Molecular Adsorption-Induced Interfacial Solvation Regulation to Stabilize Graphite Anode in Ethylene Carbonate-Free Electrolytes

Many organic solvents have excellent solution properties, but fail to serve as lithium-ion batteries (LIBs) electrolyte solvents, due to their electrochemical incompatibility with graphite anodes. Herein, a new strategy is proposed to address this issue by introducing a surface-adsorbed molecular layer to regulate the interfacial solvation structure without the alteration of electrolyte composition and properties. As a proof-of-concept study, it is demonstrated for the first time that the intrinsically incompatible propylene carbonate (PC)-based electrolyte becomes completely compatible with graphite anodes by introducing a layer of adsorbed hexafluorobenzene (HFB) molecules to weaken the Li⁺-PC coordination strength and facilitate the interfacial desolvation process. As a consequence, the graphite/ NCM811 pouch cells using the PC-based electrolyte containing only 1 vol.% HFB demonstrate excellent long-term cycling stabilities over 1150 cycles. This strategy is also proved to be applicable to other ethylene carbonate (EC)–free electrolytes, thus providing a new avenue for developing advanced LIB electrolytes.     

用于制造微波多芯片组件的LTCC技术

低温共烧陶瓷(LTCC)是实现微波多芯片组件(MMCM)的一种理想的组装技术,具有高集成密度、多种电路功能和高可靠性等技术优势.介绍了国内外应用于微波组件的LTCC技术发展现状,概述了LTCC的制造工艺流程,分析了其关键工艺难点,对LTCC基板电路的设计进行了详细阐述,并讨论了埋层电阻的设计和微带线和带状线间的垂直微波互联的方式.利用LTCC技术研制的微波多芯片组件,在现代雷达和通讯领域具有广泛的应用前景.     

光电跟踪系统力矩波动干扰抑制的研究

光电跟踪系统的力矩波动是影响其跟踪精度的噪声的角度一个关键问题.基于某光电跟踪控制系统动态模型,从抑制噪声的角度分析了加入电流环对抑制力矩波动的影响,同时还分析了系统速度、电流两环闭环带宽与力矩波动抑制之间的关系.分析表明,加入电流环后的光电跟踪系统抑制力矩波动的能力明显增强,同时较高的速度回路带宽有利于抑制力矩波动引起的干扰,且在速度带宽一定的情况下增加电流用环带宽对抑制力矩波动也有一定作用.因此,在设计光电跟踪系统时,在不影响系统稳定性的前提下应选用尽可能大的速度及电流闭环带宽.     

SDL的静态语义定义框架

Ｓ Ｄ Ｌ 语言自身的形式化描述对于该语言的不断发展、完善将发挥重要的核心作用。 Ｓ Ｄ Ｌ－ ９２的形式语义已无法充分满足应用需要,本文对 Ｓ Ｄ Ｌ 现有的静态语义定义方法进行了深入的分析,提出了一种基于抽象语法树和谓词演算的 Ｓ Ｄ Ｌ 静态语义定义方法。     

电力电子器件发展概况及应用现状

回顾了电力电子器件的发展历程,对各种电力电子器件的原理、特性以及在电力电子装置中的应用进行了比较分析,最后对电力电子器件的发展前景进行了展望。     

High‐κ Solid‐Gate Transistor Configured Graphene Biosensor with Fully Integrated Structure and Enhanced Sensitivity

A fully integrated graphene field‐effect transistor (GFET) nanosensor utilizing a novel high‐κ solid‐gating geometry for a practical biosensor with enhanced sensitivity is presented. Herein, an “in plane” gate supplying electrical field through a 30 nm HfO₂ dielectric layer is employed to eliminate the cumbrous external wire electrode in conventional liquid‐gate GFET nanosensors that undesirably limits the device potential in on‐site sensing applications. In addition to the advantage in the device integration degree, the transconductance level is found to be increased by about 50% over liquid‐gate GFET devices in aqueous‐media, thereby improves the sensitivity performance in sensor applications. As the first demonstration of biosensing applications, a small‐molecule antibiotic, kanamycin A, is detected by means of an aptameric competitive affinity principle. It is experimentally shown that the label‐free and specific quantification of kanamycin A with a concentration resolution at 11.5 × 10^?9 m is achievable through a single direct observation of the 200 s fast bioassay without any further noise canceling. These results demonstrate the utility and practicability of the new devices in label‐free biosensing as a novel analytical tool, and potentially hold great promise in other significant biomedical applications.     

Current transport studies of amorphous n/p junctions and its application in a‐Si:H/HIT‐type tandem cells

This paper presents an understanding of the fundamental carrier transport mechanism in hydrogenated amorphous silicon (a‐Si:H)‐based n/p junctions. These n/p junctions are, then, used as tunneling and recombination junctions (TRJ) in tandem solar cells, which were constructed by stacking the a‐Si:H‐based solar cell on the heterojunction with intrinsic thin layer (HIT) cell. First, the effect of activation energy (E_a) and Urbach parameter (E_u) of n‐type hydrogenated amorphous silicon (a‐Si:H(n)) on current transport in an a‐Si:H‐based n/p TRJ has been investigated. The photoluminescence spectra and temperature‐dependent current–voltage characteristics in dark condition indicates that the tunneling is the dominant carrier transport mechanism in our a‐Si:H‐based n/p‐type TRJ. The fabrication of a tandem cell structure consists of an a‐Si:H‐based top cell and an HIT‐type bottom cell with the a‐Si:H‐based n/p junction developed as a TRJ in between. The development of a‐Si:H‐based n/p junction as a TRJ leads to an improved a‐Si:H/HIT‐type tandem cell with a better open circuit voltage (V_oc), fill factor (FF), and efficiency. The improvements in the cell performance was attributed to the wider band‐tail states in the a‐Si:H(n) layer that helps to an enhanced tunneling and recombination process in the TRJ. The best photovoltage parameters of the tandem cell were found to be V_oc = 1430 mV, short circuit current density = 10.51 mA/cm², FF = 0.65, and efficiency = 9.75%. Copyright © 2015 John Wiley & Sons, Ltd.     

一种基于多模板的超宽带信道估计算法

该文针对码片率抽头间隔的脉冲超宽带(IR-UWB)系统离散信道,提出一种基于帧(frame)级采样速率的多模板信道估计算法。在该算法中引入了若干个复合信道参数,每个复合信道参数都是几个独立信道参数的线性组合。利用极大似然准则和从多个模板中获得的帧级采样数据,可以先获得所有复合信道参数的极大似然估计值。然后联合由不同模板得到的复合信道参数估计值,得到每个独立的信道参数的极大似然估计。通过仿真,验证了该方法的可行性。     

电力系统短期负荷预测中非线性模型的研究与应用

介绍了时间序列分析中的一类非线性模型-SETAR模型的特点及其建 模，将这一模型应用于电力系统的短期日负荷预报。这种模型可以描述一些非 线性的时间序列，在负荷序列波动较大时仍能进行很好的预测，实例计算结果 表明预测精度满足要求，证实了将这一模型应用于电力系统短期负荷预测是可 行的。     

谈饭店行业冷凝水的回收

介绍了回收冷凝水的技术基础及在饭店行业如何具体应用等方面的基本知识。