The selective adsorption of p-chloronitrobenzene (p-CNB) using zeolite as the adsorbent from an aqueous mixture containing p-CNB and o-chloronitrobenzene (o-CNB) was investigated. The maximum adsorption amounts of p-CNB in HZSM-5 zeolite were found to be approximately 4 molecules per unit cell (mol/uc) at all adsorption temperatures investigated. The maximum adsorption amounts of o-CNB in HZSM-5 zeolite were, however, markedly lower than those of p-CNB at different adsorption temperatures. Diffusion results revealed that the diffusivity of p-CNB at 300K was about 100 times higher than that of o-CNB in HZSM-5 zeolite. The remarkable difference in the adsorption amounts and diffusivities between p-CNB and o-CNB resulted in separation factors of 463.6, 96.8 and 21.9 for p-CNB at 278, 300 and 323 K, respectively, indicating a selective adsorption of p-CNB in HZSM-5 zeolite from the aqueous mixture of p- and o-CNB. 相似文献
To determine the flow behavior of SUS304 stainless steel under different conditions, axisymmetric compression tests were conducted over a wide range of forming temperatures (25 °C to 400 °C) and strain rates (10−3 to 10 s−1). Flow curves were obtained for different forming conditions to study the influence of the forming temperature and strain rate on the flow behavior. Moreover, electron backscatter diffraction analysis, X-ray diffraction analysis, transmission electron microscopy, and Feritscope were used to study the microstructure evolution of SUS304 stainless steel under different conditions for determining the underlying reasons for the variations in flow behavior. The experimental results indicated that the flow stress decreased with increasing the forming temperature. With increasing strain rate at 25 °C to 200 °C, the flow stress first increased and then decreased; however, the strain rate had little effect on the flow stress at 300 °C and 400 °C. By analyzing the variation in the phase transformation inside compressed SUS304 stainless steel samples under different forming conditions, the key factors affecting the flow behavior of stainless steel were identified. Finally, by examining the variation in the martensite content and the dislocation density, the dominant deformation mechanism under different forming conditions was determined.
The interaction between the construction market and the overall economy has attracted much attention, but few studies have investigated the influence of the property market on the construction market in terms of property price. The disaggregated data of Hong Kong’s housing and retail construction sectors are collected to investigate the impact of property price on construction output. The newly developed autoregressive distributed lag (ARDL) bounds testing approach and the error correction (EC)-based Granger causality test are employed. The bounds testing results suggest that there exist stable long-run relationships between construction output and property price for both housing and retail construction sectors. Specifically, a 1.00% increase in the housing price and retail price lead to a 0.55% and 0.42% increase in construction outputs for the two sectors respectively. In addition, the Granger causality tests confirm a distinct long-run causal flow from property price to construction output. Furthermore, the proposed ARDL approach provides an effective method for forecasting construction output. 相似文献
Journal of Mechanical Science and Technology - Triangulated surface flattening plays an important role in the surface shape design of a complex product, such as a vehicle, a train and an air plane.... 相似文献