煤粉源集合体对水力压裂效果的影响

煤粉颗粒在压裂液中发生"造浆"及"聚集"作用是影响煤层气藏水力压裂效果的关键.构造煤粉源集合体对压裂效果影响显著,研究结果表明:原位状态下,煤粉以构造煤粉源和原生裂缝煤粉源集合体两种形式赋存.前者体积在20~30m3之间,呈顺层和断层两种产状,其明显受煤储层小微构造的控制;后者规模很小,主要分布在内生裂隙缝间,其受煤变质程度和煤岩类型影响.煤层气完井期间,井筒附近构造煤坍塌扩径,构造煤粉源卸压膨胀,煤粉颗粒启动难度降低;压裂期间,在压裂液动压、紊流搅动作用下,煤粉颗粒均匀混合在流体中形成浆体;排采期间,回排的压裂液中煤粉含量较高,导致气井近井部位压裂裂缝及炮眼较早地堵塞,气井减产.而原生裂缝内煤粉在压裂液中通过颗粒疏水相互作用发生聚集,在压裂裂缝内形成堵塞,但堵塞程度较轻.稳定压裂液注入排量、减小流速,利用煤储层小微构造解剖技术预测构造煤粉源集合体发育部位能够降低近井部位堵塞的风险,改善水力压裂效果.     

Numerical Simulation of Energy Saving Potential in Dispersing Process of Blasted Smoke in Mines

The dispersing process of the blasted smoke in underground mines by ventilation is very important for the safety of personnel, and its energy consumption is also worthy of concern. In this study, the impact of supply air flow rate on the decay process of harmful gases and fan energy, and the role of harmful gases buried by blasted pile in the smoke dispersing process is analyzed with three-dimensional numerical simulation. According to the results, air flow facilitates quick smoke dispersion and the gas emits from the blasted pile is only significant at the beginning of ventilation. It is thus recommended that large amount of air supply is taken to disperse the smoke quickly until the concentration of harmful gases reaches relevant standards, and reduce the amount of air in the remain time with frequency conversion technology to save energy. In the given study, 12 m/s air flow rate is taken for dispersing smoke and 3 m/s air flow rate is taken for the waiting time. The energy consumption for ventilation is reduced by about 50％. In addition, due to the gases in the blasted pile remains very high concentration after the dispersing process, it is recommended to keep suitable amount of ventilation in the consequent process.     

LS—SVM算法在光伏短期功率预测中的应用

以光伏阵列为研究对象,分析了辐照强度、温度以及日类型对光伏阵列出力的影响。建立了光伏短期功率预测最小二乘支持向量机LS-SVM模型。依据实验数据对模型进行了验证计算．并与BP神经网络模型做了比较,其中LS-SVM模型最大相对误差值为10．54％,平均绝对百分比误差（MAPE）为8．18％,绝对误差平方和平均值的均方根（RMSE）为0．4884,表明模型预测值离散化程度较小,所有预测点均与实际值非常接近,模型具有较好的拟合效果和泛化能力．可以有效地预测短期光伏发电功率。     

Degradability and biocompatibility of bioglass/poly(amino acid) composites with different surface bioactivity as bone repair materials

Bioglass (BG) possesses excellent bioactivity and has been widely used in the manufacture of biomaterials. In this study, a composite with different surface bioactivity was fabricated via in situ melting polymerization by incorporating BG and poly(amino acid) (PAA) at a suitable ratio. The structure of the composite was characterized by Fourier transform infrared spectroscopy and XRD. The compressive strength of the BG/PAA composites was 139 MPa (BG:PAA = 30:70). The BG/PAA composites were degradable, and higher BG in composite showed higher weight loss after 4 weeks of incubation in simulated body fluid. In addition, the BG/PAA composite maintained adequate residual compressive strength during the degradation period. The SEM results showed the differences in surface bioactivities of the composites directly, and 30BG/PAA composite showed thicker apatite layer and higher Ca/p than 15BG/PAA. in vitro MG-63 cell culture experiments showed that the composite was noncytotoxic and thus allows cells to adhere, proliferate, and differentiate. This indicates that the composite has good biocompatibility. The implantations in the bone defects of rabbits for 4 and 12 weeks were studied. The composites had good biocompatibility and were capable of guiding new bone formation without causing any inflammation. The composite may be successfully used in the development of bone implants.     

Preparation of treelike and rodlike carboxymethylated nanocellulose and their effect on carboxymethyl cellulose films

In this work, carboxymethyl cellulose (CMC) with low substitution degree, followed by different posttreatments, was applied to prepare treelike CMC nanofibrils (CMCNFs) and rodlike CMC nanocrystals (CMCNCs), and their performance in CMC composite film was evaluated simultaneously. From transmission electron microscopy results, it was found that the treelike CMCNCFs exhibited a lager aspect ratio compared to the rodlike CMCNCs. As for reinforcing CMC film, 4 wt% was the best adding amount, at this time, the tensile strength of CMC/CMCNFs and CMC/CMCNCs composite films was increased by 72.1% and 47.3%, respectively. Moreover, adding these nanofillers to CMC also could enhance the thermal stability of composite films slightly, while the transmittance of composite films was reduced at the same time. In addition, CMC/CMCNFs film was designed as a packaging box to determine its performance. Therefore, this study could reveal the differences of properties for composites with different types of nanocellulose and provide a foundation for further application of nanocellulose.     

Removal behavior and mechanism of silver from low concentration wastewater using cellulose aerogel modified by thiosemicarbazide

Due to the low concentration of silver in water, most of the cellulose adsorbents exhibited low removal efficiency, which greatly limited their practical applications. Herein, a cellulose aerogel modified by thiosemicarbamide (CAT) was fabricated for reducing and adsorbing silver ions from low concentration wastewater. The characterization results concluded that CAT owned a three-dimensional spongy structure with many circular microspheres and a better specific surface area (19.37 m² g⁻¹), as well as the functional groups of ─C═N⁺─H and ─(C═S)─N. The static batch adsorption experiments demonstrated that CAT could reached the maximum removal percentage of 94.94% and adsorption capacity of 42.12 mg g⁻¹ under the initial concentration of Ag(I) was 15 mg L⁻¹ and the pH value was 7. Meanwhile, the adsorption of Ag(I) on CAT was second-order reaction, and the Langmuir model could better fit the adsorption process. In addition, CAT exhibited wide pH values (1–9) adaptability and excellent adsorption performance for silver through electrostatic interaction, chelation, and reduction. This study probably provides a new method as well as important experimental data and theoretical reference for the removal of silver ions and other metals.     

Engineering all-aromatic polyamide surface from hydrophilic to superhydrophobic and the accelerated strategy

Being a new kind of nanomaterials, aromatic polyamide nanofibers (ANF) have been much highlighted in recent studies. We here demonstrate an isopropyl alcohol (IPA) accelerated chemical cleavage on poly (p-phenylene terephthalamide) chopped fibers, which provides an efficient preparation method of ANF. The comprehensive study on the processes accelerated by different alcohols revealed that the preparation time of ANF in the mixed medium of dimethyl sulfoxide (DMSO)-alcohol (20:1 in volume) was shorten to 45 min and 75 min for methanol (ethanol) and isopropanol, respectively. However, the nanofibers prepared in DMSO-IPA exhibited the minimum in axial and radial dimensions, providing the finest and most uniform diameter of 16 nm. The corresponding ANF films through vacuum assisted filtration also showed the highest tensile strength of 150 MPa, in comparison with those of the ANF films prepared using other alcohols, which were about 110 MPa. Furthermore, ANF/silicon hybrid films were prepared by the ionic ring-opening reaction followed by the alkoxysilane condensation and nanoparticle fabrication. By changing the organo functional groups in the alkoxysilane, the surface of the films were adjustable in a wide contact angle range from 56° (hydrophilic) to 150° (superhydrophobic), suggesting the amendable interfacial properties potential applicable to composite fabrication with most of the resin matrix.     

Ultrahigh molecular weight polyethylene with improved crosslink density,oxidation stability,and microbial inhibition by chemical crosslinking and tea polyphenols for total joint replacements

Highly crosslinked ultrahigh molecular weight polyethylene (UHMWPE) stabilized by vitamin E (VE) is widely applied in artificial joints as the bearings. Despite the approval, there is a discord that VE lowers the crosslinking efficiency, limiting its use at high concentration. In this work, we aim to obtain highly crosslinked and oxidation resistant UHMWPE through the conjunction of tea polyphenol and chemical crosslinking. We hypothesized that highly incorporated tea polyphenol with multiple reactive sites can ameliorate crosslinking efficiency of chemical crosslinked UHMWPE in comparison to VE. Epigallocatechin gallate (EGCG) as representative tea polyphenol was incorporated into UHMWPE at high concentration (2–8 wt%), followed by chemical crosslinking with 2 wt% organic peroxide. Unlike VE/UHMWPE blends as the control, chemical crosslinking achieved an increasing trend in crosslink density of EGCG/UHMWPE blends with increasing antioxidant concentration. High concentration of EGCG also enhanced the oxidation stability of UHMWPE. Intriguingly, EGCG endowed UHMWPE with an excellent antimicrobial property, which was inefficient in VE/UHMWPE. Cell viability was hardly affected by the high loaded antioxidant and peroxide. The chemically crosslinked UHMWPE blended with EGCG is proved to be a reasonable, cost effective and realistic alternative for use in artificial joints.     

Tough and self-healing hydrophobic association hydrogels with cationic surfactant

Hydrophobic association (HA) hydrogels with outstanding mechanical, rheological and recovery properties were successfully synthesized by micellar copolymerization of acrylamide with lauryl methacrylate. The synthesis occurred at room temperature and the synthesis condition was moderate by using the redox initiator system of Ammonium persulfate - sodium bisulfite as initiators. Cationic surfactant (dodecyl trimethyl ammonium bromide) was utilized to form micelles with hydrophobe, served as physical cross-linking points in the 3D networks of hydrogels. The HA hydrogels showed a high tensile strength of 181 kPa, superior stretchability of 2300% and excellent toughness of 2.16 MJ m⁻³. Moreover, they owned extraordinary self-recovery under different conditions. It is hopeful that the hydrogels with superior mechanical strength and self-healing properties would be applied to the fields of biomedicine and engineering. Meanwhile, based on above materials, HA hydrogels could also be synthesized with the combination of hydrophobic association and other synergistic effects, such as latex particles, electrostatic effect and nanoparticles.     

基于 YOLOv5 算法的交通标志识别技术研究

针对传统方式识别交通标志算法存在的检测精度较低的问题,提出了一种改进YOLOv5算法的交通标志识别方法.首先改进YOLOv5算法的损失函数,使用EIOU损失函数代替YOLOv5算法所使用的GIOU损失函数来优化训练模型,提高算法的精度,实现对目标更快速的识别;然后使用加权Cluster非极大值抑制(NMS)改进YOLOv5本身所使用的加权NMS算法,提高生成检测框的准确率.实验结果表明,改进后的YOLOv5算法在由长沙理工大学制作的CCTSDB交通标志数据集上训练的模型的mAP值达到了84.35％,比原始的YOLOv5算法提高了6.23％.所以改进YOLOv5算法在交通标志识别中有更高的精度,能够更好的应用到实践当中.