冲击回波法检测隧洞混凝土衬砌厚度

冲击回波法是通过接收、分析在混凝土中传播的回波信号，判断结构混凝土厚度和内部质量的新型无损检测技术。室内试验和工程应用研究表明，该方法为隧洞混凝土衬砌厚度检测提供了一个有效的测试手段。     

含锂霞石颗粒和硼酸铝晶须的铝基复合材料

为了制备具有低热膨胀系数和较高强度的复合材料，选用具有负体膨胀系数的β-锂霞石颗粒和高强度的硼酸铝晶须作为复合材料组分，用挤压铸造法制备了6061铝基复合材料，并对该复合材料的显微结构、拉伸性能和热膨胀性能进行了研究，结果表明，该复合材料能同时获得较低的热膨胀系数和较高的强度；通过改变复合材料中β-锂霞石和硼酸铝的体积分数，在较大的范围内可以对复合材料的强度和热膨胀系数进行设计和调节。     

低阶煤煤层气富集模式初探

通过对美国粉河盆地以及我国铁法盆地煤层气富集规律的解剖,总结出影响低阶煤煤层气富集的关键因素是封堵,而构造、岩性和水动力是形成煤层气封堵的主要因素。同时提出了5种不同的煤层气富集模式,即背斜模式、构造—水动力模式、构造—岩性模式、岩性—水动力模式和岩性模式。     

加强电炉钢短流程生产工艺研究与技术开发的建议

论述了加强电炉钢短流程生产工艺研究与技术开发的必要性和主要课题，并提出关于组织合金钢短流程生产工艺研究与技术开发“九五”国家科技攻关及提高高研究开发投资强度的建议。     

热分析在PVA纤维预处理中的应用

用差热、热重法对原丝的热性能及由不同预处理方法所引起的PVA纤维的热行为变化进行了研究;并通过模拟脱水条件,用不同升温速率,求出了经不同预处理纤维的脱水反应活化能。结果表明,PVA原丝在230℃有一软化点,三种预处理都不同程度地影响了原丝的热效应变化;纤维在180～340℃主要为脱水反应;原丝及经脱水剂、O_3和O_3综合脱水剂处理的纤维,其脱水反应的表观活化能分别为:164.3kJ/mol,92.9kJ/mol,130.5kJ/mol和117.6kJ/mol。     

Comparative study of the elimination of toluene vapours in twin biotrickling filters using two microorganisms Bacillus cereus S1 and S2

BACKGROUND: To investigate the microbial degradation performance of organic pollutants in the atmosphere using a biotrickling filter, two microorganism strains, Bacillus cereus S1 and Bacillus cereus S2, were selected, identified and inoculated into a twin biotrickling filter for comparison. RESULTS: Both strains showed good performance towards the degradation of model organic pollutants when gas flow rates ranged from 100 to 600 L h⁻¹. For S1, the total maximum removal efficiency (RE) of toluene was maintained nearly 100% not only at gas flow rates of 100 L h⁻¹ corresponding to empty bed residence time (EBRT) 199.44 s, but also at gas flow rates of 200 L h⁻¹ (EBRT = 99.72 s) and 300 L h⁻¹ (EBRT = 66.48 s). However, S2 had a much lower degradation capability; near 100% removal efficiency was obtained only at the gas flow rate of 100 L h⁻¹ although both bacteria belong to the same Bacillus cereus. With further increase in gas flow rate, the total REs for both S1 and S2 decreased slightly at first and then dropped sharply to 46% and 35%, respectively, at an EBRT of 33.24 s, corresponding to a gas flow rate of 600 L h⁻¹. Starvation for between 2 and 10 days resulted in the re‐acclimation times of both strains ranging between 1.0 and 15.5 h. CONCLUSION: Strain S1 would be a better choice for inoculation into a biotrickling filter than strain S2, because of its much higher toluene removal capacity and rapid recovery to full performance. Copyright © 2008 Society of Chemical Industry     

正交实验优选盐生藻多糖的提取工艺

以盐生藻为原料,盐生藻多糖得率为指标,运用稀酸、稀碱和蒸馏水为提取剂提取盐生藻多糖,得出合适的提取剂为稀酸.进一步的正交实验表明,盐生藻多糖的最适提取工艺为:提取75min,pH=4,固液比为1∶70,温度为95℃.     

Restraining the associations of anthracene fluorophore by chemically linking to poly(methyl methacrylate)

Associations (dimer or aggregate) of anthracene (An) fluorophores tend to interrupt the monomer emission and reduce the quantum yield (Φ_PL); therefore, poly(methyl methacrylate) (PMMA) chain was used in this study to chemically link to anthracene and to block the mutual associations among the anthracene fluorophores. With this aim, the target polymers were prepared by anionic polymerizations with 9,10‐dibromoanthracene/s‐butyllithium as initiating system to proceed polymerizations of methyl methacrylate (MMA) directly or in the presence of 1,1‐diphenylethylene (DPE). Use of DPE before addition of MMA produces stable initiating anionic species and avoids potential side reactions during polymerization; however, it also introduces four β‐phenylene rings around the central anthracene ring, which interfere with the corresponding emission pattern and reduce the Φ_PL (32%) value due to potential interactions between phenylene rings and anthracene. On the contrast, polymerization without participation of DPE results in polymer with central anthracene ring directly connected to two PMMA chains, which gives clean vibronic emission pattern with limited association emissions and enhanced Φ_PL (52%) value. Physical blending of anthracene by PMMA is less efficient to restrain the associations and results in a film of lower Φ_PL (20%). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008