洋流干扰下的多自主水面无人船最优覆盖控制

针对洋流干扰下的多自主水面无人船(ASV)对有限海洋环境进行覆盖监控的最优化问题,提出一种基于环境信息密度的分布式控制方法。该控制方法是在考虑洋流因素的情况下,以二阶EulerLagrange模型为控制模型的最优覆盖策略。首先建立基于欠驱动系统的最优覆盖模型,提出时变洋流干扰下的多ASV最优区域分配算法。在此基础上,针对ASV的欠驱动特性,综合应用运动学控制方法与Backstepping技术设计基于二阶Euler-lagrange方程的最优覆盖控制算法,并利用Lyapunov稳定性理论证明其稳定性。最后对多ASV最优覆盖网络进行仿真验证实验,实验结果表明该控制方法能够使多ASV在洋流干扰下从区域Q的任意初始位置收敛到最优覆盖配置。     

Kinetics simulation of propylene epoxidation over different Ti species in TS-1

A thorough experimental investigation on the kinetic behavior of liquid-phase propylene epoxidation over TS-1 and tetrapropylammonium hydroxide (TPAOH) treated TS-1 catalysts was conducted in a fixed-bed reactor. The amounts of different coordinated Ti species in the catalysts were quantified by spectroscopies, and their catalytic performances of the epoxidation and alcoholysis of propylene oxide were measured by kinetic modeling. The study shows that the TPAOH treatment converted some of the tetrahedrally coordinated Ti to octahedrally coordinated Ti, and both species were active for the epoxidation and alcoholysis. The superior catalytic performance observed over the TPAOH treated TS-1 is due to two factors, the increased percentage of active sites, and reduced energy barrier for epoxidation on the octahedrally coordinated Ti. In addition, as the H₂O₂ conversion increases, the adsorption equilibrium constant of propylene oxide plays a more decisive role than the activation energy for the selectivity of propylene glycol monomethyl ethers.     

新型非离子型水性环氧固化剂的合成及性能研究

为提高水性环氧涂料的固化性能和适用期,以自制聚酰胺和生物基戊二胺为起始原料,聚乙二醇二缩水甘油醚（ PEGGE）为亲水链段,双酚 A型环氧树脂（ E-51）为疏水链段,邻甲苯缩水甘油醚（ CGE）为封端剂制备了非离子型低温水性环氧固化剂,并与自制水性环氧乳液复配制得双组分水性环氧涂料。考察了环氧固化剂合成工艺参数及涂膜各项性能。结果表明：该固化剂含有较长的柔性脂肪烃碳链和聚醚链段能够提高涂膜的柔韧性;双酚 A型环氧树脂参与扩链反应能够解决与乳液不兼容等问题;苯环结构增加了涂膜的硬度;涂膜室温固化后性能优异,具有良好的物理机械性能、耐水性、耐酸碱性和耐盐雾性。     

先进超细化处理技术在钢铁材料中的应用

介绍了近年来钢铁材料在组织超细化处理技术方面的研究成果和各种超细化技术的适用范围，探讨了典型中碳低合金钢(Cr-Mo-V系)超细处理研究结果及性能变化，并为钢铁材料组织超细化技术的理论研究和实际应用提供参考。     

在工业中采用钛合金的微弧氧化

采用硬度测试，金相显微观察和透射电镜分析等方法，研究了微量稀土Er对高纯铝再结晶行为的影响，结果表明，弥散分布的细小Al3Er质点对位错和亚晶界具有钉扎作用，可以有效抑制再结晶，将高纯铝的再结晶温度提高50左右，同时还能显著细化再结晶晶粒，再结晶形核机制是亚晶聚合和亚昌长大双重机制。     

Effect of trace rare earth element Er on high pure Al

1　INTRODUCTIONAsit swellknown ,Chinaisrichinrareearths ,whoseprovedreservesare 80 %ofthetotalreservesoftheworld ,rankingfirstintheworld .Atpresent,theresearchandapplicationofREinsteel&ironareratherprofoundinChina .ThoughtheapplicationandstudiesaboutREinaluminumanditsalloysbeganearly ,it snotuntillateinthe 1970 sthattheinvesti gationandexploitationbeganonalargescaleandgraduallycametoaclimax[13] .Inthepast ,there searchofREaluminummainlyfocusedontheapplica tionofsomeelementssuchasLa ,…     

电镀镍铁合金高整平性光亮剂的研究

简述电镀镍铁合金工艺中光亮剂的发展概况,介绍高整平性光亮剂 ABSN 的研究。试验表明:ABSN 具有高整平性,高光亮性,出光速度快(3—5min),光亮范围宽(0.5—10A/dm~2),耗量低(60—80mL/kAh),产生的镀层韧性好。     

Effects of secondary carbide precipitation and transformation on abrasion resistance of the 16Cr-1Mo-1Cu white iron

The relationship between secondary carbide precipitation and transformation of the 16Cr-1Mo-1Cu white iron and abrasion resistance were investigated. The results show that secondary carbide precipitation and transformation at holding stage play an important role in the hardness and abrasion resistance. After being held for a certain time at 853 K for subcritical treatment, the grainy secondary carbide, (Fe,Cr)₂₃C₆, precipitated first and then Fe₂MoC or MoC carbides precipitated in the alloy, both of which improve the bulk hardness and abrasion resistance of the alloy. The reasons for these improvements are the secondary carbide precipitates from the austenite and the retained austenite transforms into the martensite, both make the matrix strengthen. So the matrix has more effective support to the harder eutectic carbide against exterior abrasion. With expanding the holding time, the in situ transformation from the granular (Fe,Cr)₂₃C₆ carbide into laminar M₃C carbide causes the formation of the pearlitic matrix and an associated decrease of the alloy abrasion resistance.     

过烧YAG陶瓷晶界的分析

采用固相反应法用不同的烧结速率在1850℃烧结合成过烧钇铝石榴石（YAG）陶瓷，YAG陶瓷晶界形貌随烧结速率的变化而不同。高纯的毋Al2O3和Y2O3原料粉体经高能球磨在1400℃空气中煅烧，生成主相为YAG相的多相粉体化合物。真空烧结YAG陶瓷时烧结速率800℃／h并在1850℃真空烧结4h会使陶瓷中晶粒长大不充分，晶粒与晶粒之间仍保留明显的面接触，陶瓷内部残存大量直径约1μm的气孔，尺寸与可见光波长接近，对透过率的影响大，陶瓷成半透明；在以100~C／h升至1850℃真空烧结4h的YAG多晶陶瓷半透明化，陶瓷晶粒粗大，晶界宽化且保留熔融态凝固，用TEM及EDS确认晶界处存在毋α-Al2O3和钙钛型YAP共晶相。     

450mm热连轧机组轧制带钢拓宽分析

讨论了邯郸钢铁公司一轧厂450mm热连轧带钢的拓宽问题；对该机组及其φ500mm开坯机进行了现场测试，并在计算机上进行了带钢拓宽模拟轧制，得出了该机组的最大轧制负荷及其带钢的拓宽限度。