Electrodeposition of Ni-transition alloys for the oxygen evolution reaction

The oxygen evolution reaction (OER) is the anodic reaction in several industrial electrolytic processes. The objective of this work was to develop a new electrocatalytic material for long-lasting and economical high performance electrodes. New electrodes were prepared by electrodeposition of nickel, nickel-ruthenium and nickel-iridium alloys. They were then activated by anodic polarization at 100 mA cm^–2 to form an oxide layer. The electrocatalytic activity was characterized for the OER in 5M KOH solution. The results show that nickel-iridium alloys provide greater electrocatalytic activity for the OER and better corrosion resistance than nickel-ruthenium in alkaline solution. The effects of transition elements on improving the performance of the nickel electrode are then discussed.Notation b Tafel slope - i _ex exchange current density - i _dp electrodeposition current density - i _OER oxygen evolution reaction current density - C _dl double-layer capacity - o₂ oxygen overpotential     

PVC／PU合金的制备与研究

叙述了选择混炼型聚氨酯(PU)与分子量适中的Ⅱ型聚氯乙烯(PVC)树脂制备PVC/PU合金的过程,讨论了PVC/PU共混比、填充剂、硫化体系、共混工艺等因素对PVC/PU合金性能的影响。结果表明:选择PVC/PU=60/40(质量比),硫化剂TD15份,白炭黑30份,混炼温度140—160℃,可制得性能优良的PVC/PU合金。动态力学性能实验显示了PVC/PU合金有较好的相容性。     

新型层状表面相锆基固体酸催化酯化反应研究

将所研制的层状表面相锆基固体酸催化剂用于一元、二元醇醋酸酯和其他羧酸酯类产品的合成 ,考察了其催化性能。研究发现 :层状表面相锆基固体酸催化剂对所考察的酯化反应具有很好的普遍适用性 ,但其酯化率与醇的性质和结构密切有关。催化反应动力学研究表明乙酸与丁醇、戊醇、己醇的酯化反应均为二级反应 ,且反应活化能均较低 ,分别为 47 4kJ/mol、2 3 3kJ/mol和 19 8kJ/mo     

Cu2O/Cu Cermet as a Candidate Inert Anode for Al Production

Cu₂O/ x Cu ( x =0–25 wt%) cermets were evaluated as a novel partially inert anode for aluminum (Al) production. The physical and mechanical properties, including the compressive strength, flexural strength, thermal expansion coefficient, thermal conductivity, and dc electrical conductivity were tested at room temperature and at temperatures up to 950°C. The coefficient of thermal expansion, compressive strength, flexural strength, thermal conductivity, and electrical conductivity of Cu₂O/Cu cermets increased with increasing Cu content. High-temperature electrical conductivity measurements showed that with increasing temperature, the electrical conductivity increased when the Cu content was below the percolation threshold, while it decreased when the Cu content was above the percolation threshold. A relatively stable CuAlO₂ layer formed on the cermet surface during electrochemical testing, and the corrosion rate of this anode was estimated to be about 1.8–1.9 cm/year in Al production.     

环氧树脂-聚丙烯酸酯乳液型复合薄膜粘合剂

本文主要叙述了环氧-丙烯酸酯聚合乳液的合成,以及该乳液粘合剂的配制;讨论了该乳液粘合剂的粘合性能及耐水、耐溶剂性能。     

聚氨酯丙烯酸酯紫外光固化PVC涂料的研制

通过对涂料不同组分的种类及配比进行调节,制备不同配方的PVC清漆。在测试附着力、硬度、耐温、耐水性能的基础上,优化涂料配方,并配制出性能优异的PVC清漆涂料。     

顺酐化SBS的钠离聚体形式与丙烯酰胺的乳液接枝共聚

研究了顺酐化SBS的钠离聚体与丙烯酸胺以过氧化苯甲酰为引发剂的乳液聚合,得到了共聚的较佳条件.并以IR及DSC表征了试样的组成和多相结构.     

Effect of particle size on the surface oxidation and flotation behavior of galena particles in lime system

ABSTRACT

In this research, the effect of particle size on the surface oxidation and flotation behavior of galena in the lime system was studied. Coarse (?0.074 + 0.038 mm), intermediate (?0.038 + 0.025 mm) and fine (?0.025 mm) galena particles were used in the experiment. The dissolution tests, flotation tests, and sorption tests were accomplished. Through further analysis by XPS, the effect of particle size and lime was observed. The decrease of mineral particle sizes increased the adsorption ratio of collector and the dissolution of galena, while the hydrophilic product OH^?/Ca(OH)⁺ produced by dissolution occupied the dominant position, which led to the minerals hydrophilic.     

Preparation,characterization, and adsorption properties for metal ions of a novel chelating resin containing sulfoxide and diethylene glycol

A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg²⁺, Ag⁺, Cu²⁺, Zn²⁺, and Pb²⁺ at various pH values were determined. The maximum adsorption capacities for Hg²⁺ and Ag⁺ were 1.56 and 0.75 mmol g^?1 respectively. The resin had high selectivity for Hg²⁺ and Ag⁺ over the pH range 1.0–7.0. The adsorption capacities for Hg²⁺ and Ag⁺ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg²⁺ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006