复合型导电高分子材料研究进展

简述了复合型导电高分子材料的研究及发展,并对其导电机理、基体树脂、导电填料的研究概况进行了述评,介绍了其在各领域中的应用．     

论株洲产业结构的调整与优化

从株洲产业结构的现状与特征出发,对如何进一步调整优化株洲的产业结构进行了探讨,提出了调整优化的产业结构的基本方针和对策。     

Fabrication and characterization of optical-fiber nanoprobes for scanning near-field optical microscopy

The current scanning near-field optical microscopy has been developed with optical-fiber probes obtained by use of either laser-heated pulling or chemical etching. For high-resolution near-field imaging, the detected signal is rapidly attenuated as the aperture size of the probe decreases. It is thus important to fabricate probes optimized for both spot size and optical transmission. We present a two-step fabrication that allowed us to achieve an improved performance of the optical-fiber probes. Initially, a CO(2) laser-heated pulling was used to produce a parabolic transitional taper ending with a top thin filament. Then, a rapid chemical etching with 50% buffered hydrofluoric acid was used to remove the thin filament and to result in a final conical tip on the top of the parabolic transitional taper. Systematically, we obtained optical-fiber nanoprobes with the apex size as small as 10 nm and the final cone angle varying from 15 degrees to 80 degrees . It was found that the optical transmission efficiency increases rapidly as the taper angle increases from 15 degrees to 50 degrees , but a further increase in the taper angle gives rise to important broadening of the spot size. Finally, the fabricated nanoprobes were used in photon-scanning tunneling microscopy, which allowed observation of etched double lines and grating structures with periods as small as 200 nm.     

Efficient Nd:YAG Laser Frequency Doubling with Periodically Poled KTP

Periodically poled flux-grown KTiOPO(4) was used for efficient extracavity 1064-nm Nd:YAG laser frequency doubling. A conversion efficiency exceeding 65% was obtained in Q-switched operation, and 1.34 W of average frequency-doubled power was generated with 2.2 W of mode-locked laser output. The conversion efficiency is approximately two times higher for periodically poled KTP than for conventional type II phase-matched KTP. The measurements indicate that periodically poled KTP is less susceptible to optical damage than type II KTP.     

智能化锅炉水冷壁清焦检测机具

电厂锅炉水冷壁清焦检测工作一直是个难题,目前国内外尚无更好的解决办法。多功能金属表面清焦检测机具为电厂锅炉水冷壁的清焦检测工作提供了智能化手段,使水冷壁的检测清焦自动化,较好地解决了这一难题。另外,它亦可广泛应用于船体检测、储油气罐及给排水、油管道的检测、疏通堵塞等领域。     

Quantitative analysis and structure determination of styrene/methyl methacrylate copolymers by pyrolysis gas chromatography

A pyrolysis gas chromatography (Py-GC) method has been developed to study the composition and microstructure of styrene/methyl methacrylate (STY/MMA) copolymers. The composition was quantified by Py-GC using monomer peak intensity. Because of the poor stability of methyl methacrylate oligomers, neither MMA dimer nor MMA trimers were detected under normal pyrolysis conditions. The number-average sequence length for STY was determined by pure and hybrid trimer peak intensities. The number-average sequence length for MMA was determined by using formulas that incorporate composition and the number-average sequence length of STY. This method is a new approach for the investigation of the microstructure of those copolymers that do not produce dimer and trimer peaks upon pyrolysis.     

Optical monitoring of silver-based transparent heat mirrors

Both three-layer (TiO(2)-Ag-TiO(2)) and five-layer (TiO(2)-Ag-TiO(2)-Ag-TiO(2)) heat mirrors with optimum transmission in the visible and good reflectance in the IR have been designed by admittance diagram techniques. The mirrors were fabricated successfully by optical monitoring. An interesting anomalous layer was found and explained, and its equivalent refractive index and thickness are 2.015 - i0.016 and 2.56 nm, respectively.     

The interactions between In-Sn solders and an electroless Ni-P deposit upon heat treatment

The interactions between In-Sn solders and an electroless Ni-P deposit within the multilayer combinations comprised of In-Sn/electroless Ni-P/Al were investigated with the aid of heat treatments at various temperatures and durations. The main reaction product was identified with X-ray diffractometry (XRD) as In₃Ni₂ regardless of the In-contents of the In-Sn solders. The formation of this In₃Ni₂ compound occurred through the diffusion of Ni towards the In-Sn solder. The intermetallic compound layer achieved its maximum thickness within 100 h upon heat treatment at 60 C; the thickness of the compound layer did not increase upon extending heat treatment. Sn tended to dissolve in the In₃Ni₂ compound.     

Experimental study on fitness of one-piece casting osseointegrated implant frameworks with relation to fixture abutment positions

An experiment on fitness of one-piece casting osseointegrated implant frameworks was performed among three fixture abument positions where other conditions were controlled. The result revealed that there was statistically significant differences in dimensional change among the three fixture abument positions. In terms of the relation between abument position and fitness, the more backward the abument position was, the worse the osseointegrated framework fitness was. The frameworks showed deformations in "arch form" and "warp" in three dimensions.