Fiberoptic intrinsic fluorescence for in-situ cure monitoring of amine cured epoxy and composites

The cure reactions of epoxy-diamine and its composites are monitored in-situ using the intrinsic fluorescence of the aromatic diamine, diaminodiphenyl sulfone (DDS). With a fiberoptic fluorimeter, in-situ cure monitoring was performed via a single fiber, distal-end probe, in neat epoxy as well as in commercial grade prepregs containing graphite fibers and DDS curing agent. The prepregs were investigated during multiply lamination in an oven. The fluorescence excitation spectra were obtained by emitting at 420 nm with a scan range of 320 to 400 nm, and the DDS peak position was determined as a function of cure time and temperature. The DDS spectra show a progressive red shift up to 24 nm when the primary amine is reacted with epoxide to become the secondary and the tertiary amines. The spectral shift of the DDS is also correlated with the extent of epoxide reaction determined by the Fourier transform infrared (FTIR) spectroscopy. Both data exhibit a linear relation, consistent with the behavior of the DDS peak shift, which increases linearly with the amine reaction. The excitation spectra also show a temperature dependency such that the amount of red shift increases with the measurement temperature in a manner that can be described by an exponential function. The temperature effects also depend on the state of cure in the sample. The temperature correction can be made by the application of an empirically developed equation. Thus, a direct comparison can be made among the on-line data obtained under varying conditions of cure, by reducing the spectral data to any reference temperature. This intrinsic fluorescence technique is much simpler than the previously reported extrinsic fluorophore technique, which requires the addition of an extrinsic fluorophore and an internal dye, and can be applied to any commercial prepregs containing DDS, thus making it a very powerful and widely applicable monitoring tool for composite processing.     

New approach to enhance adhesions between carbon nanotube emitters and substrate by the combination of electrophoresis and successive electroplating

Complementary electroplating combined with electrophoresis enhanced the field emission characteristics of emitters by improving the adhesions between CNT emitters and substrate. The emitting current of the CNT emitters prepared by our combined method increased nine times higher than that of CNT emitters prepared by electrophoresis only, since electroplating improved the adhesion of CNT emitters. During the life-time measurement for 10 h, the emitting current of CNT emitters fabricated by electrophoresis only was drastically decreased to 13% of the initial current, while that prepared by the combination of electrophoresis and successive electroplating decreased to 64% of the initial current. We suggest that our method is a promising approach for the efficient fabrication of reliable CNT emitters.     

Porosity distribution in highly compressible cake: Experimental and theoretical verification of the dense skin

The rate of filtration and the water content of cake are influenced by the existence of a dense skin in a highly compressible cake. The phenomenon of the dense skin has been rarely studied, and its existence has not been verified experimentally. In this study, the porosity variation in a very compressible cake is measured by using a new experimental apparatus, and with this the existence of dense skin has been established experimentally. ‘Unified theory on solid-liquid separation’, a recently developed theory, is utilized for calculating the porosity variation in a very compressible cake.     

A 6 GHz 68 mW BiCMOS phase-locked loop

The design of a 6 GHz fully monolithic phase-locked loop fabricated in a 1 μm, 20 GHz BiCMOS technology is described. The circuit incorporates a voltage-controlled oscillator that senses and combines the transitions in a ring oscillator to achieve a period equal to two ECL gate delays. A mixer topology is also used that exhibits full symmetry with respect to its inputs and operates with supply voltages as low as 1.5 V. Dissipating 60 mW from a 2 V supply, the circuit has a tracking range of 300 MHz, an rms jitter of 3.1 ps, and phase noise of -75 dBc/Hz at 1 kHz offset     

A linear minimum mean square error multiuser receiver inRayleigh-fading channels

We generalize the multiuser (CDMA spread spectrum) communication systems to the fading environments. We first extend Verdu's (1986) conventional optimum receiver to Rayleigh-fading environments and then evaluate its performance. Having no knowledge of the received power at the receiving end, we therefore need an estimator to efficiently estimate the received signal strength of each user in fading environments. A linear minimum mean square error (LMMSE) unbiased estimator is proposed to attain this goal. By using the minimum mean square error (MMSE) Bayesian estimation, we further propose the LMMSE bit estimator for efficient demodulation. Its performance is close to the optimum multiuser receiver but with a much simpler polynomial complexity. To further reduce the complexity, we extend the LMMSE estimator to the sequential LMMSE estimator. In sequential estimation, we do not need to implement the matched filter banks and to perform the matrix inversion when estimating. In addition, it converges after approximately 2k iterations, where k is the number of users. With this fast convergence property and the simple structure, the sequential LMMSE estimator provides an attractive alternative to the implementation of a multiuser system     

Phase transformation of calcia-alumina-magnesia fibres produced by inviscid melt spinning

CaO-Al₂O₃-MgO (CAM) ceramic fibre produced via inviscid melt spinning (IMS) was investigated for phase transformation. Differential thermal analysis (DTA) on the as-spun CAM fibre gave two transformation peaks, one for exothermic peak at around 927°C and the other for endothermic one at around 1100°C. In order to identify each phase transformation x-ray diffraction (XRD) analysis was performed on the CAM fibres heat-treated to each phase transformation completion temperature. The exothermic peak was determined to represent crystallization of remaining amorphous phase in the as-spun CAM fibre. The endothermic peak was determined to correspond to transformation of non-equilibrium CaO · Al₂O₃ phase to equilibrium 3CaO· 5Al₂O₃ phase.     

Cryptanalysis of an involutional block cipher using cellular automata

In 2006, an involutional block cipher using cellular automata was proposed. A self-invertible CA-based structure allows for an efficient hardware implementation. This paper analyzes the insecurity of the cipher due to its conjugate property. The results of this study will make it possible to construct a decryption process without knowledge of the secret key.