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151.
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Jianwei Su Mingshan Wang Yuan Li Fakun Wang Qiao Chen Peng Luo Junbo Han Shun Wang Huiqiao Li Tianyou Zhai 《Advanced functional materials》2020,30(17)
2D H‐phase vanadium disulfide (VS2) is expected to exhibit tunable semiconductor properties as compared with its metallic T‐phase structure, and thus is of promise for future electronic applications. However, to date such 2D H‐phase VS2 nanostructures have not been realized in experiment likely due to the polymorphs of vanadium sulfides and thermodynamic instability of H‐phase VS2. Preparation of H‐phase VS2 monolayer with lateral size up to 250 µm, as a new member in the 2D transition metal dichalcogenides (TMDs) family, is reported. A unique growth environment is built by introducing the molten salt‐mediated precursor system as well as the epitaxial mica growth platform, which successfully overcomes the aforementioned growth challenges and enables the evolution of 2D H‐phase structure of VS2. The honeycomb‐like structure of H‐phase VS2 with broken inversion symmetry is confirmed by spherical aberration‐corrected scanning transmission electron microscopy and second harmonic generation characterization. The phase structure is found to be ultra‐stable up to 500 K. The field‐effect device study further demonstrates the p‐type semiconducting nature of the 2D H‐phase VS2. The study introduces a new phase‐stable 2D TMDs materials with potential features for future electronic devices. 相似文献
153.
Wenshu Chen Jiajun Gu Yongping Du Fang Song Fanxing Bu Jinghan Li Yang Yuan Ruichun Luo Qinglei Liu Di Zhang 《Advanced functional materials》2020,30(25)
Large‐scale production of hydrogen from water‐alkali electrolyzers is impeded by the sluggish kinetics of hydrogen evolution reaction (HER) electrocatalysts. The hybridization of an acid‐active HER catalyst with a cocatalyst at the nanoscale helps boost HER kinetics in alkaline media. Here, it is demonstrated that 1T–MoS2 nanosheet edges (instead of basal planes) decorated by metal hydroxides form highly active / heterostructures, which significantly enhance HER performance in alkaline media. Featured with rich / sites, the fabricated 1T–MoS2 QS/Ni(OH)2 hybrid (quantum sized 1T–MoS2 sheets decorated with Ni(OH)2 via interface engineering) only requires overpotentials of 57 and 112 mV to drive HER current densities of 10 and 100 mA cm?2, respectively, and has a low Tafel slope of 30 mV dec?1 in 1 m KOH. So far, this is the best performance for MoS2‐based electrocatalysts and the 1T–MoS2 QS/Ni(OH)2 hybrid is among the best‐performing non‐Pt alkaline HER electrocatalysts known. The HER process is durable for 100 h at current densities up to 500 mA cm?2. This work not only provides an active, cost‐effective, and robust alkaline HER electrocatalyst, but also demonstrates a design strategy for preparing high‐performance catalysts based on edge‐rich 2D quantum sheets for other catalytic reactions. 相似文献
154.
Tengfei Qiu Bin Luo Eser Metin Akinoglu Jung‐Ho Yun Ian R. Gentle Lianzhou Wang 《Advanced functional materials》2020,30(31)
Metallic mesh materials are promising candidates to replace traditional transparent conductive oxides such as indium tin oxide (ITO) that is restricted by the limited indium resource and its brittle nature. The challenge of metal based transparent conductive networks is to achieve high transmittance, low sheet resistance, and small perforation size simultaneously, all of which significantly relate to device performances in optoelectronics. In this work, trilayer dielectric/metal/dielectric (D/M/D) nanomesh electrodes are reported with precisely controlled perforation size, wire width, and uniform hole distribution employing the nanosphere lithography technique. TiO2/Au/TiO2 nanomesh films with small hole diameter (≤700 nm) and low thickness (≤50 nm) are shown to yield high transmittance (>90%), low sheet resistance (≤70 Ω sq?1), as well as outstanding flexural endurance and feasibility for large area patterning. Further, by tuning the surface wettability, these films are applied as easily recyclable flexible electrodes for electrochromic devices. The simple and cost‐effective fabrication of diverse D/M/D nanomesh transparent conductive films with tunable optoelectronic properties paves a way for the design and realization of specialized transparent electrodes in optoelectronics. 相似文献
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在简要总结了各种检测大口径反射镜难点的基础上,为了实现30 m望远镜(TMT)超大口径第三反射镜的高精度检测,提出了一种融合五棱镜扫描技术和子孔径拼接测试技术的新方法。大口径反射镜分阶段依次进行了五棱镜扫描测试和子孔径拼接检测,对该技术的基本原理和基础理论进行了分析和研究,制定了检测30 m望远镜第三反射镜(口径为3.5 m×2.5 m)的方案,对其测试流程、五棱镜设计、五棱镜扫描像差拟合、拼接最优化算法等进行了详细分析,并对30 m望远镜第三反射镜的原理镜进行了实验验证,其最终拼接检测面形的均方根值(RMS)和斜率均方根值(slopeRMS)分别为28.676 nm和0.97 μrad。 相似文献
159.
基于高阶统计的盲均衡算法需要大量的观测数据,当观测数据有限或信道变化较快时,由于模型失配将使均衡性能严重下降,因此短数据、快收敛是近年来盲均衡技术研究的主要方向之一。本文讨论了基于子空间分解的信道识别和盲均衡技术,利用卡尔曼滤波方程,给出了一种快速收敛的盲均衡解调算法,算法只需要较少的数据样本,仿真结果表明该方法是有效的。 相似文献
160.