基于ADS的低频电子元器件建模技术研究

针对国产元器件模型库缺乏的问题,在ADS软件的基础上,对不同低频电子元器件的建模方法进行了详细的介绍,重点阐述了元器件几种建模方法和具体实施步骤,并介绍了新建模型的封装和验证。该建模方法也可用于其他软件平台上的元器件建模。     

定向破片拦截下RPG-7类反坦克火箭弹(静态)毁伤模式的试验研究

为优化主动防护系统的性能,文中以静态放置的RPG-7类反坦克火箭弹战斗部为例,对其在密集破片作用下的毁伤模式进行了理论分析,并在典型条件下进行了试验验证。试验结果表明,战斗部结构解体、引信失效、装药被击爆、装药和药型罩被损坏以及装药燃烧等毁伤模式都存在,验证了理论分析的结果。文中的研究结果可为主动防护系统拦截交会参数的选择、拦截弹战斗部破片场参数的优化设计提供有益的参考。     

TiB2 Powders Synthesis by Borothermal Reduction in TiO2 Under Vacuum

TiB₂ powders were synthesized by borothermal reduction in nanoscale TiO₂ with boron under vacuum. Reaction processes were investigated, and the effect of by‐product B₂O₃ was evaluated. Results showed that TiO₂ was firstly reduced by boron to form TiBO₃ and Ti₂O₃, and then to produce TiB₂ and B₂O₃ with increasing temperature. The reaction processes of TiB₂ powders synthesis included two‐step reduction in TiO₂ by boron and the removal of B₂O₃. The presence of B₂O₃, which was previously reported as the most important factor in promoting the coarsening of ZrB₂ and HfB₂ powders by borothermal reduction, did not lead to significant coarsening of TiB₂ powders. Due to the minor effect of B₂O₃, TiB₂ powders with small particle size and low oxygen content could be prepared by direct heat treatment of TiO₂ and boron at 1550°C under vacuum for 1 h. The particle size and oxygen content of synthesized TiB₂ powders were ~0.9 μm and ~1.7 wt%, respectively.     

Sintering Behavior and Dielectric Properties of Ultra‐Low Temperature Fired Silver Molybdate Ceramics

Ag₂MoO₄ ceramic was prepared by using the solid‐state reaction method, which could be sintered at 450°C for 2 h, having a relative permittivity of 8.08, a Qf value of 17 000 GHz, and a temperature coefficient of resonance frequency about ?133 ppm/°C. Ag₂MoO₄ ceramic was chemically compatible with silver but reacted seriously with aluminum to form (Ag_0.5Al_0.5)MoO₄ during the sintering. The fitting of infrared spectra and the Shannon's additive rule were employed to study intrinsic dielectric behaviors of the ceramics at microwave region. Ionic displacive polarization and the electronic polarization contributed almost equally to the dielectric permittivity of the ceramic at microwave region. The Ag₂MoO₄ ceramics could be a good candidate for ultra‐low temperature co‐fired microwave devices.     

A Decomposition Route for Synthesis of Al2O3 Crystal and its Applications as Thermal Conductivity Filler

Platelike α‐Al₂O₃ powder was obtained at 850°C by thermal decomposition of ammonium aluminum carbonate hydroxide precursor, which was treated by hydrofluoric acid. The results showed the decomposition of the as‐prepared precursors experienced via three steps, adsorption of physical water, dehydration of crystalline water, and decomposition of the precursor, and the activation energies of the above three steps were calculated using the Coats–Redfern method. Meanwhile, the intermediate of (NH₄)₃AlF₆ obtained played an important role in decreasing activation energy of the decomposition and phase transformation. Moreover, the thermal conductivity of the epoxy resin filled with platelike alumina was improved obviously.     

Differentiated Electric Behaviors of La2/3Cu3Ti4O12 Ceramics Prepared by Different Methods

Microstructure and electric behaviors of La_2/3Cu₃Ti₄O₁₂ (LCTO) ceramics prepared by the sol‐gel method (SG) and solid‐state method (SS) have been systemically investigated. The results indicated that LCTO‐SG ceramics sintered at 1105°C for 15 h showed larger grain size, higher density, and especially higher dielectric constant up to about 0.9–1.6 × 10⁴ at 10²~10⁵ Hz compared to LCTO‐SS ceramics. The higher dielectric constant of the LCTO‐SG ceramics might be due to the stronger internal barrier layer capacitor (IBLC) effect. More notably, compared with LCTO‐SS ceramics, two kinds of dielectric anomalies, one conduction activation energy value and same activation energies for the conduction and relaxation process in LCTO‐SS ceramics, the LCTO‐SG ceramics showed three kinds of dielectric anomalies, two values of conduction activation energy, and decrease in conduction activation energy with increasing temperature. The activation energies for the conduction and relaxation process in LCTO‐SG ceramics showed great difference below about 210°C, suggesting that the mechanism of electrical conduction and dielectric relaxation seem to be different in LCTO‐SG ceramics. These remarkable differences in electric behaviors of LCTO ceramics prepared by sol‐gel and solid‐state methods were firstly found and analyzed.     

Physicochemical Property and Fatty Acid Profile of Cephalotaxus fortunei Nut Oils

This paper focused on the main composition of Cephalotaxus fortunei nuts, the physicochemical property of its oils, the fatty acid profiles and the content of alkaloids and tocopherol in the nuts oils. And these elements were compared among three kinds of C. fortunei nuts and their oil. The results showed the C. fortunei nuts contained about 65 % crude oil. Meanwhile, the content of crude protein, crude fiber, moisture, ash and reduced sugar were presented, respectively. The important physicochemical indicators of the crude C. fortunei nuts oils were presented, including specific gravity, refractive index, viscosity, acid value and saponification value, etc. The contents of alkaloids were 0.41 % in NUT1, 0.24 % in NUT2 and 0.31 % in NUT3. The contents of tocopherol were low. The analysis of the fatty acid composition showed that the three kinds of oils were all rich in unsaturated fatty acids, oleic acid and linoleic acid, and the main triacylglycerols were dioleoyl-monolinoleoyl (OLO) and triolein (OOO). This work might help with the exploration of the applications of C. fortunei nuts and its oil.     

A New Ferroelectric Phase of YMnO3 Induced by Oxygen‐Vacancy Ordering

Manganese oxides are good candidates of strongly correlated electron materials due to the uniqueness of electronic structure of manganese and the mobility of oxygen among lattice sites under external impacts. Here, we used electron beam as the excitation source to explore the structural evolution of YMnO₃ and identified a new phase under the radiation of electron beam in the transmission electron microscope. Analyses of the electron energy‐loss spectra reveal that this phase originates from ordered oxygen vacancy. We applied the first principles calculation to pick out the optimized stable structure with a lower polarization, and verified its correctness by electron diffraction and image simulations. Analyses of density of states indicate that weak Y–O covalence is favorable for the existence of ferroelectricity, supporting the electrostatic nature of ferroelectricity in the YMnO₃.     

Biomolecular Structure and Dynamics with Neutrons: The View from Simulation

The characterization of the structure and internal dynamics of biomolecules is essential to understanding their biological function. Neutron scattering probes similar time- and length-scales to molecular dynamics simulation. Hence, simulation models of biomolecules have become invaluable in the interpretation of experimental neutron data. Here, we report on advances in the application of simulation in developing neutron scattering to investigate internal protein motions and, as an example of industrial relevance, in the derivation of physical models of use in biofuel renewable energy research.     

Rheology of natural fibers thermoplastic compounds: Flow length and fiber distribution

The presented study investigates the flow length and the corresponding fiber content distribution in the injection‐moulded natural fiber reinforced thermoplastics and its relation to fiber type and processing parameters such as injection pressure, temperature, injection rate and mould tempering by increasing die temperature. In this research, polypropylene compounds with nominally 30 wt % hemp and sisal fibers are investigated. The influence of the injection pressure (500 and 1000 bar), melt temperature (180°C, 200°C, and 220°C), and die temperature (23°C and 80°C) on the fiber content distribution all over the sample is investigated. An increasing linear trend of fiber content along the spiral length is observed as an evidence of a fiber/polymer multiflow system. A pattern for fiber content distribution with respect to the fiber length along the injected spiral can be distinguished, where the longer fibers are usually found at the end of the injected part and the shorter fibers remain near mould entrance point. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39861.