Electrophosphorescent Polyfluorenes Containing Osmium Complexes in the Conjugated Backbone

Electrophosphorescent copolymers have been synthesized by covalent bonding of a red‐emitting osmium complex Os(bpftz), which contains two 3‐trifluoromethyl‐5‐(4‐tert‐butyl‐2‐pyridyl)triazolate (bpftz) cyclometalated ligands, into the backbone of a bipolar polyfluorene (PF) copolymer. Employing these copolymers, a highly efficient red polymer light‐emitting diode has been realised that has an external quantum efficiency of 18.0%, a maximum brightness of 38 000 cd m^?2, and an emission centered at 618 nm. In addition, after incorporating appropriate amounts of green‐emitting benzothiadiazole (BT) and the aforementioned Os(bpftz) into the bipolar PF, an efficient white‐light electroluminescent polymer is obtained that displays simultaneous blue, green, and red emissions.     

基于Multisim8的运算放大器的线性应用仿真

在模拟电路的教学中,运算放大器的线性应用无疑是一个重点内容。如果在教学中应用Multisim8仿真辅助教学,可以避免理论教学过程中讲述枯燥,大大提高教学效率。通过仿真可以形象的将运算放大器的应用电路和结果展示在学生眼前,一方面加深学生对理论的理解,另一方面学生通过设计仿真软件看到了实际电路的结构和使用方法。     

Si-H bond breaking induced retention degradation during packaging process of 256 mbit DRAMs with negative wordline bias

Data retention degradation of a 256-Mbit DRAM during the packaging process is investigated in this paper. Electrical measurement and device simulation show that a trap-assisted leakage degrades the retention time even in packaging process at about 250/spl deg/C. Retention time of the degraded chip is strongly dependent on the negative wordline voltage and operation temperature, but less sensitive to the substrate bias. Trap-assisted gate induced drain leakage is proposed as the mechanism of retention loss in the degraded chip. The degraded chips usually can be repaired by another thermal baking process. We propose Si-H bond breaking and the subsequent trap generation at the gate and drain overlap region as the root cause of retention degradation according to the fact that the Si-H bond density of backend passivation oxide and nitride layers correlate well with the retention performance of DRAM chips with negative wordline bias. Moreover, the packaged chip shows variable retention behavior during a thermal baking of 250/spl deg/C. Theoretical calculation indicates that the trap generation or movement to the high electrical field region beneath the gate can increase the trap-assisted gate induced drain leakage by about an order of magnitude.     

Deposition of Carotenoids in Eggs from Hens Fed Diets Containing Saponified and Unsaponified Oleoresin Paprika

Deposition of carotenoids in saponified paprika (SP) and unsaponified oleoresin paprika (OP) in egg yolks as well as the dietary level for desired pigmentation were evaluated. Sixty-four hens on a carotenoid-depletion diet were divided into two replicated groups of each of eight dietary treatments containing from 0 to 16 mg paprika carotenoids per kg feed. Colour and the carotenoid content of egg yolk increased linearly ( P< 0·01) with the amounts of paprika carotenoids in the diets. The colours of egg yolks from hens fed similar concentra-tions of OP or SP were not significantly different ( P< 0·01). A low dose (4 mg kg⁻¹) of OP or SP provided yolk colour equivalent to the colour of eggs in supermarkets. High-performance liquid chromatographic analyses showed that carotenoids deposited in the yolk are in the free alcohol form, regardless of the form of carotenoids in the diet. Capsanthin, the predominant carotenoid in paprika, was deposited in egg yolk less efficiently than zeaxanthin and lutein.     

Bioinspired Graphene Actuators Prepared by Unilateral UV Irradiation of Graphene Oxide Papers

Inspired by natural autonomous systems that demonstrate controllable shape, appearance, and actuation under external stimuli, a facile preparation of moisture responsive graphene‐based smart actuators by unilateral UV irradiation of graphene oxide (GO) papers is reported. UV irradiation of GO is found to be an effective protocol to trigger the reduction of GO; however, due to the limited light transmittance and thermal relaxation, thick GO paper cannot be fully reduced. Consequently, by tuning the photoreduction gradient, anisotropic GO/reduced GO (RGO) bilayer structure can be easily prepared toward actuation application. To get better control over the responsive properties, GO/RGO bilayer paper with a certain curvature and RGO patterns are successfully prepared for actuator design. As representative examples, smart humidity‐driven graphene actuators that mimic the cilia of respiratory tract and tendril climber plant are successfully developed for controllable objects transport.     

Design of smallest size two-dimensional linear-phase FIR filters with magnitude error constraint

This paper presents an online procedure that produces the smallest feasible size of two-dimensional FIR filters with prescribed magnitude error constraint. The procedure uses the mean square normalized error of constrained and unconstrained least-square filters to produce the initial and the subsequent sizes that converge to the smallest feasible one in a few iterations, where the constrained least-square filters are defined as the least-square filters satisfying the magnitude error constraint. The procedure finally returns a smallest size filter that satisfies the magnitude error constraint and has least total squared magnitude error. Design examples of diamond-shaped, rectangular, and elliptic filters are provided, and comparisons with an exhaustive search are given.     

Ni1−xCoxSe2?C/ZnIn2S4 Hybrid Nanocages with Strong 2D/2D Hetero-Interface Interaction Enable Efficient H2-Releasing Photocatalysis

Designing a semiconductor-based heterostructure photocatalyst for achieving the efficient separation of photogenerated electron-hole pairs is highly important for enhancing H₂ releasing photocatalysis. Here, a new class of Ni_1−xCo_xSe₂–C/ZnIn₂S₄ hierarchical nanocages with abundant and compact ZnIn₂S₄ nanosheets/Ni_1−xCo_xSe₂^ C nanosheets 2D/2D hetero–interfaces, is designed and synthesized. The constructed heterostructure photocatalyst exposes rich hetero-junctions, supplying the broad and short transfer paths for charge carriers. The close contacts of these two kinds of nanosheets induce a strong interaction between ZnIn₂S₄ and Ni_1−xCo_xSe₂ C, improving the separation and transfer of photo-generated electron-hole pairs. As a consequence, the distinctive Ni_1−xCo_xSe₂ C/ZnIn₂S₄ hierarchical nanocages without using additional noble-metal cocatalysts, display remarkable H₂-relaesing photocatalytic activity with a rate of 5.10 mmol g⁻¹ h⁻¹ under visible light irradiation, which is 6.2 and 30 times higher than those of fresh ZnIn₂S₄ nanosheets and bare Ni_1−xCo_xSe₂ C nanocages, respectively. Spectroscopic characterizations and theory calculations reveal that the strong interaction between ZnIn₂S₄ and Ni_1−xCo_xSe₂ C 2D/2D hetero-interfaces can powerfully promote the separation of photo-generated charge carriers and the electrons transfer from ZnIn₂S₄ to Ni_1−xCo_xSe₂ C.     

Non-Halogenated-Solvent Processed and Additive-Free Tandem Organic Solar Cell with Efficiency Reaching 16.67%

Organic solar cells (OSCs) have recently reached a remarkably high efficiency and become a promising technology for commercial application. However, OSCs with top efficiency are mostly processed by halogenated solvents and with additives that are not environmentally friendly, which hinders large-scale manufacture. In this study, high-performance tandem OSCs, based on polymer donors and two small-molecule acceptors with different bandgaps, are fabricated by solution processing with non-halogenated solvents without additive. Importantly, the two active layers developed from non-halogenated solvents show better phase segregation and charge transport properties, leading to superior performance than halogenated ones. As a result, a tandem OSC with high efficiency of up to 16.67% is obtained, showing unique advantages in future massive production.     

Mediated Electrochemistry to Mimic Biology's Oxidative Assembly of Functional Matrices

Biology uses diffusible oxidants to perform functions that range from signaling to matrix assembly, and these oxidation chemistries offer surprising selectivities. Here, it is reported that mediated electrochemistry can access the richness of such oxidation chemistries. Specifically, electrode‐imposed voltage inputs are used to locally generate oxidized mediators that can diffuse into polymer solutions and induce the formation of covalent bonds for the deposition and functionalization of hydrogels at the electrode surface. Depending on the mediator's redox potential (E⁰), it is possible to “gate” the voltage inputs to target specific residues (e.g., thiols or amines) and oxidation chemistries. Further, mediators of varying E⁰ offer different reactivities and thus allow control of reaction‐diffusion rates to modulate the hydrogel's crosslink density and mechanical properties. Importantly, this mediated oxidation can be performed under physiologically relevant conditions to preserve labile biological functionalities (e.g., cell viability and protein function). Finally, it is demonstrated that protein fusion tags can be engineered to have “targetable” amino acid residues that enable protein function to be oxidatively conjugated to electrodeposited hydrogels. In summary, mediated electrochemistry can engage orthogonal oxidation chemistries to create functionalized matrices and thus mediated electrochemistry should add important capabilities to the electrofabrication toolbox.     

An indium phosphide MMIC amplifier for 180-205 GHz

This paper describes a high-performance indium phosphide (InP) monolithic microwave integrated circuit (MMIC) amplifier, which has been developed for application in radioastronomy and imaging-array receivers. Implemented using coplanar waveguide, the six-stage amplifier exhibits 15 db gain, 10 dB input and output return loss, and low noise figure over the 180-205 GHz frequency range. Only one design pass was needed to obtain excellent agreement between the predicted and measured characteristics of the circuit, a unique achievement in this frequency band. The circuit is also the first 180-205 GHz amplifier designed for and successfully fabricated using TRW's standard 0.1-μm InP HEMT process