Electrocatalysis of Fe-N-C Bonds Driving Reliable Interphase and Fast Kinetics for Phosphorus Anode in Sodium-Ion Batteries

Phosphorus exhibits high capacity and low redox potential, making it a promising anode material for future sodium-ion batteries. However, its practical applications are confined by poor durability and sluggish kinetics. Herein, an innovative in-situ electrochemically self-driven strategy is presented to embed phosphorus nanocrystal (≈10 nm) into a Fe-N-C-rich 3D carbon framework (P/Fe-N-C). This strategy enables rapid and high-capacity sodium ion storage. Through a combination of experimental assistance and theoretical calculations, a novel synergistic catalytic mechanism of Fe-N-C is reasonably proposed. In detail, the electrochemical formation of Fe-N-C catalytic sites facilitates the release of fluorine in ester-based electrolyte, inducing Na⁺-conducting-enhanced solid-electrolyte interphase. Furthermore, it also effectively induces the dissociation energy of the P-P bond and promotes the reaction kinetics of P anode. As a result, the unconventional P/Fe-N-C anode demonstrates outstanding rate-capability (267 mAh g⁻¹ at 100 A g⁻¹) and cycling stability (72%, 10 000 cycles). Notably, the assembled pouch cell achieves high-energy density of 220 Wh kg⁻¹.     

BPA-Containing Polydopamine Nanoparticles for Boron Neutron Capture Therapy in a U87 Glioma Orthotopic Model

Boron neutron capture therapy (BNCT) is a promising therapy for refractory cancer based on the cytotoxic reaction of ¹⁰B (n, α) ⁷Li. Although two BNCT agents are clinically available, they are quickly metabolized and show modest enrichment in tumor sites, partially limiting BNCT widespread application. Consequently, novel agents that perform active targeting and show good biocompatibility have to be developed. Herein, boronophenylalanine-containing polydopamine (B-PDA) nanoparticles are easily fabricated by encapsulating boronophenylalanine (BPA) in polydopamine via nitrogen-boronate coordination. In this study, B-PDA achieves increased tumor accumulation and prolonged retention effects in the tumor site and superior antitumor activity post neutron irradiation in the orthotopic xenograft glioma model. In brief, this study offers a novel strategy for BPA delivery and may broaden the perspective on nanomedicine design for BNCT.     

Magnesium Gradient-Based Hierarchical Scaffold for Dual-Lineage Regeneration of Osteochondral Defect

Osteochondral regeneration remains a great challenge due to the limited self-healing ability and the complexity of its hierarchical structure and composition. Mg²⁺ and hypoxia are two effective modulators in boosting chondrogenesis. To this end, a double-layered scaffold (D) consisting of a hydrogel layer on a porous cryogel is fabricated to mimic the hierarchical structure of osteochondral tissue. An Mg²⁺ gradient is incorporated into the double-layered scaffold with hypoxia-mimicking deferoxamine (DFO) embedded in the hydrogel (D-Mg-DFO), which remarkably augments the dual-lineage regeneration of both cartilage and subchondral bone. The higher Mg²⁺ supplementation from the upper hydrogel, associated with its hypoxia-mimicking situation and small pore size, exhibits promotive effects on chondrogenic differentiation. The lower Mg²⁺ supplementation from the bottom cryogel, associated with its interconnected macroporous structure, achieves multiple contributions in stem cell migration from bone marrow cavity, matrix mineralization, and osteogenesis. Furthermore, rabbits’ trochlea osteochondral defects are established to evaluate the regenerative outcome. Compared to control scaffolds containing only Mg²⁺ or DFO, the D-Mg-DFO scaffold presents the best regenerative effect under the synergistic contribution of multiple factors. Overall, this work provides a new design of scaffold toward an effective repair of cartilage defect.     

一种单材料双功函数栅MOSFET解析模型

An analytical surface potential model for the single material double work function gate(SMDWG) MOSFET is developed based on the exact resultant solution of the two-dimensional Poisson equation. The model includes the effects of drain biases, gate oxide thickness, different combinations of S-gate and D-gate length and values of substrate doping concentration. More attention has been paid to seeking to explain the attributes of the SMDWG MOSFET, such as suppressing drain-induced barrier lowering(DIBL), accelerating carrier drift velocity and device speed. The model is verified by comparison to the simulated results using the device simulator MEDICI. The accuracy of the results obtained using our analytical model is verified using numerical simulations. The model not only offers the physical insight into device physics but also provides the basic designing guideline for the device.     

基于均匀离散曲波变换的多聚焦图像融合

利用均匀离散曲波变换（UDCT）多尺度、多方向、低冗余等特征,提出了一种新的多聚焦图像融合方法。首先使用UDCT对源图像进行多频带分解;然后根据多聚焦图像的特点,对分解后的低频子带系数运用一种基于改进拉普拉斯和算子的方案进行融合,对高频方向子带系数运用基于局部能量的融合规则进行融合,并对融合系数做一致性检测;最后重建各子带系数得到融合图像。实验结果表明:所提方法可以有效地融合源图像中的方向信息和细节特征,同时抑制了融合图像中的伪Gibbs现象;与基于拉普拉斯金字塔分解、小波变换以及轮廓波变换的图像融合方法相比,该方法取得了更好的视觉效果和量化结果。     

基于Sagnac干涉的光纤对冲床脉动电流计量技术的研究

基于Sagnac干涉原理的全光纤光电互感器具有响应特性好、精度高、安全性好的特性,是解决脉动电流测量的新技术之一。以J21-40T普通冲床为研究对象,应用光波的偏振性和法拉第磁光效应理论,探究了全光纤光电互感器测量冲床脉动电流的工作机理。通过对Sagnac调制技术的全面分析,设计了系统框图。借助测量数据,阐述了测量重复性、温度变化、1／4波片、Verdet常数误差。研究结果表明：这一技术可以普遍用于冲床脉动电流的准确测量,是一种有效的大电流计量技术。     

K(4P)原子与H2分子高转动态间的碰撞转移

研究了K(4P)与H2的电子-高转动态能级间的碰撞转移.利用CARS(相干反斯托克斯拉曼散射)探测H2的高转动态分布,扫描和激活CARS谱证实了在的H2(0.9),(0,10),(0,11)和(1,7)能级上有布居.由扫描和激活CARS谱的峰值得到转动态布居数之比.通过速率方程分析,由时间分辨CARS轮廊得到(0,9),(0,10),(1,7)的自弛豫速率及H2(0,11)→H2(1,7)的碰撞转移速率系数为(2.2±0.6)× 10-12cm3s-1.     

赴日无线电监测技术考察报告

首先介绍了日本总务省关东综合通信局电波监理部的情况，然后对日本安立公司生产的RR510A型无线电监测接收机和技术参数以及MS8609A型数字移动无线发射机测试仪的功能进行了分析和介绍。     

New-vst Plus塔板在MAL脱水塔技术改造中的应用

New-vst Plus塔板成功应用在甲基丙烯酸甲酯(MMA)行业的甲基丙烯醛(MAL)脱水塔技术改造中,在塔体利旧的情况下,仅以New-vst Plus塔板替换原填料,便成功解决了该塔长期存在的堵塔问题。改造后,各项指标运行正常,塔底水质量分数小于0.02%,全塔阻力降维持在10kPa以内。该技术改造不仅为厂家带来了经济效益,还为其他处理易聚物系的塔内件改造开辟了新途径,具有广阔的应用前景。     

火山岩储层微观孔隙结构分类评价——以准噶尔盆地东部西泉地区石炭系火山岩为例

基于准噶尔盆地西泉地区火山岩储层特征研究较薄弱的现象,通过25口井的岩心观察、铸体薄片、扫描电镜及高压压汞等分析,以产能大小为依据,将火山岩储层分为4类,对火山岩储集空间类型及组合、微观孔隙结构特征进行分类评价。根据研究区火山岩储层面孔率及优势储集空间组合关系：Ⅰ类为气孔+溶蚀扩大孔、溶蚀孔+裂缝型,Ⅱ类为气孔+构造缝（溶蚀缝）型,Ⅲ类为气孔+溶孔型,Ⅳ类为孤立小孔隙型,面孔率依次降低。火山岩储层不同类型微观孔隙结构特征表明：Ⅰ类储层发育大孔隙、粗喉道,为优势储集层;Ⅱ类和Ⅲ类储层发育大—中孔隙,中—细喉道,为较好到中—差储层;Ⅳ类储层发育小孔隙、细喉道,为致密储层。在此基础上,结合测井资料,建立了研究区火山岩储层分类评价标准。