The oxidative coupling of methane (OCM) has been found to be structure sensitive on La2O3 catalysts exhibiting different crystallite morphologies. Thin plates obtained by thermal decomposition of lanthanum nitrate at 650 °C are more selective on OCM reaction performed at 750 °C than the particles obtained by decomposition of the nitrate at 800 °C. It is assumed that the oxycarbonate observed is formed from the methane deep oxidation on the catalyst surface. This compound appears to act as an intermediate in the production of CO2 and is thus important hi the resulting selectivity. 相似文献
This work presents a novel scalable multiplication algorithm for a type-t Gaussian normal basis (GNB) of GF(2m). Utilizing the basic characteristics of MSD-first and LSD-first schemes with d-bit digit size, the GNB multiplication can be decomposed into n(n + 1) Hankel matrix-vector multiplications. where n = (mt + 1)/d. The proposed scalable architectures for computing GNB multiplication comprise of one d × d Hankel multiplier, four registers and one final reduction polynomial circuit. Using the relationship of the basis conversion from the GNB to the normal basis, we also present the modified scalable multiplier which requires only nk Hankel multiplications, where k = mt/2d if m is even or k = (mt − t + 2)/2d if m is odd. The developed scalable multipliers have the feature of scalability. It is shown that, as the selected digit size d ≥ 8, the proposed scalable architectures have significantly lower time-area complexity than existing digit-serial multipliers. Moreover, the proposed architectures have the features of regularity, modularity, and local interconnection ability. Accordingly, they are well suited for VLSI implementation. 相似文献
Copper overload is a novel way to achieve copper-ion-interference therapy by disrupting copper homeostasis and treating diseases through multiple cell death pathways. However, it is difficult to reach copper overload since excess intracellular copper ions will be pumped out. Herein, copper overload is achieved by both raising cellular uptake and reducing the efflux of copper ions using hydrogen sulfide (H2S)-responsive copper hydroxyphosphate nanoparticles (Cu2(PO4)(OH) NPs). After immersion in an H2S-enriched colon cancer microenvironment, Cu2(PO4)(OH) NPs can transform into copper sulfide NPs with reduced size for higher cell entering, resulting in improved Fenton activity as well as copper ion dissociation. Reactive oxygen species generated by the Fenton reaction not only activate inflammasomes and Caspase-1 proteins, cause the cleavage of gasdermin D to induce pyroptosis, but also affect mitochondrial function and down-regulate copper exporter ATP7A to further reduce the copper excretion. The combination of higher endocytosis and lower exportation leads to maximized copper overload. Together with the efficient copper ions release, mitochondrial tricarboxylic acid cycle can be disrupted and iron-sulfur cluster proteins are downregulated, ultimately triggering cuproptosis. As both pyroptosis and cuproptosis are efficient ways to induce cell death, this study provides a novel way to realize effective tumor-targeted therapy based on H2S-activated copper overload with simple Cu2(PO4)(OH) NPs. 相似文献
Recently, truthful spectrum auctions have been extensively studied to improve spectrum utilization. Furthermore, privacy preservation in truthful spectrum auctions has also been taken into account. However, existing work mainly focuses on privacy-preserving homogenous spectrum auctions, while the case of heterogeneous spectrum auctions is ignored. In this paper, we propose PATH, a privacy-preserving auction for single-sided heterogeneous spectrum allocations. Through organically combining three security techniques: homomorphic encryption, secret sharing and garbled circuit, PATH reveals nothing about buyers’ bids and identities beyond the auction outcome to any participant party. Specifically, PATH not only maintains the properties of truthfulness and spectrum reuse of the underlining auction mechanism TAMES, but also implements the first provably secure solution for single-sided heterogeneous spectrum auctions. Finally, experimental results demonstrate that PATH incurs only limited computation and communication overhead, and it is feasible for large-scale applications.
Rational manipulation of hollow structure with uniform heterojunctions is evolving as an effective approach to meet the lightweight and high-performance microwave absorption for metal-organic frameworks (MOFs) derived absorbers. Herein, a new and controlled synergistic protecting-etching strategy is proposed to construct shelled ZIF-67 rhombic dodecahedral cages using tannic acid under theoretical guidance, then hollow Co@N-doped carbon nanocages with uniform heterojunctions and hierarchical micro-meso-macropores are obtained via a pyrolysis process, which addresses the shortcomings of using sacrificing templates or corrosive agents. The outer Co@N-doped carbon shell, composed of highly dispersive core-shell heterojunctions, possesses micro-mesopores while the inner hollow macroporous cavity endows the absorbers with lightweight characteristics. Accordingly, the maximum reflection loss is −60.6 dB at 2.4 mm and the absorption bandwidth reaches 5.1 GHz at 1.9 mm with 10 wt% filler loading, exhibiting superior specific reflection loss compared with the vast majority of previous MOFs derived absorbers. Furthermore, this synergistic protecting-etching strategy provides inspiration for precisely creating a hollow void inside other MOFs crystals and broadens the desirable candidates for lightweight and high-efficient microwave absorbers. 相似文献