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991.
992.
采用物理掺和法,在苯丙乳液中加入锐钛型纳米TiO2,制成内墙涂料,进行抑菌试验和甲醛降解实验研究,分析了纳米TiO2的光催化原理和抗菌机理。结果表明,随着TiO2含量增加,甲醛降解能力和抗菌性能增强,当TiO2含量为4%时效果最好。 相似文献
993.
SBR反应器中反硝化条件下去除苯酚工艺 总被引:2,自引:0,他引:2
基于异养反硝化原理,在序批式间歇反应器(SBR)中对反硝化同时降解苯酚的菌种进行了149 d的驯化,驯化通过逐步提高进水中苯酚和NO3--N的浓度进行.驯化结束后,进水苯酚质量浓度达到360 mg/L,葡萄糖质量浓度达到100 mg/L,NO3--N质量浓度达到240 mg/L,水力停留时间6 h,苯酚和NO3--N去除率均大于98%.反应器运行结果表明:进水苯酚质量浓度低于720 mg/L时,SBR反应器运行稳定;高浓度NO2--N(>60 mg/L)可以严重影响微生物对苯酚以及NO3--N的去除能力,同时反应器中20.5%~23.5%的COD可被用于微生物的细胞合成. 相似文献
994.
分析了含高浓度不凝组分蒸汽在立式螺旋槽管表面强制对流冷凝的传热机理。在不凝性组分体积百分浓度超过90%时,螺旋槽管的强化传热效果不明显,而含量为44%~90%时,螺旋槽管总换热系数比光滑管提高20%~35%。 相似文献
995.
996.
Summary
Novel sulfonated poly(arylene ether ketone)s were prepared directly by aromatic nucleophilic polycondensation of 4,4'-sulfonyldiphenol
with various ratios of 4,4'-difluorobenzophenone to 5,5'-carbonylbis(2-fluorobenzenesulfonate) in dimethyl sulfoxide. The
resulting polyelectrolytes were characterized by IR, NMR, TGA and DSC. The 10% weight loss temperature of the products is
higher than 510°C, and their glass transition temperature is above 260°C. The introduction of 4,4'-sulfonyldiphenol with powerful
electron-withdrawing group, -SO2−, into the main chain of sulfonated poly(arylene ether ketone)s improves the thermal stability against desulfonation. The
ion-exchange capacity and swelling of the polyelectrolyte membranes were measured, which are higher than 1.23meq/g and not
higher than 20.9%, respectively. The membranes show very good perspectives in polymer electrolyte fuel cell (PEMFC) application.
Received: 27 March 2002 / Revised version: 7 May 2002 / Accepted: 13 May 2002 相似文献
997.
998.
Siyang Jiang Yan Kong Jun Wang Xiaoqian Ren Qijie Yan 《Journal of Porous Materials》2006,13(3):341-346
A series of Sn-Zn modified-MCM41 has been synthesized by direct hydrothermal method and characterized using ICP, XRD, TG/DTA,
FT-IR, HRTEM and N2-adsorption techniques. Catalytic performances of the obtained materials were evaluated in the hydroxylation of phenol with H2O2. Results indicated that all the samples exhibited typical hexagonal arrangement of mesoporous structure with high surface
area and the heteroatoms were probably incorporated into the framework of MCM41. Catalytic tests revealed that the bimetallic
incorporated materials were effective catalysts in the hydroxylation of phenol. The conversion of phenol could be reach to
56.8% for the catalysts with Sn: Zn: Si = 2.69: 4.57: 100 (molar ratio) under the optimized reaction conditions. Moreover,
the materials containing Sn and Zn exhibited higher catalytic activity than monometallic Sn and Zn modified MCM41. 相似文献
999.
1000.
Jia Bing Dai Xing Yuan Zhang Jing Chao Chen Yan Bai 《Journal of Coatings Technology and Research》2007,4(3):283-288
A novel core–shell type fluorinated acrylic and siliconated polyurethane (FSiPUA) hybrid emulsion was prepared by seeded emulsion
polymerization using siliconated polyurethane (SiPU) as a seed and forming the structure with SiPU as a shell and the copolymer
of butyl acrylate (BA) with 2,2,2-trifluoroethylmethacrylate (TFEMA) as a core. SiPU was synthesized using isophorone diisocyanate
(IPDI), polytetramethylene ether glycol (PTMG), polypropylene glycol (PPG), dihydroxybutyl-terminated polydimethylsiloxane
(PDMS), dimethylol propionic acid (DMPA), 1,6-hexanediol (HDO) and triethylamine (TEA). The contents of siloxane and fluorine
were determined according to the feed ratio. Fourier transform infrared spectroscopy (FTIR) was used to identify the chain
structure of SiPU and FSiPUA. Investigation of transmission electron microscopy (TEM) confirmed the core–shell structure of
FSiPUA emulsion and gave the particle size at about 50 nm. The measurement results of water contact angles and the solvent
absorptions in water and n-octane for cured films showed that the water and the oil repellency for FSiPUA had been improved significantly with a suitable
content of fluorine and siloxane. 相似文献