High/low temperature operation of electric double layer capacitor utilizing acidic cellulose-chitin hybrid gel electrolyte

An acidic cellulose-chitin hybrid gel electrolyte consisting of cellulose, chitin, 1-butyl-3-methylimidazolium, 1-allyl-3-methylimidazolium bromide, and an aqueous H₂SO₄ solution is investigated for electric double layer capacitors (EDLCs) with activated carbon fiber cloth electrodes. The acidic cellulose-chitin hybrid gel electrolyte shows a high ionic conductivity comparable to that for an aqueous 2 mol dm⁻³ H₂SO₄ solution at 0-80 °C. This system's temperature dependence in EDLC performance is investigated by galvanostatic charge-discharge measurement. An EDLC cell with the acidic hybrid gel electrolyte has higher capacitance than that with the aqueous H₂SO₄ solution in the range of operation temperatures (−10 to 60 °C). Moreover, the capacitance retention of the EDLC cell with the acidic hybrid gel electrolyte is better than that of a cell with the H₂SO₄ solution at 60 °C over 10,000 cycles. This suggests that the proposed acidic gel electrolyte has excellent stability in the presence of a strong acid, even at a high temperature of 60 °C.     

Ring-opening polymerization of various oxirane derivatives using organotin phosphate condensate; Selective synthesis of the polyether containing oxirane ring in the side chain

Ring-opening polymerization (ROP) of various oxirane derivatives of the type, 2,2-R¹,R²-CCH₂O [R¹ = H (1), CH₃ (2); R² = CH₃ (a), CH₂Cl (b), CH₂OCH₃ (c)], using organotin phosphate (Bu₂SnO-Bu₃PO₄) condensate has been explored. The ROP of monosubstituted oxiranes (1a-c) afforded ring-opened polymers in high yields (1a, 1c = 99% and 1b = 69%); the resultant polymers from monomers 1a and 1b possessed high molecular weights (M_n = 9.49 × 10⁴, 10.60 × 10⁴, respectively). In contrast, both polymer yields and molecular weights for resultant polymers in the polymerization of disubstituted oxiranes (2a-c) were considerably lower than those in the polymerization of monosubstituted monomers (1a-c). ROP of glycidyl 2-methylglycidyl ether (3) possessing two oxirane groups with different reactivity was thus conducted by organotin catalyst; the high molecular weight polyether (M_n = 9.17 × 10⁴) containing oxirane ring in the side chain has successfully been obtained in moderate yield.     

Cytoprotective effects of geraniin against peroxynitrite- and peroxyl radical-induced cell death via free radical scavenging activity

The role of natural antioxidants in combating the deleterious effects of free radicals has received much attention. In the present study, the cytoprotective effects and the free radical scavenging activity of geraniin, a hydrolysable ellagitannin from Nephelium lappaceum rind, were evaluated by using various approaches. Addition of geraniin to the culture media resulted in a profound cytoprotective effect against damages induced by the peroxynitrite generator 3-morpholinosydnonimine (SIN-1), and the peroxyl radical generator 2,2′-azobis(2-amidinopropane) dihydrochloride (AAPH). Geraniin exhibits more potent cytoprotective activity than that of 6-hydroxy-2,5,7,8-tetramethylchroman-2-carboxylic acid (Trolox). Geraniin exhibited potent antioxidant activity against reactive species, such as nitric oxide, superoxide anion, and chemically synthesized peroxynitrite. Kinetic analysis of reactivity against peroxyl radicals generated by AAPH revealed that geraniin possesses potent reactivity against peroxyl radicals with higher stoichiometric number than Trolox. The cytoprotective effect of geraniin was only observed when geraniin and these toxic compounds were co-existing, suggesting that geraninn exhibits cytoprotective effects via free radical scavenging activity in the extracellular fluid.     

Solid state NMR analysis of poly(L‐lactide) random copolymer with poly(ε‐caprolactone) and its reactive extrusion process

A random copolymer based on poly(L ‐lactide) (PLA) with poly(ε‐caprolactone) (PCL) was prepared and characterized by mechanical testing and solid state NMR, compared with a polymer blend. For a monofilament sample consisting of PLA/PCL random copolymer, there were negative correlations between the CL content and the mechanical properties: tensile strength, tensile elastic modulus, flexural rigidity, and flexural hysteresis decreased with increasing CL content. In contrast, the mechanical properties of the polymer blend were only slightly changed by addition of the CL unit. For the random copolymer, the addition of a small amount of CL reduced relaxation times, T₁C and T_1ρH, gradually. The T₁C and T_1ρH values correlated closely with the tensile elastic modulus and the tensile strength, respectively. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Double-stimuli responsive O/W emulsion gel based on a novel amidoamine surfactant

A heat-induced O/W emulsion gel that undergoes a phase transition from sol to gel on heating was formed from the addition of aqueous HCl to a toluene solution of a long-chain amidoamine derivative (C18AA). The heat induced O/W emulsions are highly sensitive to temperature, and the sol-gel transition temperature could be simply controlled by adjusting the C18AA concentration. Interestingly, the sol-gel transition of the O/W emulsions was also very sensitive to pH. Thus, we have successfully prepared a novel double-stimuli responsive gel based on O/W emulsions consisting of C18AA and HCl.     

Analytical benchmark example for risk allocation in structural optimization

Recently, Rozvany and Maute presented a simple problem of topology optimization under uncertainty with a single load condition that can be solved without Monte Carlo simulation. This note extends this idea to a two-bar truss under two load conditions for the purpose of illustrating differences between deterministic designs and reliability–based ones in terms of risk allocation. For this example, for the same probability of failure, a deterministic design based on the same safety factor for both loads can be substantially heavier than the reliability–based design. The difference in weight is due to very different risk allocation between the two failure modes.     

Finite heterogeneous element method using sliced microstructures for linear elastic analysis

A new finite heterogeneous element consisting of sliced microstructures (FHES) is applied in a multi?scale technique. The FHES represents a heterogeneous material with microscopic constituents without homogenization or microscopic finite element analysis. A representative volume element extracted from a heterogeneous structure is thinly sliced. Each slice is modeled as a combined spring to calculate properties of the FHES. Each FHES has the same number of nodes as an ordinary finite element, and the macroscopic analysis cost is the same as that for ordinary finite element analysis. However, the FHES retains information about the microscopic material layout (i.e., the distribution of a material's property) in itself that is lost during homogenization. In the proposed approach, materials are not homogenized. The FHES does not have a constant (homogenized) material property and can ‘change stiffness’ depending on its deformation behavior. This reduces error due to coarse?graining and allows us to calculate the macroscopic deformation behavior with sufficient accuracy even if a large gradient of strain is generated in the macroscopic field. The novelty of the research is the development of rational heterogeneous finite elements. The paper presents the theory behind the FHES and its practical application to a linear elastic problem. Copyright © 2014 John Wiley & Sons, Ltd.     

Synthesis of a linearly interpolated gain scheduling controller for large flexible spacecraft ETS-VIII

This paper illustrates a design procedure for a linearly interpolated gain scheduling controller for Engineering Test Satellite VIII (ETS-VIII) using its linear parameter-varying (LPV) model. The LPV model here consists of piecewise-linear functions of the paddle rotation angle and a norm-bounded perturbation. The main purpose of this research is to derive a simple structured scheduling law that can be easily implemented in a satellite onboard computer. The derived gain has only two grid points and is scheduled simply by linear interpolation, which is desirable from the standpoint of implementability. Moreover, since the synthesis condition is based on parameter-dependent Lyapunov functions, it gives less conservative results than existing methods. Simulation results are presented to show the effectiveness of the proposed synthesis.