高层建筑塑料给水管道水压的非常规无损检测技术综述

综述了高层建筑塑料给水管道水压的非常规无损检测技术。高层建筑塑料给水管道在进行水压实验检测时,周围环境温度变化会影响实验结果,出现误差;在开始水压实验前,必须进行管道的预压处理,这样可消除管道变形产生的影响;高层建筑塑料给水管道在进行水压实验检测时,应尽可能消除所有可能产生误差的因素。以某高层房屋漏水为例,对楼上房间内的热水管道、冷水管道进行水压实验,发现热水管道质量状况出现异常,有渗漏点存在,管道在实际检测中已破损,压力降很快超出GB 50242—2016要求的0.05 MPa。     

Parametrized Maximum Principle Preserving Flux Limiters for High Order Schemes Solving Multi-Dimensional Scalar Hyperbolic Conservation Laws

In this paper, we will extend the strict maximum principle preserving flux limiting technique developed for one dimensional scalar hyperbolic conservation laws to the two-dimensional scalar problems. The parametrized flux limiters and their determination from decoupling maximum principle preserving constraint is presented in a compact way for two-dimensional problems. With the compact fashion that the decoupling is carried out, the technique can be easily applied to high order finite difference and finite volume schemes for multi-dimensional scalar hyperbolic problems. For the two-dimensional problem, the successively defined flux limiters are developed for the multi-stage total-variation-diminishing Runge–Kutta time-discretization to improve the efficiency of computation. The high order schemes with successive flux limiters provide high order approximation and maintain strict maximum principle with mild Courant-Friedrichs-Lewy constraint. Two dimensional numerical evidence is given to demonstrate the capability of the proposed approach.     

合成氢化松香乙酯的新工艺研究

以DRC为催化剂,在无溶剂条件下,通过氢化松香与乙醇的直接酯化反应合成氢化松香乙酯。探索了反应温度、催化剂用量、反应时间、物料配比等因素对反应酯化率的影响,确定最佳反应条件为:反应温度180℃,催化剂用量为原料氢化松香质量的6%,反应时间6h,醇与酸的摩尔比为3∶1。在最佳条件下酯化率达92.2%。还探讨了用阴离子交换树脂柱层析分离纯化氢化松香乙酯粗产物的方法。此外,利用红外光谱对氢化松香乙酯精制产物进行了表征;用GC-MS分别对氢化松香乙酯粗产物及其精制产物进行了定性和定量分析,比较了柱层析前后化学组成的变化。     

Poly(3‐chlorothiophene) films prepared by the direct electrochemical oxidation of 3‐chlorothiophene in mixed electrolytes of boron trifluoride diethyl etherate and sulfuric acid

3‐Chlorothiophene (CT) was electrochemically polymerized in mixed electrolytes of a boron trifluoride diethyl etherate solution containing 0–20% (by volume) sulfuric acid. The oxidation potentials of the monomer in these media were measured to be only 1.06–1.31 V (vs Ag/AgCl). These values were much lower than that of CT in acetonitrile and 0.1 mol/L (Bu)₄NBF₄ (1.92 V vs Ag/AgCl). Poly(3‐chlorothiophene) (PCT) films with conductivities of 0.1–2 S cm^?1 were obtained. The structure, morphology, and electrochemical behavior of the PCT films also were investigated. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 502–509, 2003     

石油钻采机械用橡胶气囊的研制

橡胶气囊是石油钻采设备上常用的一种刹车装置。介绍了橡胶气囊的模具设计、铜气嘴的处理、排气槽的加工布置等整个研制过程。经试验，生产制作的橡胶气囊完全达到设计要求。     

Water-soluble and amphiphilic polymers

Summary Three PEO-PSt-PEO triblock polymers and their parent ho-nopolystyrene have been studied by means of light scattering technique in chloroform, toluene and ethyl acetate. It has been found that the weight average molecular weights calculated by using the equation Mapp- were unbelievable negative values; and the largest deviation appeared for the sample with PEO mole content of about 50%. Data of PSt-PEO-PSt triblock polymers in literature have been quoted and discussed.     

基于Jpcap的Webmail邮件还原技术

基于Smtp和Pop3的邮件还原技术已经日臻成熟,而由于主要Webmail邮件格式不同,Webmail邮件还原技术一直是难点。通过对主要Webmail的内容格式分析,针对不同网站的Webmail建立相应的还原模块,实现对主要Webmail的内容还原。实验结果验证了该技术的有效性。     

The determination of the pore structural parameters of isoporous resins by inverse GPC

The swollen pore structure of a series of microporous isoporous resins (7.4–140 Å) are investigated with inverse GPC, n-alkylbenzenes and linear polystyrenes being used as probe molecules. The results indicated that, with the lowering of crosslinking degree of isoporous resins, the average pore diameter increased and the pore distribution curve broadened. All pore volume distribution obeyed a log-normal distribution. Based on the linear regression method, the experimental data were fitted to a monotonously declining exponential function and a normal distribution function by a computer, and some important structural parameters such as average pore diameter, pore volume distribution, specific surface area, etc. were obtained. The specific surface area of swollen gels were found much greater than those in the dry state measured by N₂ adsorption.     

Formation Mechanisms of Platelet Sr3Ti2O7 Crystals Synthesized by the Molten Salt Synthesis Method

The molten salt synthesis (MSS) method is utilized to synthesize the anisotropic platelet Sr₃Ti₂O₇ (S3T2) single-crystal particles. The aim of this study is to identify the essence of platelet Sr₃Ti₂O₇ crystal growth and guide the synthesis of anisotropic platelet SrTiO₃ crystals as well as various technologically important materials. Based on the results of X-ray diffraction, scanning electron microscopy, and high-resolution transmission electron microscopy, the formation mechanism of platelet Sr₃Ti₂O₇ crystals conforms to a nucleation–structure rearrangement–dissolution–diffusion in situ epitaxial growth mechanism model. First, SrCO₃ reacts with TiO₂ to form submicrometer SrTiO₃ nuclei. Then, most of the nuclei surrounded by salt ions aggregate and rearrange to form a large SrTiO₃ matrix. The structural rearrangement and the subsequent in situ epitaxial growth processes control the morphology, composition, and size of the final Sr₃Ti₂O₇ crystals. In the synthesis process, the conversion between SrTiO₃ and Sr₃Ti₂O₇ is as follows: and the crystallographic orientation relationship between Sr₃Ti₂O₇ and SrTiO₃ in the interface is (100)_S3T2//{100}_ST, (010)_S3T2//{010}_ST, and (001)_S3T2//{001}_ST.     

Preparation,characterization, and adsorption properties for metal ions of a novel chelating resin containing sulfoxide and diethylene glycol

A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg²⁺, Ag⁺, Cu²⁺, Zn²⁺, and Pb²⁺ at various pH values were determined. The maximum adsorption capacities for Hg²⁺ and Ag⁺ were 1.56 and 0.75 mmol g^?1 respectively. The resin had high selectivity for Hg²⁺ and Ag⁺ over the pH range 1.0–7.0. The adsorption capacities for Hg²⁺ and Ag⁺ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg²⁺ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006