地面防空训练模拟系统中实现电子对抗训练的工程方法.提出了电子对抗训练科目的设置原则,建立了适合软件实现的电子对抗模型,包括电子干扰模型与雷达反干扰模型,最后给出了软件实现的关键流程.     

极性小分子对Ni/TiO_2核壳结构电流变液性能的影响

通过力学性能试验、形貌观察,重点研究电流变液的核壳微粒Ni/TiO2用Urea等极性分子修饰对电流变液性能、形貌的影响。结果表明,极性小分子可大幅提高电流变液的性能,对Ni/TiO2/Urea微粒存在一个Urea/Ti临界值,其值的质量分数为30%。