Effect of temperature on methyl radical generation over Sr/La2O3 catalysts

The role of gas phase CH₃ radicals in the oxidative coupling of CH₄ over 1 wt% Sr/La₂O₃ is supported by the observations that (i) this is a very effective catalyst for the generation of CH₃ · radicals and (ii) the concentration of CH₃ · radicals increases with temperature over the range of 450 °C–800 °C.     

纸张用有机硅抗水剂的制备

采用氨基硅油、十二烷基三甲氧基硅烷、甲基三乙氧基硅烷配成11种抗水剂,用于纸张的抗水处理.通过渗透法和接触角法测试发现,有机硅抗水剂对实验选择的9种纸张均有明显的抗水效果;其中采用氨基硅油配制的抗水剂效果最好,经其处理的生宣纸与空白样相比,接触角由完全润湿提高到125°,渗透时间由0提高到18 s.最佳应用工艺为:将氨基硅油配制成质量分数为2.041%的甲苯溶液,按照10g/m2的涂布量喷涂于纸张表面,自然晾干3～5天至恒定质量.     

Electromagnetic properties of ferroelectric-ferrite ceramic composites

The NiFe₂O₄ and Pb(Zr_0.52Ti_0.48)O₃ ceramic composites are prepared by conventional solid state reaction method. The microstructural and morphological properties of the composites are studied by X-ray diffraction analysis and scanning electron microscopy. Results indicate that the ferrite and piezoelectric phases can co-exist in the composites. The relationship between the dielectric constant and frequency (40 Hz–40 MHz) as well as temperature is also investigated. It is noted that the transition temperature of the composites is about 380 °C. A double electric hysteresis loop is observed in our composites. The magnetic properties are relatively weak according to the magnetic hysteresis loop. With increase in the content of the ferrite phase, the permeability increases. The electromagnetic properties of the as-prepared composites are tunable according to the content of the NiFe₂O₄ phase.     

保山气田新近系羊邑组二-三段沉积微相

保山盆地为滇西的一个具西断东超箕状断陷结构的新近系小型盆地。为搞清区内保山气田的沉积特征，指导该区油气勘探工作，结合沉积岩（物）与沉积环境之间的辩证关系，通过对沉积岩的岩性特征（颜色、岩石类型、岩石结构、黏土矿物、岩相组合）的分析研究，借助于沉积相在测井和地震剖面上的显著特征，研究并划分了保山气田新近系上新统羊邑组二-三段的沉积微相类型。结果表明，在该研究区主要发育了扇三角洲前缘亚相中的水下分流河道、分流河道间、前缘席状砂、河口坝等沉积微相类型，以及浅湖亚相中的浅湖泥和浅湖漫流席状砂沉积微相。剖析各类骨架微相的沉积特征后指出：水下分流河道、河口坝和前缘席状砂为该区最有利的储集砂体。     

Effect of fluoropolymer antidripping agent on the microstructure and properties of polyesters

Poly(ethylene terephthalate) (PET) is of excellent mechanical properties and melt processability and is widely used as raw material for textile fibers. However, the flame retardant properties of PET were rather poor, and both reactive and additive phosphorus- and halogen-containing compounds have been employed to enhance the reaction-to-fire properties while the meltdripping behaviour during burning hasn’t been handled properly with the flame retardants. In this work, fluoropolymer was blended with both pure PET (pPET) and reactive phosphorus-containing flame retarded copolyester (fPET), and the flame retardance and char formation and mechanical properties of the resulted pPET and fPET blends were investigated. The tensile strengths of modified pPET samples were worsen whereas those of modified fPET samples were improved at low concentrations. The initial thermal degradation in nitrogen was accelerated remarkably for the two polyesters with fluoropolymer. The oxygen indices of the all modified samples were reduced while char formation and meltdripping suppression were encouraged. The apparent melt viscosity and elasticity for the two polyesters were gained much with antidripping agent. Therefore, fluoropolymer improved char formation of the two polyesters based on the gaseous phase mechanism while the partial suppression of meltdripping behavior and the decrease of mechanical properties mainly originated from the increase of melt viscosity via fibrillation for pPET.     

Periodic surface modeling for computer aided nano design

Current solid and surface modeling methods based on Euclidean geometry in traditional computer aided design are not efficient in constructing a large number of atoms and particles. In this paper, we propose a periodic surface model for computer aided nano design such that geometry of atoms and molecules can be constructed parametrically. At the molecular scale, periodicity of the model allows thousands of particles to be built efficiently. At the meso scale, inherent porosity of the model represents natural morphology of polymer and macromolecule. Surface and volume operations are defined to support crystal and molecular model creation with loci and foci periodic surfaces. The ultimate goal is to enable computer assisted material and system design at atomic, molecular, and meso scales.     

En/Decoder for Spectral Phase-Coded OCDMA System Based on Amplitude Sampled FBG

A novel en/decoder for spectral phase-coded optical code-division multiple-access system based on amplitude sampled fiber Bragg grating (FBG) is proposed. Both equivalent chirp and equivalent phase shift are achieved by amplitude sampling. Compared with previous en/decoder based on step chirped FBG, it is easier to fabricate. The performance of the proposed en/decoder is verified by both numerical simulation and experimental demonstration.