气化炉复合炉衬的传热计算

新型 (多喷嘴对置 )水煤浆气化炉拟采用水冷管和耐火浇铸料组成的复合炉衬结构 .炉内的高温高压对复合炉衬的高温侵蚀十分严重 ,是影响其寿命的重要因素 ,因此合理设计气化炉复合炉衬的结构对充分发挥其材质的作用具有十分重要的意义 .建立了气化炉复合炉衬的传热计算的数学模型 ,同时编制了模型求解的计算程序 ,并用某工艺条件对复合炉衬的温度分布进行了计算 .结果表明 ,该方法可有效计算出复合炉衬的温度分布情况 ,为复合炉衬的设计、运行和维护提供理论依据     

GYM系列亿丰磨在非金属矿物超微粉碎中的应用

干法生产超细粉是我国非金属粉体的重要加工工艺之一，传统的粉磨设备难以达到大量生产d97=2—10μm超细粉的要求，且生产效率低。阐述了采用多磨轮、多磨道原理设计的GYM-83型亿丰磨在生产粒径为11μ的碳酸钙干粉时，其累积分布达98％，粒径为2μm的占总质量44．96％，产量达到了1250kg／h，且基建投资少，性价比好。     

TiB2的SHS合成过程理论分析

在ＴｉＢ２陶瓷材料的自蔓延高温合成（简称ＳＨＳ）过程中，通过改变原料的起始温度，稀释剂的含量和原始颗粒的尺寸等都可以调节合成过程的绝热温度，产物中熔融相的含量，以及燃烧波蔓延的速度，人而最终影响合成产物的结构和性质。本文对上述各种关系进行了理论计算和分析，其结果对实际合成与制备过程将有着重要的指导作用。     

Preparation,characterization, and adsorption properties for metal ions of a novel chelating resin containing sulfoxide and diethylene glycol

A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg²⁺, Ag⁺, Cu²⁺, Zn²⁺, and Pb²⁺ at various pH values were determined. The maximum adsorption capacities for Hg²⁺ and Ag⁺ were 1.56 and 0.75 mmol g^?1 respectively. The resin had high selectivity for Hg²⁺ and Ag⁺ over the pH range 1.0–7.0. The adsorption capacities for Hg²⁺ and Ag⁺ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg²⁺ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006     

Propylene epoxidation in a microreactor with electric heating

Gas phase propylene epoxidation on gold catalysts has attracted wide attention from industry and academia due to its high selectivity. However, it suffers from low propylene conversion and rapid catalyst deactivation. Experiments showed that propylene conversion could be increased by raising H₂, O₂, or C₃H₆ concentration in the feed, but the feed compositions were within the explosion limit. It was also shown that the activity of the used catalyst could be fully recovered, but the regeneration temperature was 280 °C, much higher than that for reaction. Therefore a microchannel reactor was devised to suppress explosion and was constructed with Fecralloy, to raise the temperature rapidly for catalyst regeneration by electric heating. In two minutes the temperature of the reactor could be raised from 50 to 300 °C. Catalysts were coated on the alloy belt by dip coating, and the performance of the reactor was evaluated under different operating conditions. Results showed that in the microreactor the overall reaction rate was controlled mainly by the intrinsic reaction rate, and also influenced by film diffusion to a certain extent. The deactivated catalyst was regenerated in the microchannel reactor and the activity was fully recovered.     

智能混合控制器在转炉干法除尘中的应用

转炉干法除尘蒸发冷却器出口烟气温度大多数采用常规串级控制方式,但转炉冶炼前期控制效果并不理想.对转炉冶炼过程及蒸发冷却器出口烟气温度的控制难点进行研究,找出常规串级控制方式的缺点,并设计出一种智能混合控制器.采用智能模糊控制器和常规控制器并联的控制方式,对蒸发冷却器出口烟气温度进行控制,控制效果理想.实际应用表明,同常规串级控制器相比,智能混合控制器具有响应快、被控对象稳定等优点.     

伴有平衡反应的分离过程的数学模拟——(Ⅱ)催化精馏塔的模拟计算

提出了平衡反应的非均相催化反应精馏过程的微分数学模型。应用多目标打靶法和 Newtor-Raphson 迭代对模型方程进行了求解。本算法应用于非理想系统,反应动力学未知的快速可逆反应过程。可求得沿塔最大转化率和平衡浓度分布。应用本算法对 MTBE 的催化反应过程进行了模拟计算,能快速稳定收敛。计算结果与文献数据进行比较,表现出良好的一致性。     

Fenton氧化法处理废水的机理及应用

阐述了Fenton试剂的氧化机理 ,分析了各项因素对氧化效果的影响。介绍了光 -Fenton法、电 -Fenton法及Fenton -混凝法在废水处理中应用情况以及存在的问题 ,并展望了其发展趋势。     

低熔点合金填充聚合物材料断口形貌研究

研究了合金元素、加工温度、金属含量、第三组分对低熔点金属填充聚合物材料断口形貌的影响。实验结果表明:不同的合金对体系的影响很大,低分子量、低结晶性聚合物,高的成型加工温度可提高材料的相容性。