非水解溶胶-凝胶法低温合成硅酸锆

以工业纯ZrCl4、 Si(OC2H5)4为前驱体,通过非水解溶胶-凝胶法合成了硅酸锆.采用DTA-TG和XRD等测试手段研究了凝胶热处理过程中的物相变化.结果表明:当前驱体溶胶中未引入矿化剂时,硅酸锆的合成温度高达1450℃;相比之下,溶胶中引入矿化剂LiF后在600℃下便开始出现了ZrSiO4衍射峰,在700℃合成的硅酸锆不仅合成率高,而且晶体发育好,实现了低温合成硅酸锆的目标.     

水上地震折射互换法误差分析

在理论上，用源检互换的方法进行折射地震勘探是没有误差的，在某些特殊条件下无法铺设检波器而又必须进行折射地震勘探时它也是唯一的选择，然而，在实际工作中，由于各种因素的影响，其误差是不可忽略的。为此，本文从地震折射运动学的角度对水上地震折射互换法因过河钢丝绳的重量、水的流速和流向、炮点深度等客观因素造成的解释误差进行了分析，揭示了水上地震折射互换法应注意的问题。这对水上地震折射互换法的资料解释进行误差校正提供了理论基础。     

一种基于像素自适应仲裁的OSD分层混合结构设计

数据混合是OSD分层显示的关键技术之一.本文基于OSD的分层结构及数据组织结构特点,提出一种OSD分层显示的单混合结构,该结构采用基于像素自适应仲裁的策略,按照层优先级次序,对多个OSD图层信号实时地切换显示.FPGA验证结果表明,该结构在满足OSD分层混合显示、实现菜单选择鼠标控制等高级人机对话功能的前提下,其硬件资源开销比多混合结构节省约33%以上,且具有良好的层次可扩展性和操作灵活性.     

Synthesis and aggregate formation of poly(styrenesulfonate)-b-poly(ethylene glycol)-b-poly(styrenesulfonate) triblock copolymers in aqueous solution induced by binding with aluminum ions

Summary  Well-defined water-soluble poly(styrenesulfonate)-b-poly(ethylene glycol)-b- poly(styrenesulfonate) (PSS-b-PEG-b-PSS) triblock copolymers with narrow molecular weight distribution (1.29 < M_w/M_n < 1.36) were synthesized in aqueous solution at 70 ^oC via reversible addition-fragmentation chain transfer (RAFT) polymerization. The complex formed by the PSS-b-PEG-b-PSS triblock copolymer coordinated with aluminum ion was investigated with turbidimetry, dynamic light scattering (DSL), zeta-potential, and transmission electron microscopy (TEM). The aggregation formation was based on the neutralization of the SO₃^- groups in the PSS blocks with Al³⁺ ions. The appearance, size and stability of the PSS-b-PEG-b-PSS/Al³⁺ aggregates were controlled by varying the PSS block length and degree of neutralization (DN). At DN = 0.33, where the PSS-b-PEG-b-PSS copolymer was completely neutralized with Al³⁺, the aggregate size increased with increasing PSS block length. The transition from the shrinking coil of small size to the interchain aggregates of large size was found at DN of about 0.33.     

固体超强酸S_2O_8~(2-)/SnO_2-SiO_2催化合成环己酮1,2-丙二醇缩酮

采用沉淀-浸渍法制备了固体超强酸S2O28-/SnO2-SiO2,以它为催化剂催化环己酮和1,2-丙二醇合成了环己酮1,2-丙二醇缩酮;考察了带水剂种类及用量、酮醇摩尔比、催化剂用量、反应时间对产品收率的影响,并用正交实验对反应条件进行了优化。实验结果表明,适宜的反应条件为:n(环己酮)∶n(1,2-丙二醇)=1∶1.6、催化剂用量为反应物料总质量的2.0%、带水剂环己烷用量5.0mL、反应时间50min。在此条件下,环己酮1,2-丙二醇缩酮收率达到91.47%;催化剂的稳定性良好,在重复使用5次后环己酮1,2-丙二醇缩酮收率为82.20%,活性下降的主要原因为催化剂表面积碳和吸附了有机物;经傅里叶变换红外光谱和气相色谱质谱分析表明,产物为环己酮1,2-丙二醇缩酮,纯度为100%。     

Electron microscopic observations and DNA chain fragmentation studies on apoptosis in bone tumor cells induced by ~(153)Sm-EDTMP

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Study on phase behavior–impact strength relationship of unsaturated polyester/polyurethane hybrid polymer network

The phase behavior of a hybrid polymer network (HPN) composed of poly[(propylene glycol maleate)-co-(propylene glycol phthalate)] crosslinked with styrene and polyester–urethane crosslinked with methylene-bis-ortho-chloroaniline was examined. The correlation between phase separation and impact strength of the HPNs is discussed. The composition of HPNs has an effect on their properties.     

Lubricating behavior of iron rhenate and its relation to matching pairs

The iron rhenate was compounded by chemical method, which may be generated during wear process of Fe-Re alloys at elevated temperature. The friction coefficient of iron rhenate has been determined by a pin-on-disc device. The results show that iron rhenate plays role of lubricating at RT-600 °C. The lubricating behavior is related to the matching pairs. The hardness of the materials of matching pairs, compatibility of iron rhenate with materials of matching pairs and surface roughness of disc affect the lubricating behavior of iron rhenate mostly. The principle of matching pairs is proposed. Project supported by the National Natural Science Foundation of China Synopsis of the first author Xiong Dangsheng. associated professor, born in 1960. Current research fields include high-temperature self-lubricating alloys and tribological properties of material.