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111.
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113.
The effects of oxidation in air and corrosion in high-temperature, high-pressure water on the mechanical properties of three commercially available amorphous Si-Ti-C-O (Tyranno) fibers with different oxygen contents (12%–18%) and diameters (8–11 μm) were investigated. The fibers were exposed to isothermal treatments at elevated temperatures and subsequently tested at room temperature. Structural changes in the fibers after oxidation and corrosion were also studied in order to understand better the degradation mechanisms of the fibers. Oxidation resulted in the formation of vitreous silica films and decreases of strength and Young's modulus of the fibers. Hydrothermal corrosion under 100 MPa water pressure started above 300°C and resulted in the formation of a carbon layer on the surface of the fibers. Dissolution of silica in water during the treatment was observed. Corrosion at temperatures above 400°C led to the formation of relatively thick carbon films which delaminated easily. It caused a decrease of strength and Young's modulus of the fibers. The hydrothermal method can be used for producing carbon coatings with thickness up to 2 μm on the surface of silicon carbide fibers. The degrading of the mechanical properties after oxidation and corrosion was controlled by the thickness of the oxide or carbon layer. Based on this fact, it is possible to predict changes in the mechanical properties from the oxidation data. 相似文献
114.
J. Steinhauer K. Schwab Yury Mukharsky J. C. Davis Richard E. Packard 《Journal of Low Temperature Physics》1995,100(3-4):281-307
The velocity dependence of the energy barrier for vortex creation in microscopic apertures is determined. When compared to results from other laboratories, the energy barrier seems to be a universal function of velocity. This universality suggests that the vortex nucleation process is independent of the microscopic surface structure of the aperture. In DC flow experiments, the vortices are nucleated at rates up to 700kHz. In single phase slip experiments, the rate of nucleation is on the order of 10 Hz. Each of these types of experiments gives the energy barrier in a different velocity regime. The energy barrier has more curvature, as a function of velocity, than can be accounted for by the half-ring model of vortex nucleation. 相似文献
115.
V. E. Illarionov B. M. Kochanov 《Journal of Engineering Physics and Thermophysics》1984,46(5):517-521
A practical solution is obtained for the axisymmetric problem of quasistatic drop and bubble growth.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 46, No. 5, pp. 724–729, May, 1984. 相似文献
116.
Chuanfang Zhang Matthias P. Kremer Andrés Seral‐Ascaso Sang‐Hoon Park Niall McEvoy Babak Anasori Yury Gogotsi Valeria Nicolosi 《Advanced functional materials》2018,28(9)
The fast growth of portable smart electronics and internet of things have greatly stimulated the demand for miniaturized energy storage devices. Micro‐supercapacitors (MSCs), which can provide high power density and a long lifetime, are ideal stand‐alone power sources for smart microelectronics. However, relatively few MSCs exhibit both high areal and volumetric capacitance. Here rapid production of flexible MSCs is demonstrated through a scalable, low‐cost stamping strategy. Combining 3D‐printed stamps with arbitrary shapes and 2D titanium carbide or carbonitride inks (Ti3C2Tx and Ti3CNTx, respectively, known as MXenes), flexible all‐MXene MSCs with controlled architectures are produced. The interdigitated Ti3C2Tx MSC exhibits high areal capacitance: 61 mF cm?2 at 25 µA cm?2 and 50 mF cm?2 as the current density increases by 32 fold. The Ti3C2Tx MSCs also showcase capacitive charge storage properties, good cycling lifetime, high energy and power densities, etc. The production of such high‐performance Ti3C2Tx MSCs can be easily scaled up by designing pad or cylindrical stamps, followed by a cold rolling process. Collectively, the rapid, efficient production of flexible all‐MXene MSCs with state‐of‐the‐art performance opens new exciting opportunities for future applications in wearable and portable electronics. 相似文献
117.
Tokarev A Aprelev A Zakharov MN Korneva G Gogotsi Y Kornev KG 《The Review of scientific instruments》2012,83(6):065110
We report on the development of a multifunctional magnetic rotator that has been built and used during the last five years by two groups from Clemson and Drexel Universities studying the rheological properties of microdroplets. This magnetic rotator allows one to generate rotating magnetic fields in a broad frequency band, from hertz to tens kilohertz. We illustrate its flexibility and robustness by conducting the rheological studies of simple and polymeric fluids at the nano and microscale. First we reproduce a temperature-dependent viscosity of a synthetic oil used as a viscosity standard. Magnetic rotational spectroscopy with suspended nickel nanorods was used in these studies. As a second example, we converted the magnetic rotator into a pump with precise controlled flow modulation. Using multiwalled carbon nanotubes, we were able to estimate the shear modulus of sickle hemoglobin polymer. We believe that this multifunctional magnetic system will be useful not only for micro and nanorheological studies, but it will find much broader applications requiring remote controlled manipulation of micro and nanoobjects. 相似文献
118.
A matheuristic for the discrete bilevel problem with multiple objectives at the lower level 下载免费PDF全文
Ekaterina Alekseeva Yury Kochetov El‐Ghazali Talbi 《International Transactions in Operational Research》2017,24(5):959-981
In this paper, we solve a discrete bilevel problem with multiple objectives at the lower level and constraints at the upper level coupling variables of both levels. In the case of a multiobjective lower level, we deal with a set of Pareto‐efficient solutions rather than a single optimal lower level solution. To calculate the upper level objective function value, we need to select one solution out of a potentially large set of efficient lower level solutions. To avoid the enumeration of the whole set of Pareto solutions, we formulate an auxiliary mixed integer linear programming problem with a large number of constraints. We propose an iterative exact method to solve it. To find a near‐optimal upper level solution, we apply a metaheuristic. The method is tested on the discrete ()‐centroid problem with multiple objectives at the lower level. 相似文献
119.
Xu Xiao Patrick Urbankowski Kanit Hantanasirisakul Yao Yang Stephen Sasaki Long Yang Chi Chen Hao Wang Ling Miao Sarah H. Tolbert Simon J. L. Billinge Hctor D. Abrua Steven J. May Yury Gogotsi 《Advanced functional materials》2019,29(17)
Ultrathin and 2D magnetic materials have attracted a great deal of attention recently due to their potential applications in spintronics. Only a handful of stable ultrathin magnetic materials have been reported, but their high‐yield synthesis remains a challenge. Transition metal (e.g., manganese) nitrides are attractive candidates for spintronics due to their predicted high magnetic transition temperatures. Here, a lattice matching synthesis of ultrathin Mn3N2 is employed. Taking advantage of the lattice match between a KCl salt template and Mn3N2, this method yields the first ultrathin magnetic metal nitride via a solution‐based route. Mn3N2 flakes show intrinsic magnetic behavior even at 300 K, enabling potential room‐temperature applications. This synthesis procedure offers an approach to the discovery of other ultrathin or 2D metal nitrides. 相似文献
120.
Pol Salles David Pinto Kanit Hantanasirisakul Kathleen Maleski Christopher E. Shuck Yury Gogotsi 《Advanced functional materials》2019,29(17)
MXenes, a large family of 2D transition metal carbides and nitrides, have shown potential in energy storage and optoelectronic applications. Here, the optoelectronic and pseudocapacitive properties of titanium carbide (Ti3C2Tx) are combined to create a MXene electrochromic device, with a visible absorption peak shift from 770 to 670 nm and a 12% reversible change in transmittance with a switching rate of <1 s when cycled in an acidic electrolyte under applied potentials of less than 1 V. By probing the electrochromic effect in different electrolytes, it is shown that acidic electrolytes (H3PO4 and H2SO4) lead to larger absorption peak shifts and a higher change of transmittance than the neutral electrolyte (MgSO4) (Δλ is 100 nm vs 35 nm and ΔT770 nm is ≈12% vs ≈3%, respectively), hinting at the surface redox mechanism involved. Further investigation of the mechanism by in situ X‐ray diffraction and Raman spectroscopy reveals that the reversible shift of the absorption peak is attributed to protonation/deprotonation of oxide‐like surface functionalities. As a proof of concept, it is shown that Ti3C2Tx MXene, dip‐coated on a glass substrate, functions as both transparent conductive coating and active material in an electrochromic device, opening avenues for further research into optoelectronic and photonic applications of MXenes. 相似文献