有机电沉积涂料的新动向

阴极电沉积涂料是 2 0世纪 70年代以来发展起来的一种新的涂装方法 ,具有挥发性有机物 (VOCs)和有害空气污染物(HAPs)含量低、防蚀能力强、漆膜质量好、涂料利用率高、适合涂装结构复杂的构件和设备等特点。介绍了近年来阴极电沉积涂料研发的新动向。它们主要集中在有机双层电涂和高分子 聚电解质 /低聚物电解质复合物多层电涂体系 ,这些新的电涂体系在涂料的稳定性以及涂层的物理化学性质和力学性能方面具有明显的改进。     

城建档案工作中的敬业精神

城建档案工作涉及各行各业、各条战线,是一项科学性极强的工作,城建档案工作者不仅要有广博的知识素养,还要有实事求是的科学态度,一丝不苟的工作作风,尤其需要兢兢业业的敬业精神。     

25MVA矿热炉炉眼烧损原因及开堵眼机的开发使用

对炉眼烧损原因进行了分析，矿热炉通过使用开堵眼机，减少了炉眼烧损，解决了跑眼频繁、出铁口使用寿命短的问题，并取得了一定的经济效益。     

建筑艺术--膜结构建筑

结合具体工程实例 ,介绍了膜结构建筑 ,从其类型、膜材料的种类、膜结构建筑的特点等方面进行了论述 ,展望了2 1世纪膜结构建筑的发展。     

我国炼油技术开发的若干思考与建议

分析了我国炼油工业面临的挑战，世界炼油工业的发展趋势，提出了我国炼油技术开发要围绕符合国情的清洁燃料生产技术，炼油与化工结合的炼油技术，适合现有炼油装置技术改造、提高技术水平，降低加工成本的技术，渣油转化技术，煤制油，天然气制油技术，炼油厂智能化的技术，减少炼油厂烟尘排放的技术等7个方面开展工作的具体建议。     

Computation of 2D discrete Hartley transform

Based on a decimation-in-time decomposition, a fast split-radix algorithm for the 2D discrete Hartley transform is presented. Compared to other reported algorithms, the proposed algorithm achieves substantial savings on the number of operations and provides a wider choice of transform sizes     

SiC颗粒尺寸及含量对SiCp／2024Al复合材料性能的影响

本文对粉末冶金法制备的SiCp/2024Al复合材料的性能进行了研究。随SiC颗粒尺寸的增大,复合材料的强度降低,而塑性和磨损抗力则增加。SiC颗粒尺寸对复合材料的物理性能没有什么影响。增加SiC颗粒含量,复合材料的强度、模量均增大,磨损抗力亦明显增加,而塑性和热膨胀系数则降低。     

临盘油田分层注水管柱有效率影响因素分析

分层注水管柱有效率低一直是困扰临盘油田开发生产的一大难题。针对这一现状，在分析油藏结构、施工工艺和现场资料的基础上，分析了影响分层注水井管柱有效率的因素，阐述了封隔器、工艺操作、管枉自身及温度等制约分层注水管柱有效率提高的原因，并提出了相应的对策和措施。     

An infrared spectroscopic study of the mechanism of chloromethane conversion to higher hydrocarbons on HZSM5 catalyst

Investigation of the reaction mechanism of chloromethane on ZSM5 is a new topic. In this work an in situ FTIR technique was employed to study the conversion processes of chloromethane, the active sites on HZSM5, and the desorption state of surface species. The catalytic conversion of chloromethane to higher hydrocarbons was also studied. It is demonstrated that chloromethane can be reversibly adsorbed on acidic sites of HZSM5 at room temperature. At 100°C chloromethane is irreversibly and dissociatively adsorbed on the strong acidic sites of HZSM5, on which surface methoxyl is formed as proved by infrared characteristic C-H stretchings of-CH₃ at 2960 and 2870 cm^–1. Alkoxyls are produced and adsorbed on the catalyst surface as characterized by the infrared absorption bands of -CH₂-groups at 1460 and 2930 cm^–1. At 100°C the adsorbed methoxyl and alkoxyls are the main surface species, and a small amount of aromatics might exist as detected by a characteristic absorption band at 1510 cm^–1. Between 100 and 200°C the adsorbed surface methoxyl and alkoxyls are converted to aromatics, and the occupied OH groups partially appear. At temperature higher than 300°C the adsorbed aromatics are thermally desorbed into the gas phase. Aromatics and alkanes are the main products in catalytic conversion. These results reveal that the formation of aromatics from methoxyl and alkoxyls is easier than the desorption of aromatics from HZSM5 catalyst. An alkoxyl mechanism is proposed for the conversion of chloromethane on HZSM5 based upon the experimental results and the three assumptions: (a) The primary C-C bond is formed from surface methoxyl groups via the methoxyl group polarization and C-H bond weakening, (b) The adsorbed alkoxyls are converted to aromatics via hydrogen transfer and bond rearrangement similar to the conventional carbenium ion mechanism for the aromatization of olefins and alkanes on HZSM5. The hydrogen atoms from the aromatization stimulate the desorption of alkoxyls to alkanes. (c) At temperature higher than 300°C surface reactions and desorption of adsorbed species take place simultaneously, determining the product distribution in the catalytic conversion.     

Study on phase behavior–impact strength relationship of unsaturated polyester/polyurethane hybrid polymer network

The phase behavior of a hybrid polymer network (HPN) composed of poly[(propylene glycol maleate)-co-(propylene glycol phthalate)] crosslinked with styrene and polyester–urethane crosslinked with methylene-bis-ortho-chloroaniline was examined. The correlation between phase separation and impact strength of the HPNs is discussed. The composition of HPNs has an effect on their properties.