Improvement of dielectric breakdown strength and energy storage performance in Er2O3–modified 0.95Sr0.7Ba0.3Nb2O6-0.05CaTiO3 lead-free ceramics

In this study, 0.95?Sr_0.7Ba_0.3Nb₂O₆-0.05CaTiO₃-x wt% Er₂O₃ ceramics (SBNCTEx; x?=?0–5) were synthesized using traditional solid-state method, and we investigated the microstructure, energy storage properties as well as the relationship between dielectric breakdown strength and interfacial polarization. As compared with pure 0.95?Sr_0.7Ba_0.3Nb₂O₆-0.05CaTiO₃ ceramics, the Er₂O₃ dopants suppressed the grain growth of SBNCTEx, and the doped ones showed the dense microstructure. The secondary phase was found for x?≥?1 according to the EDS results, and the influence of the secondary phase on relative dielectric breakdown strength has also been studied. The dielectric breakdown strength increased from 18.1?kV/mm to 34.4?kV/mm, which is good for energy storage. The energy storage density of 0.28?J/cm³ and the energy storage efficiency of 91.4% were obtained in the SBNCTE5 ceramics. The results indicate that SBNCTE ceramics can be used as energy storage capacitors.     

A new perspective of co-doping and Nd segregation effect on proton stability and transportation in Y and Nd co-doped BaCeO3

Bulk and surface properties of proton stability and transportation in Y and Nd co-doped BaCeO₃ (BCYN), especially the effect of Nd segregation, were investigated by first-principles calculations. Since the structure of doped BaCeO₃ at the operating temperature of proton-conducting has been unclear for a long time, we have summarized the latest experimental results and calculated the structure of the asymmetric BCYN for the first time. The results show that compared with Y, Nd doping promotes oxygen vacancy formation, however reduces proton stability. Our calculation can also provide a possible explanation for the formation of space charge layer at the grain boundary of doped BaCeO₃ in experiment. Unlike the stable Y in BCYN, Nd is calculated to be easily segregated, which can facilitate both proton hydration and proton transportation near the surface. Moreover, Nd segregation at the grain boundary is predicted to be beneficial for proton transportation between grains.     

Fine-grained cooperative access control scheme with hidden policies

The traditional ciphertext policy attribute-based encryption (CP-ABE) has two problems:one is that the access policy must be embedded in the ciphertext and sent, which leads to the disclosure of user爷 s privacy information, the other is that it does not support collaborative decryption, which cannot meet the actual demand of conditional collaborative decryption among multiple users. In order to deal with the above two problems at the same time, a fine-grained cooperative access control scheme with hidden policies (FCAC-HP) is proposed based on the existing CP-ABE schemes combined with blockchain technology. In FCAC-HP scheme, users are grouped by group identifier so that only users within the same group can cooperate. In the data encryption stage, the access policy is encrypted and then embedded in the ciphertext to protect the privacy information of the access policy. In the data access stage, the anonymous attribute matching technology is introduced so that only matched users can decrypt ciphertext data to improve the efficiency of the system. In this process, a smart contract is used to execute the verification algorithm to ensure the credibility of the results. In terms of security, FCAC-HP scheme is based on the prime subgroup discriminative assumption and is proved to be indistinguishable under chosen plaintext attack (CPA) by dual system encryption technology. Experimental verification and analysis show that FCAC-HP scheme improves computational efficiency while implementing complex functions.     

Microstructural and electrical changes in Ca0.9R0.1CeNbMoO8 (R = Y,Sm, Nd,La) ceramics induced by rare-earth ion doping

Rare-earth ions doped Ca_0.9R_0.1CeNbMoO₈ (R = Y, Sm, Nd, La) ceramics have been successfully prepared by solid-state method, and their modifications to the microstructure and electrical properties are also investigated. The rare-earth ions doped ceramics exhibit the scheelite structure. With the increase in the radius of rare-earth ions, the lattice distortion and bond interaction will be enhanced, and the consistency of grain size will be reduced. The ceramics exhibit negative temperature coefficient (NTC) thermistor characteristics in the temperature range of 473 K-1273 K, and the activation energy decreases with the increase of the radius of rare-earth ions. Rare-earth ions doping can increase the content of Ce³⁺ ions and promote the conductivity of ceramics. Except for Sm³⁺-doped ceramics, the high-temperature aging rate of other ceramics is less than 2%. The existence of some metastable Sm²⁺ ions in Sm³⁺-doped ceramics not only increases the activation energy, but also reduces the high-temperature stability of the ceramics.     

Prediction of methane adsorption content in continental coal-bearing shale reservoir using SLD model

Shale gas, as an important unconventional resource, has drawn global attention. It is mainly composed of adsorption gas and free gas. Adsorption gas content could play an important guiding role on both the selection of favorable perspective area and the exploration and exploitation of shale gas resources. In order to accurately measure adsorption gas content, a new approach was established to predict the adsorption isotherm of methane on shale. Based on the simplified local-density (SLD) method, both the adsorption isotherms of illite, illite/smectite mixed-layer, cholorite and type III kerogen and the total shale rock could be well fitted. The fitting results show good coincidences with the true experimental test data, which proves the method is reasonable and dependable and the prediction results are effective and credible. In addition, the good simulation results show that the SLD parameters can reflect the pore structure characteristics and corresponding adsorption characteristics of the shale samples, which can be used for the quantitative characterization of shale pore system.     

"十四五"生活垃圾焚烧发电行业发展趋势分析

截至2020年年底,全国垃圾焚烧发电行业垃圾处理能力超60万吨/日,并网装机容量达到1533万千瓦,年焚烧处理垃圾量约为1.4亿吨."十三五"期间行业发展迅猛,生活垃圾焚烧发电项目在守护城乡环境、节约土地资源等方面发挥了重要作用,已是民生兜底工程,城乡协同发展的重要基础设施.在2030年碳达峰、2060年碳中和的大背景下,行业将如何发展.文中对行业现状进行简单分析,对"十四五"期间行业发展趋势进行预判,并提出相关行业发展建议.